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Ni Addition Induced Changes in Structural, Magnetic, and Cationic Distribution of Zn0.75−xNixMg0.15 Cu0.1Fe2O4 Nano-ferrite

  • Manvi Satalkar
  • Shashank Narayan Kane
  • Tetiana Tatarchuk
  • João Pedro Araújo
Conference paper
Part of the Springer Proceedings in Physics book series (SPPHY, volume 214)

Abstract

Ni added Zn0.75−xNi x Mg0.15Cu0.1Fe2O4 (with x = 0.00–0.75) nanoparticles with Scherrer’s grain diameter (D) < 56.73 nm were prepared via sol-gel auto-combustion technique. The morphological and quantitative analysis of structural, magnetic properties was performed by X-ray diffraction (XRD), magnetic measurements, scanning electron microscope (SEM), and energy-dispersive X-ray analysis (EDAX). Lattice parameter (a) of Zn-Ni-Mg-Cu ferrite shows non-monotonic variation with Ni content. With Ni addition no changes are observed in the concentration of Mg2+ ions at tetrahedral A and octahedral B site. The calculated oxygen parameter (\( {u}^{\overline{4}3m} \)) values are greater than the ideal value (0.375) for Zn0.75−xNi x Mg0.15Cu0.1Fe2O4 nano-ferrite revealing distortion in spinel structure. SEM images for x = 0.00 reveal the formation of non-connected spherical pores with pore size of 555.70 nm, 768.37 nm, and 1.30 μm. EDAX validates existence of all the elements (Zn, Ni, Mg, Cu, Fe, O) in the sample. Non-zero Y-K angles for Zn0.75−xNi x Mg0.15Cu0.1Fe2O4 ferrite suggest presence of non-collinear spin structure on B site. Coercivity (Hc) ranges between 8.95 and 136.39 Oe and increases linearly with nickel addition. Saturation magnetization (Ms) increases from 23.47 to 69.78 Am2/kg for lower Ni content (0.00 ≤ x ≤ 0.45), and for higher Ni content (x > 0.45), Ms reduces from 69.78 to 36.11 Am2/kg, ascribed to cationic diffusion from A to B or from B to A site in Zn0.75−xNi x Mg0.15Cu0.1Fe2O4 nano-ferrite. The nature of the surface defects in the Ni-doped Zn-Mg-Cu ferrites has been described on the basis of antistructural modeling.

Keywords

Ferrites Cation distribution Yafet-Kittel angle Néel magnetic moment Antistructural modeling 

Notes

Acknowledgments

This work is supported by projects 783/CST/R & D/Phy and, Engg Sc, CSR-IC/CRS-74/2014-15/2104. Authors thank Dr. Mukul Gupta and Mr. L. Behra, UGC-DAE Consortium for Scientific Research, Indore, for performing XRD measurements. Authors express their gratitude to Dr. Shibu. M. Eapen, scientist-in-charge, STIC, Kochi (India), for providing SEM measurements.

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© Springer International Publishing AG, part of Springer Nature 2018

Authors and Affiliations

  • Manvi Satalkar
    • 1
  • Shashank Narayan Kane
    • 1
  • Tetiana Tatarchuk
    • 2
    • 3
  • João Pedro Araújo
    • 4
  1. 1.Magnetic Materials Laboratory, School of PhysicsD. A. UniversityIndoreIndia
  2. 2.Department of Pure and Applied ChemistryVasyl Stefanyk Precarpathian National UniversityIvano-FrankivskUkraine
  3. 3.Educational and Scientific Center of Chemical Materials Science and NanotechnologyVasyl Stefanyk Precarpathian National UniversityIvano-FrankivskUkraine
  4. 4.IFIMUP and IN-Institute of Nanoscience and Nanotechnology, Department of Physics and Astronomy, Faculty of SciencesUniversity of PortoPortoPortugal

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