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Characteristics of Bound Water

  • Mohammad U. H. Joardder
  • Monjur Mourshed
  • Mahadi Hasan Masud
Chapter

Abstract

Bound water is that fraction of water present in food materials which is either physically or chemically attached with other compounds and solid structural matrix. Bound water shows several extraordinary characteristics. Bound water shows remarkable discrepancy in physic-chemical properties including molecular mobility, dielectric nature, vapor pressure, boiling and freezing temperature, during thermodynamic processing of foods. Several distinctive features of bound water that make it distinct from free water have been discussed in this chapter.

References

  1. 1.
    J.W. Pyper, The determination of moisture in solids: a selected review. Anal. Chim. Acta 170, 159–175 (1985)Google Scholar
  2. 2.
    M.U.H. Joardder, A. Karim, C. Kumar, R.J. Brown, Effect of cell wall properties of plant tissue on porosity and shrinkage of dried apple, in Proceedings of the 2014 International Conference on Food Properties (ICFP2014) (2014)Google Scholar
  3. 3.
    R. Toledo, M.P. Steinberg, A.I. Nelson, Quantitative determination of bound water by NMR. J. Food Sci. 33(3), 315–317 (1968)Google Scholar
  4. 4.
    H.-D. Isengard, Water content, one of the most important properties of food. Food Control 12(7), 395–400 (2001)Google Scholar
  5. 5.
    H. Hatakeyama, T. Hatakeyama, Interaction between water and hydrophilic polymers. Thermochim. Acta 308(1–2), 3–22 (1998)Google Scholar
  6. 6.
    M. Tanaka, A. Mochizuki, Effect of water structure on blood compatibility—thermal analysis of water in poly (meth) acrylate. J. Biomed. Mater. Res. A 68(4), 684–695 (2004)PubMedGoogle Scholar
  7. 7.
    T. Hatakeyama, H. Hatakeyama, Thermal Properties of Green Polymers and Biocomposites, vol 4 (Springer, Berlin, 2006)Google Scholar
  8. 8.
    D.R. Briggs, Water relationships in colloids. II. J. Phys. Chem. 36(1), 367–386 (1932)Google Scholar
  9. 9.
    J. Kuprianoff, Bound water in foods, in Fundamental Aspects of the Dehydration of Foodstuffs (1958), pp. 14–23Google Scholar
  10. 10.
    H.T. Meryman, Freeze-drying, in Cryobiology, ed. by H.T. Meryman (Academic, London, 1966), pp. 609–663Google Scholar
  11. 11.
    L.C. Dickinson, P. Chinachoti, Mobility of “unfreezable” and “freezable” water in waxy corn starch by 2 H and 1 H NMR. J. Agric. Food Chem. 8561(96), 62–71 (1998)Google Scholar
  12. 12.
    H.K. Leung, M.P. Steinberg, Water binding of food constituents as, determined by NMR, freezing, sorption and dehydration. J. Food Sci. 44(4), 1212–1216 (1979)Google Scholar
  13. 13.
    S. Shanbhag, M.P. Steinberg, A.I. Nelson, Bound water defined and determined at constant temperature by wide-line NMR. J. Food Sci. 35(5), 612–615 (1970)Google Scholar
  14. 14.
    T.P. Labuza, G.C. Busk, An analysis of the water binding in gels. J. Food Sci. 44(5), 1379–1385 (1979)Google Scholar
  15. 15.
    A.J. Fontana Jr., Measurement of Water Activity, Moisture Sorption Isotherms, and Moisture Content of Foods (Blackwell, Ames, 2008)Google Scholar
  16. 16.
    M. Caurie, A practical approach to water sorption isotherms and the basis for the determination of optimum moisture levels of dehydrated foods. Int. J. Food Sci. Technol. 6(1), 85–93 (1971)Google Scholar
  17. 17.
    S.S.H. Rizvi, Thermodynamic properties of foods in dehydration. Eng. Prop. Foods 2, 223–309 (1986)Google Scholar
