The Effect of Heat-Treatment and Bioresorbability of Silicate-Containing Hydroxyapatite

  • Tatyana Panova
  • Olga A. GolovanovaEmail author
Conference paper
Part of the Lecture Notes in Earth System Sciences book series (LNESS)


The possibility of modification of hydroxyapatite of a prototype extracellular liquid synthesized from solution under close physiological conditions by silicate ions was studied. The formation of chemically structured hydroxyapatite with various degrees of substitution of phosphate groups in silicate groups was established by chemical and X-ray diffraction analysis, IR spectroscopy and optical microscopy. It is shown that apatite modified by silicon has an imperfect structure and crystallizes in the nanocrystalline state. It was found that during the experiment an increase in the calcination temperature to 200–1000 °C leads to weight loss. The greatest loss of mass occurs at temperatures in the range of 25–400 °C, which is due to the removal of crystallization and adsorption water and volatile impurities. Three main stages of thermal decomposition of Si-HA are isolated, the final product is a mixture consisting of two phases: Si-HA and β-TKF. The results of the research can be used to study the kinetics of dissolution and the biocompatibility of ceramic materials for medicine, namely for reconstructive surgery, dentistry, and development of drug delivery systems.


Hydroxyapatite XRD IR spectroscopy Extracellular fluid Structure Phase composition Degradation Thermal effects Bioresorbability 


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© Springer Nature Switzerland AG 2020

Authors and Affiliations

  1. 1.F.M. Dostoevsky State UniversityOmskRussia

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