Use of Fourier Transform Infrared (FT-IR) Spectroscopy to Determine the Type and Quantity of Rejuvenator Used in Asphalt Binder

  • L. Noor
  • N. M. WasiuddinEmail author
  • Louay N. Mohammad
  • D. Salomon
Conference paper
Part of the Sustainable Civil Infrastructures book series (SUCI)


Recent development in chemical characterization of asphalt binder ascends the scope of using nondestructive techniques to evaluate asphalt binder more rapidly in different laboratory and field condition. Among these techniques, portable Fourier Transform Infrared (FT-IR) Spectroscopy is the most advantageous considering its applicability and efficacy in terms of quick identification and quantification of chemical components in asphalt binder. Previous studies with FT-IR primarily focused on envisaging the chemical alteration in asphalt binder due to the addition of rejuvenator. In this study, FT-IR was used as a primary tool to identify the type and amount of rejuvenator added in asphalt binder. Two types of rejuvenators (bio and aromatic) were used in unmodified, polymer modified and extracted binder from RAP (Reclaimed Asphalt Pavement). Results showed that bio rejuvenator added two distinctive functional groups in asphalt binder at wavenumber 1744 cm−1 (C=O stretching) and 1162 cm−1 (C-O stretching). The amount of bio rejuvenator in asphalt sample can also be determined since C=O and C-O functional groups increased linearly with the increased percentage of added rejuvenator. The R2 values observed for unmodified and modified binders are greater than 0.95 for C=O and C-O respectively, indicating the viability of using FT-IR spectrometer for determining the type and amount of rejuvenator added. It is also observed that bio rejuvenator can be determined in samples containing 20% RAP binder mixed with both unmodified and polymer modified binder while achieving a R2 value of 0.96 (C=O and C-O). On the other hand, aromatic rejuvenator used in this study, did not add any significant functional group in all cases.


