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Application of Magnetic Nanoparticles for Removal of Pesticides from Environmental Samples Prior to Instrumental Analysis

  • Kamlesh Shrivas
  • Sanyukta Patel
  • Pathik Maji
  • Deepak Sinha
Chapter
Part of the Nanotechnology in the Life Sciences book series (NALIS)

Abstract

Magnetic nanoparticles (MNPs) are a special class of functional materials which can be manipulated using magnetic fields. Such particles commonly consist of a magnetic material (iron, nickel, and cobalt) and a functionalized chemical component. MNPs are superparamagnetic because of their nanoscale size, offering great potentials in their bare form or coated with a surface coating and functional groups. Magnetic nanoparticles (MNPs) are of great interest in modern research for various environmental remedies including a wide range of other disciplines. It is a challenging task to synthesize novel MNPs with unique physical, chemical, and electrical properties for application use for separation and analysis of chemical substances. Here, we describe the different synthesis methods such as coprecipitation, thermal decomposition, hydrothermal method, microemulsion, sonochemical processing, sol-gel method, and electrochemical method for preparation of functionalized MNPs. Finally, the mechanism of separation and its application for analysis of pesticides from various samples using UV-Vis, high-performance liquid chromatography (HPLC), gas chromatography (GC), HPLC-mass spectrometry (MS) and GC-MS, and electroanalytical techniques are also reported.