  18. 18.
    S. Brunauer, P.H. Emmett, E. Teller, Adsorption of gases in multimolecular layers. J. Am. Chem. Soc. 60(2), 309–319 (1938)Google Scholar
  19. 19.
    M. Le Maguer, Thermodynamic properties for water removal processes in solid and liquid foods, in Food Properties and Computer-Aided Engineering of Food Processing Systems (Springer, Berlin, 1989), pp. 157–175Google Scholar
  20. 20.
    S. Kaleemullah, R. Kailappan, Monolayer moisture, free energy change and fractionation of bound water of red chillies. J. Stored Prod. Res. 43(2), 104–110 (2007)Google Scholar
  21. 21.
    J.M. Barat, J. Martínez-Monzó, P. Fito, A. Chiralt, Mass transport and deformation relaxation phenomena in plant tissues, in Engineering and Food for the 21st Century (CRC Press, Boca Raton, 2002)Google Scholar
  22. 22.
    L.E. Kurozawa, M.D. Hubinger, K.J. Park, Glass transition phenomenon on shrinkage of papaya during convective drying. J. Food Eng. 108(1), 43–50 (2012)Google Scholar
  23. 23.
    M.E. Katekawa, M.A. Silva, On the influence of glass transition on shrinkage in convective drying of fruits: a case study of banana drying. Dry. Technol. 25(10), 1659–1666 (2007)Google Scholar
  24. 24.
    A.J. Fontana Jr., S.J. Schmidt, T.P. Labuza, Water Activity in Foods: Fundamentals and Applications, vol 13 (Wiley, Hoboken, 2008)Google Scholar
  25. 25.
    M.S. Rahman, Food stability beyond water activity and glass transtion: macro-micro region concept in the state diagram. Int. J. Food Prop. 12(4), 726–740 (2009)Google Scholar
  26. 26.
    O.R. Fennema, Water and ice, in Food Science and Technology (Marcel Dekker, New York, 1996), pp. 17–94Google Scholar
  27. 27.
    R.B. Duckworth, Differential thermal analysis of frozen food systems. I. The determination of unfreezable water. Int. J. Food Sci. Technol. 6(3), 317–327 (1971)Google Scholar
  28. 28.
    P.S. Belton, R.R. Jackson, K.J. Packer, Pulsed NMR studies of water in striated muscle: I. Transverse nuclear spin relaxation times and freezing effects. Biochim. Biophys. Acta 286(1), 16–25 (1972)PubMedGoogle Scholar
  29. 29.
    M.V. Sussman, L. Chin, Liquid water in frozen tissue: study by nuclear magnetic resonance. Science 151(3708), 324–325 (1966)PubMedGoogle Scholar
  30. 30.
    Y.H. Roos, S. Drusch, Phase Transitions in Foods (Academic, San Diego, 2015)Google Scholar
  31. 31.
    W. Boonsupthip, D.R. Heldman, Prediction of frozen food properties during freezing using product composition. J. Food Sci. 72(5), E254–E263 (2007)PubMedGoogle Scholar
  32. 32.
    R.W. Clark, J.M. Bonicamp, The Ksp-solubility conundrum. J. Chem. Educ. 75(9), 1182 (1998)Google Scholar
  33. 33.
    M. Caurie, Bound water: its definition, estimation and characteristics. Int. J. Food Sci. Technol. 46(5), 930–934 (2011)Google Scholar
  34. 34.
    J.M. Leitch, D.N. Rhodes, Recent advances in food science. Volume 3. Biochemistry and biophysics in food research, in Recent Advances in Food Science. Volume 3. Biochemistry and Biophysics in Food Research (1963)Google Scholar
  35. 35.
    S. Chandrasekaran, S. Ramanathan, T. Basak, Microwave food processing—a review. Food Res. Int. 52(1), 243–261 (2013)Google Scholar
  36. 36.
    H.V. Lankford, L.R. Fox, Melting ice and boiling water in the mountains: a history and physics essay. Wilderness Environ. Med. 28(4), 370–374 (2017)PubMedGoogle Scholar
  37. 37.