  1. 1.
    Hou, X., Lv, S., Chen, Z., Xiao, F.: Applications of Fourier transform infrared spectroscopy technologies on asphalt materials. Measurement 121, 304–316 (2018)CrossRefGoogle Scholar
  2. 2.
    Ren, R., Han, K., Zhao, P., Shi, J., Zhao, L., Gao, D., Yang, Z.: Identification of asphalt fingerprints based on ATR-FTIR spectroscopy and principal component-linear discriminant analysis. Constr. Build. Mat. 198, 662–668 (2019)CrossRefGoogle Scholar
  3. 3.
    Ghauch, A., Deveau, P.A., Jacob, V., Baussand, P.: Use of FTIR spectroscopy coupled with ATR for the determination of atmospheric compounds. Talanta 68(4), 1294–1302 (2006)CrossRefGoogle Scholar
  4. 4.
    DeDene, C.D., You, Z.P.: The performance of aged asphalt materials rejuvenated with waste engine oil. Int. J. Pavement Res. Technol. 7(2), 145–152 (2014)Google Scholar
  5. 5.
    Jia, X., Huang, B., Bowers, B.F., Zhao, S.: Infrared spectra and rheological properties of asphalt cement containing waste engine oil residues. Constr. Build. Mat. 50, 683–691 (2014)CrossRefGoogle Scholar
  6. 6.
    Azahar, W.N.A.W., Jaya, R.P., Hainin, M.R., Bujang, M., Ngadi, N.: Chemical modification of waste cooking oil to improve the physical and rheological properties of asphalt binder. Constr. Build. mat. 126, 218–226 (2016)CrossRefGoogle Scholar
  7. 7.
    Asli, H., Ahmadinia, E., Zargar, M., Karim, M.R.: Investigation on physical properties of waste cooking oil–Rejuvenated bitumen binder. Constr. Build. Mat. 37, 398–405 (2012)CrossRefGoogle Scholar
  8. 8.
    Sun, Z., Yi, J., Huang, Y., Feng, D., Guo, C.: Properties of asphalt binder modified by bio-oil derived from waste cooking oil. Constr. Build. Mat. 102, 496–504 (2016)CrossRefGoogle Scholar
  9. 9.
    Chen, M., Xiao, F., Putman, B., Leng, B., Wu, S.: High temperature properties of rejuvenating recovered binder with rejuvenator, waste cooking and cotton seed oils. Constr. Build. Mat. 59, 10–16 (2014)CrossRefGoogle Scholar
  10. 10.
    Sun, D., Lu, T., Xiao, F., Zhu, X., Sun, G.: Formulation and aging resistance of modified bio-asphalt containing high percentage of waste cooking oil residues. J. Cleaner Prod. 161, 1203–1214 (2017)CrossRefGoogle Scholar
  11. 11.
    Nguyen, D., Haghshenas Fatmehsari, H., Kommidi, S., Kim, Y.R.: Optimizing Chemical & Rheological Properties of Rejuvenated Bitumen (2016)Google Scholar
  12. 12.
    Zhu, H., Xu, G., Gong, M., Yang, J.: Recycling long-term-aged asphalts using bio-binder/plasticizer-based rejuvenator. Constr. Build. Mat. 147, 117–129 (2017)CrossRefGoogle Scholar
  13. 13.
    Cavalli, M.C., Zaumanis, M., Mazza, E., Partl, M.N., Poulikakos, L.D.: Effect of ageing on the mechanical and chemical properties of binder from RAP treated with bio-based rejuvenators. Compos. Part B: Eng. 141, 174–181 (2018)CrossRefGoogle Scholar
  14. 14.
    Zhang, R., You, Z., Wang, H., Ye, M., Yap, Y.K., Si, C.: The impact of bio-oil as rejuvenator for aged asphalt binder. Constr. Build. Mat. 196, 134–143 (2019)CrossRefGoogle Scholar
  15. 15.
    Cai, X., Zhang, J., Xu, G., Gong, M., Chen, X., Yang, J.: Internal aging indexes to characterize the aging behavior of two bio-rejuvenated asphalts. J. Cleaner Prod. 220, 1231–1238 (2019)CrossRefGoogle Scholar
  16. 16.
    Elkashef, M., Williams, R.C., Cochran, E.W.: Thermal and cold flow properties of bio-derived rejuvenators and their impact on the properties of rejuvenated asphalt binders. Thermochim. Acta 671, 48–53 (2019)CrossRefGoogle Scholar
  17. 17.
    Kaseer, F., Martin, A.E., Arámbula-Mercado, E.: Use of recycling agents in asphalt mixtures with high recycled materials contents in the United States: a literature review. Constr. Build. Mat. 211, 974–987 (2019)CrossRefGoogle Scholar
  18. 18.
    Yut, I., Zofka, A.: Attenuated total reflection (ATR) Fourier transform infrared (FT-IR) spectroscopy of oxidized polymer-modified bitumens. Appl. Spectrosc. 65(7), 765–770 (2011)CrossRefGoogle Scholar
  19. 19.
    ASTM D2172-05, Standard Test Methods for Quantitative Extraction of Bitumen From Bituminous Paving Mixtures, ASTM International, West Conshohocken, PA (2005).
  20. 20.
    ASTM D5404-03, Standard Practice for Recovery of Asphalt from Solution Using the Rotary Evaporator, ASTM International, West Conshohocken, PA (2003).
  21. 21.
    AASTHO T302, Standard Method of Test for Polymer Content of Polymer-Modified Emulsified Asphalt Residue and Asphalt Binders, American Association of State Highway and Transportation Officials (AASHTO) (2015)Google Scholar
  22. 22.
    Marcelo, M.C.A., Mariotti, K.C., Ferrão, M.F., Ortiz, R.S.: Profiling cocaine by ATR–FTIR. Forensic Sci. Int. 246, 65–71 (2015)CrossRefGoogle Scholar

Copyright information

© Springer Nature Switzerland AG 2020

Authors and Affiliations

  • L. Noor
    • 1
  • N. M. Wasiuddin
    • 1
    Email author
  • Louay N. Mohammad
    • 2
  • D. Salomon
    • 3
  1. 1.Louisiana Tech UniversityRustonUSA
  2. 2.Department of Civil and Environmental EngineeringLouisiana State UniversityBaton RougeUSA
  3. 3.Pavement Preservation Systems, LLCGarden CityUSA

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