Keywords

Magnetic nanoparticles Pesticides Extractions Analysis 

References

  1. Adelantado C, Rios A, Zougagh M (2018) Magnetic nanocellulose hybrid nanoparticles and ionic liquid for extraction of neonicotinoid insecticides from milk samples prior to determination by liquid chromatography-mass spectrometry. Food Addit Contam Part A Chem Anal Control Expo Risk Assess 35:1755–1766CrossRefGoogle Scholar
  2. Badawy MEI, Marei ASM, El-Nouby MAM (2018) Preparation and characterization of chitosan-siloxane magnetic nanoparticles for the extraction of pesticides from water and determination by HPLC. Sep Sci Plus 1:506–519CrossRefGoogle Scholar
  3. Baker I (2018) Magnetic nanoparticle synthesis. Nanobiomaterial 198–229Google Scholar
  4. Bala R, Sharma RK, Wangoo N (2016) Development of gold nanoparticles based aptasensor for the colorimetric detection of organophosphorus pesticides phorate. Anal Bioanal Chem 408:333–338CrossRefGoogle Scholar
  5. Conroy S, Jerry Lee SH, Zhang M (2008) Magnetic nanoparticles in MR imaging and drug delivery. Adv Drug Deliv Rev 60:1252–1265CrossRefGoogle Scholar
  6. Daou TJ, Pourroy G, Colin SB, Greneche JM, Bouillet CU, Legare P, Bernhardt P, Leuvrey C, Rogez G (2006) Hydrothermal synthesis of monodisperse magnetite nanoparticles. Chem Mater 18:4399–4404CrossRefGoogle Scholar
  7. Darezereshki E, Alizadeh M, Bakhtiari F, Schaffie M, Ranjbar M (2011) A novel thermal decomposition method for the synthesis of ZnO nanoparticles from low concentration ZnSO4 solutions. Appl Clay Sci 54:107–111CrossRefGoogle Scholar
  8. Domingo C, Clemente RR, Blesa M (1994) Morphological properties of a-FeOOH, g-FeOOH and Fe3O4 obtained by oxidation of aqueous Fe (II) solutions. J Colloid Interface Sci 165:244–252CrossRefGoogle Scholar
  9. Fan C, Liang Y, Dong H, Ding G, Zhang W, Tang G, Yang J, Kong D, Wang D, Cao Y (2017) In-situ ionic liquid dispersive liquid-liquid microextraction using a new anion-exchange reagent combined Fe3O4 magnetic nanoparticles for determination of pyrethroid pesticides in water samples. Anal Chim Acta 975:20–29CrossRefGoogle Scholar
  10. Gleich B, Weizenecker J (2005) Tomographic imaging using the nonlinear response of magnetic particles. Nature 435:1214–1217CrossRefGoogle Scholar
  11. Gu H, Xu K, Xu C, Xu B (2006) Biofunctional magnetic nanoparticles for protein separation and pathogen detection. Chem Commun 941–949Google Scholar
  12. Gupta AK, Gupta M (2005) Synthesis and surface engineering of iron oxide nanoparticles for biomedical applications. Biomaterials 26:3995–4021CrossRefGoogle Scholar
  13. Gupta V, Moradi O, Tyagi I, Agrawal S, Sadegh H, Shahryari-Ghoshekandi R, Makhlouf A, Goodarzi M, Garshasbhi A (2016) Study on the removal of heavy metal ions from industry waste by carbon nanotubes: effect of the surface modification: a review. Crit Rev Environ Sci Technol 46:93–118CrossRefGoogle Scholar
  14. He L, Wang M, Ge J, Yin Y (2012) Magnetic assembly route to colloidal responsive photonic nanostructures. Acc Chem Res 45:1431–1440CrossRefGoogle Scholar
  15. Heidari H, Razmi H (2012) Multi-response optimization of magnetic solid phase extraction based on carbon-coated Fe3O4 nanoparticles using desirability function approach for the determination of the organophosphorus pesticides in aquatic samples by HPLC–UV. Talanta 99:13–21CrossRefGoogle Scholar
  16. Hyeon T (2003) Chemical synthesis of magnetic nanoparticles. Chem Commun 8:927–934CrossRefGoogle Scholar
  17. Karimian R, Piri F, Hosseini Z (2017) Magnetic molecularly imprinted nanoparticles for the solid-phase extraction of diazinon from aqueous medium, followed its determination by HPLC-UV. J Appl Biotechnol Rep 4:533–539Google Scholar
  18. Kaur R, Hasan A, Iqbal N, Alam S, Saini MK, Raza SK (2014) Synthesis and surface engineering of magnetic nanoparticles for environmental cleanup and pesticide residue analysis: a review. J Sep Sci 37:1805–1825CrossRefGoogle Scholar
  19. Kavre I, Kostevc G, Kralj S, Vilfan A, Babic D (2014) Fabrication of magneto-responsive microgears based on magnetic nanoparticle embedded PDMS. RSC Adv 4:38316–38322CrossRefGoogle Scholar