    F. Kong, R.P. Singh, Chemical deterioration and physical instability of foods and beverages, in The Stability and Shelf Life of Food, 2nd ed. (Elsevier, London, 2016), pp. 43–76Google Scholar
  38. 38.
    R.W. Hartel, K.R. Morison, Evaporation and freeze concentration, in Handbook of Food Engineering, 2nd ed. (CRC Press, Boca Raton, 2006), pp. 507–564Google Scholar
  39. 39.
    M. Vedamuthu, S. Singh, G.W. Robinson, Properties of liquid water: origin of the density anomalies. J. Phys. Chem. 98(9), 2222–2230 (1994)Google Scholar
  40. 40.
    F. Colin, S. Gazbar, Distribution of water in sludges in relation to their mechanical dewatering. Water Res. 29(8), 2000–2005 (1995)Google Scholar
  41. 41.
    L. Vaclavik, A.J. Krynitsky, J.I. Rader, Targeted analysis of multiple pharmaceuticals, plant toxins and other secondary metabolites in herbal dietary supplements by ultra-high performance liquid chromatography–quadrupole-orbital ion trap mass spectrometry. Anal. Chim. Acta 810, 45–60 (2014)PubMedGoogle Scholar
  42. 42.
    R. Ludwig, Water: from clusters to the bulk. Angew. Chem. Int. Ed. 40(10), 1808–1827 (2001)Google Scholar
  43. 43.
    H.-D. Isengard, Water determination–scientific and economic dimensions. Food Chem. 106(4), 1393–1398 (2008)Google Scholar
  44. 44.
    D.R. Heldman, D.B. Lund, C. Sabliov, Handbook of Food Engineering (CRC Press, Boca Raton, 2006)Google Scholar
  45. 45.
    V. Mykhailyk, N. Lebovka, Specific heat of apple at different moisture contents and temperatures. J. Food Eng. 123, 32–35 (2014)Google Scholar
  46. 46.
    R. Ilker, A.S. Szczesniak, Structural and chemical bases for texture of plant foodstuffs. J. Texture Stud. 21(1), 1–36 (1990)Google Scholar
  47. 47.
    R.M. Reeve, Relationships of histological structure to texture of fresh and processed fruits and vegetables. J. Texture Stud. 1(3), 247–284 (1970)PubMedGoogle Scholar
  48. 48.
    M.U.H. Joardder, M.A. Karim, C. Kumar, Better understanding of food material on the basis of water distribution using thermogravimetric analysis, in International Conference on Mechanical, Industrial and Materials Engineering (ICMIME2013). Rajshahi, Bangladesh (2013)Google Scholar
  49. 49.
    E. Maltini, D. Torreggiani, E. Venir, G. Bertolo, Water activity and the preservation of plant foods. Food Chem. 82, 79–86 (2003)Google Scholar
  50. 50.
    H. Salwin, The role of moisture in deteriorative reactions of dehydrated foods, in Frecze-Drying of Foods (1962), p. 58Google Scholar
  51. 51.
    L.B. Rockland, Water activity and storage stability. Food Technol. 23(10), 1241 (1969)Google Scholar
  52. 52.
    R.M. Syamaladevi, S.S. Sablani, J. Tang, J. Powers, B.G. Swanson, Water sorption and glass transition temperatures in red raspberry (Rubus idaeus). Thermochim. Acta 503, 90–96 (2010)Google Scholar
  53. 53.
    G. Moraga, N. Martınez-Navarrete, A. Chiralt, Water sorption isotherms and glass transition in strawberries: Influence of pretreatment. J. Food Eng. 62(4), 315–321 (2004)Google Scholar
  54. 54.
    G. Moraga, N. Martínez-Navarrete, A. Chiralt, Water sorption isotherms and phase transitions in kiwifruit. J. Food Eng. 72(2), 147–156 (2006)Google Scholar
  55. 55.
    A. Lopez-Malo, E. Palou, J. Welti, P. Corte, A. Argaiz, Moisture sorption characteristics of blanched and osmotically treated apples and papayas. Dry. Technol. 15(3–4), 1173–1185 (1997)Google Scholar
  56. 56.
