Development of a Pd-Catalyzed Dearomative 1,2-Diarylation of Indoles Using Aryl Boron Reagents

Chapter
Part of the Springer Theses book series (Springer Theses)

Abstract

The Suzuki-Miyaura cross-coupling reaction is undoubtedly one of the most important carbon–carbon bond-forming processes. The extremely broad scope of this transformation has made it one of the most employed carbon–carbon bond-forming reactions in the pharmaceutical industry. This reaction traditionally involves C(sp2)–C(sp2) coupling, however, virtually all permutations of nucleophile and electrophile hybridizations have been explored. Recent effort has been focused on stereospecific and stereoselective Suzuki-Miyaura cross-couplings which allows for the formation of stereodefined carbon–carbon bonds.

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© Springer International Publishing AG, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Laboratory for Organic ChemistryETH ZürichZürichSwitzerland

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