  20. Liu X, Li L, Liu YQ, Shi XB, Li WJ, Yang Y, Mao LG (2014) Ultrasensitive detection of deltamethrin by immune magnetic nanoparticles separation coupled with surface plasmon resonance sensor. Biosens Bioelectron 59:328–334CrossRefGoogle Scholar
  21. Lopez JA, Gonzalez F, Bonilla FA, Zambrano G, Gomez ME (2010) Synthesis and characterization of Fe3O4 magnetic nanofluid. Revista Latinoam. e Metal. y Mater 30:60–66Google Scholar
  22. Lu AH, Schmidt W, Matoussevitch N, Bonnemann H, Spliethoff B, Tesche B, Bill E, Kiefer W, Schuth F (2004) Nanoengineering of a magnetically separable hydrogenation catalyst. Ang Chem Int Ed Engl 43:4303–4306CrossRefGoogle Scholar
  23. Lu AH, Salabas EL, Schuth F (2007) Magnetic nanoparticles: synthesis, protection, functionalization, and application. Angew Chem Int Ed Engl 46:1222–1244CrossRefGoogle Scholar
  24. Ma X, Wang J, Sun M, Wang W, Wu Q, Wang C, Wang Z (2013) Magnetic solid-phase extraction of neonicotinoid pesticides from pear and tomato samples using graphene grafted silica-coated Fe3O4 as the magnetic adsorbent. Anal Methods 5:2809–2815CrossRefGoogle Scholar
  25. Mahendran V (2012) Nanofluid based opticalsensor for rapid visual inspection of defects in ferromagnetic materials. Appl Phys Lett 100:073104CrossRefGoogle Scholar
  26. Mornet S, Vasseur S, Grasset F, Veverka P, Goglio G, Demourgues A, Portier J, Pollert E, Duguet E (2006) Magnetic nanoparticle design for medical applications. Prog Solid State Chem 34:237–247CrossRefGoogle Scholar
  27. Nathan MGT, Suganya R (2018) Investigation of the morphological and magnetic properties of Fe3O4 nanoparticles for biomedical applications. Int J Pure Appl Math 119:6515–6524Google Scholar
  28. Nodeh HR, Ibrahim WAW, Kamboha MA, Sanagi MM (2015) Dispersive graphene-based silica-coated magnetic nanoparticles as a new adsorbent for preconcentration of chlorinated pesticides from environmental water. RSC Adv 5:76424–76434CrossRefGoogle Scholar
  29. Noori AH, Rezaee M, Kazemipour M, Mashayekhi HA (2017) Simultaneous determination of permethrin and deltamethrin in water samples by magnetic solid-phase extraction coupled with dispersive liquid-liquid microextraction combined with gas chromatography. S Afr J Chem 70:200–208CrossRefGoogle Scholar
  30. Ozcan S, Tor A, Aydin ME (2012) Application of magnetic nanoparticles to residue analysis of organochlorine pesticides in water samples by GC/MS. J AOAC Int 95:1343–1348CrossRefGoogle Scholar
  31. Perez JAL, Quintela MAL, Mira J, Rivas J, Charles SW (1997) Advances in the preparation of magnetic nanoparticles by the microemulsion method. J Phys Chem 101(41):8045–8047CrossRefGoogle Scholar
  32. Philip J, Raj SPDB (2006) Nanofluid with tunable thermal properties. Appl Phys Lett 92:043108CrossRefGoogle Scholar
  33. Philip J, Kumar TJ, alyanasundaram PK, Raj B (2003) Tunable optical filter. Meas Sci Technol 14:1289–1294CrossRefGoogle Scholar
  34. Philip J, Mahendran V, Felicia L (2013) A simple, in-expensive and ultrasensitive magnetic nanofluid based sensor for detection of cations, ethanol and ammonia. J Nanofluids 2:112–119CrossRefGoogle Scholar
  35. Prasad R, Kumar V, Prasad KS (2014) Nanotechnology in sustainable agriculture: present concerns and future aspects. Afr J Biotechnol 13(6):705–713Google Scholar
  36. Prasad R, Bhattacharyya A, Nguyen QD (2017) Nanotechnology in sustainable agriculture: Recent developments, challenges, and perspectives. Front Microbiol 8:1014.  https://doi.org/10.3389/fmicb.2017.01014
  37. Qiu JD, Xiong M, Liang RP, Peng HP, Liu F (2009) Synthesis and characterization of ferrocene modified Fe3O4@Au magnetic nanoparticles and its application. Biosens Bioelectron 24:2649–2653CrossRefGoogle Scholar
  38. Rahman IA, Padavettan V (2012) Synthesis of silica nanoparticles by sol-gel: size-dependent properties, surface modification and applications in silica-polymer nanocomposites-a review. J Nanomater 2:112–119Google Scholar
  39. Ramaswamy B, Kulkarni SD, Villar PS, Smith RS, Eberly C, Araneda RC, Depireux DA, Shapiro B (2015) Movement of magnetic nanoparticles in brain tissue: mechanisms and safety. Nanomed Nanotech Biol Med 11:1821–1829CrossRefGoogle Scholar
  40. Sadegh H, Zare K, Maazinejad B, Shahryari-ghoshekandia R (2006) Synthesis of MWCNT-COOH-Cysteamine composite and its application for dye removal. J Mol Liq 215:221–228CrossRefGoogle Scholar