    T.P. Labuza, Sorption phenomena in foods: theoretical and practical aspects, in Theory, Determination and Control of Physical Properties of Food Materials (Springer, Dordrecht, 1975), pp. 197–219Google Scholar
  57. 57.
    M.S. Rahman, State diagram of foods: Its potential use in food processing and product stability. Trends Food Sci. Technol. 17(3), 129–141 (2006)Google Scholar
  58. 58.
    L.N. Bell, T. P. Labuza, Determination of moisture sorption isotherms, in Moisture Sorption: Practical Aspects of Isotherm Measurement and Use (American Association of Cereal Chemists, St. Paul, 2000), pp. 33–56Google Scholar
  59. 59.
    R. Boquet, J. Chirife, H.A. Iglesias, Technical note: on the equivalence of isotherm equations. Int. J. Food Sci. Technol. 15(3), 345–349 (1980)Google Scholar
  60. 60.
    K.W. Lang, M.P. Steinberg, Linearization of the water sorption isotherm for homogeneous ingredients over Aw 0.30–0.95. J. Food Sci. 46(5), 1450–1452 (1981)Google Scholar
  61. 61.
    S. Brunauer, P.H. Emmett, E. Teller, Absorption of gases in multimolecular layers. J. Am. Chem. Soc. 60, 309–319, Find this Artic. online (1938)Google Scholar
  62. 62.
    C. Van den Berg, Description of water activity of foods for engineering purposes by means of the GAB model of sorption. Eng. Food 1(311), e321 (1984)Google Scholar
  63. 63.
    A.N.N. Cadden, Moisture sorption characteristics of several food fibers. J. Food Sci. 53(4), 1150–1155 (1988)Google Scholar
  64. 64.
    C. Mok, N.S. Hettiarachchy, Moisture sorption characteristics of ground sunflower nutmeat and its products. J. Food Sci. 55(3), 786–789 (1990)Google Scholar
  65. 65.
    G. Ayerst, Determination of the water activity of some hygroscopic food materials by a dew-point method. J. Sci. Food Agric. 16(2), 71–78 (1965)Google Scholar
  66. 66.
    D.S. Reid, Water activity: fundamentals and relationships, in Water Activity in Foods. Fundamentals and Applications (2007), pp. 15–28Google Scholar
  67. 67.
    M.S. Rahman, T.P. Labuza, Water activity and food preservation. Handb. Food Preserv. 20, 448–471 (2007)Google Scholar
  68. 68.
    P.P. Lewicki, Water as the determinant of food engineering properties. A review. J. Food Eng. 61(4), 483–495 (2004)Google Scholar
  69. 69.
    S.S. Sablani, S. Kasapis, M.S. Rahman, Evaluating water activity and glass transition concepts for food stability. J. Food Eng. 78(1), 266–271 (2007)Google Scholar
  70. 70.
    M. Caurie, Bound water: Its definition, estimation and characteristics. Int. J. Food Sci. Technol. 46, 930–934 (2011)Google Scholar
  71. 71.
    E. Sandulache, Water activity concept and its role in food preservation, Technical University of Moldova, Chisinau, pp. 42–43, 2012Google Scholar
  72. 72.
    A.J. Fontana, G.V. Barbosa-Cánovas, S.J. Schmidt, T.P. Labuza, Water Activity in Foods: Fundamentals and Applications (Wiley, Exeter, 2008)Google Scholar
  73. 73.
    M. Fouskaki, K. Karametsi, N.A. Chaniotakis, Method for the determination of water content in sultana raisins using a water activity probe. Food Chem. 82, 133–137 (2003)Google Scholar
  74. 74.
    T.P. Labuza, S.R. Tannenbaum, M. Karel, Water content and stability of low-moisture & intermediate-moisture foods. Food Technol. 24, 543–550 (1970)Google Scholar
  75. 75.
    M. Shafiur Rahman, R. Hamed Al-Belushi, Dynamic isopiestic method (DIM): measuring moisture sorption isotherm of freeze-dried garlic powder and other potential uses of DIM. Int. J. Food Prop. 9(3), 421–437 (2006)Google Scholar
  76. 76.
    L. Slade, H. Levine, A food polymer science approach to structure-property relationships in aqueous food systems: non-equilibrium behavior of carbohydrate-water systems, in Water Relationships in Foods (Springer, Berlin, 1991), pp. 29–101Google Scholar
  77. 77.
    J. Chirife, P. Buera, Water activity, glass transition and microbial stability in concentrated/semimoist food systems. J. Food Sci. 59(5), 921–927 (1994)Google Scholar
  78. 78.
    M.S. Rahman, Food stability determination by macro – micro region concept in the state diagram and by defining a critical temperature. J. Food Eng. 99(4), 402–416 (2010)Google Scholar
  79. 79.
    Y. Roos, M. Karel, Plasticizing effect of water on thermal behavior and crystallization of amorphous food models. J. Food Sci. 56(1), 38–43 (1991)Google Scholar
  80. 80.
    Y.H. Roos, Water activity and glass transition, in Water Activity in Foods: Fundamentals and Applications (Blackwell, Ames, 2007), pp. 29–45Google Scholar
  81. 81.
    H. Kunzek, R. Kabbert, D. Gloyna, Aspects of material science in food processing: changes in plant cell walls of fruits and vegetables. Z. Lebensm. Unders Forsch. A 208, 233–250 (1999)Google Scholar
  82. 82.
    Y. Roos, M. Karel, Applying state diagrams to food processing and development. Food Technol. 45(12), 66–68 (1991)PubMedGoogle Scholar
  83. 83.
    M.S. Rahman, Food Properties Handbook (CRC press, Boca Raton, 2009)Google Scholar
  84. 84.
    Y.I. Matveev, V.Y. Grinberg, V.B. Tolstoguzov, The plasticizing effect of water on proteins, polysaccharides and their mixtures. Glassy state of biopolymers, food and seeds. Food Hydrocoll. 14(5), 425–437 (2000)Google Scholar
  85. 85.
    Y.H. Roos, M. Karel, J.L. Kokini, Glass transitions in low moisture and frozen foods: effects on shelf life and quality. Food Technol. 50(11), 95–108 (1996)Google Scholar
  86. 86.
    H. Levine, L. Slade, A polymer physico-chemical approach to the study of commercial starch hydrolysis products (SHPs). Carbohydr. Polym. 6(3), 213–244 (1986)Google Scholar
  87. 87.
    Y.H. Roos, Effect of moisture on the thermal behavior of strawberries studied using differential scanning calorimetry. J. Food Sci. 52(1), 146–149 (1987)Google Scholar
  88. 88.
    R.K. Richardson, S. Kasapis, Rheological methods in the characterisation of food biopolymers. Dev. Food Sci. 39, 1–48 (1998)Google Scholar
  89. 89.
    S. Kasapis, I.M. Al-Marhoobi, J.R. Mitchell, Testing the validity of comparisons between the rheological and the calorimetric glass transition temperatures. Carbohydr. Res. 338(8), 787–794 (2003)PubMedGoogle Scholar
  90. 90.
    G. Vuataz, V. Meunier, J.C. Andrieux, TG – DTA approach for designing reference methods for moisture content determination in food powders. Food Chem. 122(2), 436–442 (2010)Google Scholar
  91. 91.
    J.M.V. Blanshard, The glass transition, its nature and significance in food processing, in Physico-Chemical Aspects of Food Processing (Springer, Berlin, 1995), pp. 17–48Google Scholar

Copyright information

© Springer Nature Switzerland AG 2019

Authors and Affiliations

  • Mohammad U. H. Joardder
    • 1
  • Monjur Mourshed
    • 1
  • Mahadi Hasan Masud
    • 1
  1. 1.Department of Mechanical EngineeringRajshahi University of EngineeringRajshahiBangladesh

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