  41. Saeidi M, Naeimi A, Komeili M (2016) Magnetite nanoparticles coated with methoxy polyethylene glycol as an efficient adsorbent of diazinon pesticide from water. Adv Environ Technol 1:25–31Google Scholar
  42. Salazar S, Guerra D, Yutronic N, Jara P (2018) Removal of aromatic chlorinated pesticides from aqueous solution using β-cyclodextrin polymers decorated with Fe3O4 nanoparticles. Polymers 10:1038CrossRefGoogle Scholar
  43. Shaw SY, Chen YJ, Ou JJ, Ho L (2006) Preparation and characterization of Pseudomonas putida esterase immobilized on magnetic nanoparticles. Enzym Microb Technol 39:1089–1095CrossRefGoogle Scholar
  44. Shen HY, Zhu Y, Wen XE, Zhuang YM (2007) Preparation of Fe3O4-C18 nano-magnetic composite materials and their cleanup properties for organophosphorous pesticides. Anal Bioanal Chem 387:2227–2237CrossRefGoogle Scholar
  45. Tang SCN, Lo IMC (2013) Magnetic nanoparticles: essential factors for sustainable environmental applications. Water Res 47:2613–2632CrossRefGoogle Scholar
  46. Tian M, Chen DX, Sun YL, Yang YW, Jia Q (2013) Pillararene-functionalized Fe3O4 nanoparticles as magnetic solid-phase extraction adsorbent for pesticide residue analysis in beverage samples. RSC Adv 3:22111–22119CrossRefGoogle Scholar
  47. Uchida M, Flenniken ML, Allen M, Willits DA, Crowley BE, Brumfield S, Willis AF, Jackiw L, Jutila M, Young MJ, Douglas T (2006) Targeting of cancer cells with ferrimagnetic ferritin cage nanoparticles. J Am Chem Soc 128:16626–16633CrossRefGoogle Scholar
  48. Wang C, Irudayaraj J (2010) Multifunctional magnetic–optical nanoparticle probes for simultaneous detection, separation, and thermal ablation of multiple pathogens. Inter Sci 6:283–289Google Scholar
  49. Wang X, Zhuang J, Peng Q, Li Y (2005) A general study for nanocrystal synthesis. Nature 437:121–124CrossRefGoogle Scholar
  50. Wanjeri VWO, Sheppard CJ, Prinsloo ARE, Ngila JC, Ndungu PG (2018) Isotherm and kinetic investigations on the adsorption of organophosphorus pesticides on graphene oxide based silica coated magnetic nanoparticles functionalized with 2-phenylethylamine. J Environ Chem Eng 6:1333–1346CrossRefGoogle Scholar
  51. Woo K, Lee HJ, Ahn JP, Park YS (2003) Sol-gel mediated synthesis of Fe2O3 nanorods. Adv Mater 15:1761–1764CrossRefGoogle Scholar
  52. Wu Q, Zhao G, Feng C, Wang C, Wang Z (2011) Preparation of a graphene-based magnetic nanocomposite for the extraction of carbamate pesticides from environmental water samples. Chromatography 1218:7936–7942CrossRefGoogle Scholar
  53. Yantasee W, Warner CL, Sangvanich T, Addleman RS, Carter TG, Wiacek RJ, Warner MG (2007) Removal of heavymetals from aqueous systems with thiol functionalized superparamagnetic nanoparticles. Environ Sci Technol 4:5114–5119CrossRefGoogle Scholar
  54. Yao GH, Liang RP, Huang CF, Wang Y, Qiu JD (2013) Surface plasmon resonance sensor based on magnetic molecularly imprinted polymers amplification for pesticide recognition. Anal Chem 85(24):11944–11951CrossRefGoogle Scholar
  55. Yin B, Ma H, Wang S, Chen S (2003) Electrochemical synthesis of silver nanoparticles under protection of poly(N-vinylpyrrolidone). J Phys Chem 107:8898–8904CrossRefGoogle Scholar
  56. Yang T, Shen C, Yang H, Xiao C, Xu Z, Chen S, Shi D, Gao H (2006) Synthesis, characterization and self-assemblies of magnetite nanoparticles. Surf Interf Ana 38:1063–1067Google Scholar
  57. Zamora-Galvez A, Mayorga-Matinez CC, Parolo C, Pons J, Merkoci A (2017) Magnetic nanoparticle-molecular imprinted polymer: a new impedimetric sensor for tributyltin detection. Electrochem Commun 82:6–11CrossRefGoogle Scholar
  58. Zeng Q, Baker I, Loudis JA, Liao Y, Hoopes PJ, Weaver JB (2007) Fe/Fe oxide nanocomposite particles with large specific absorption rate (SAR) for hyperthermia. Appl Phys Lett 90:233112–233114CrossRefGoogle Scholar
  59. Zhang S, Zhang H, Chen D (2015) Preparation and application of Fe3O4 magnetic nanoparticles graphene sheet in the magnetic solid-phase extraction of organochiorine pesticides from water. J Chem Pharm Res 7:1378–1383Google Scholar
  60. Zhao Q, Lu Q, Feng YQ (2013) Dispersive microextraction based on magnetic polypyrrole nanowires for the fast determination of pesticide residues in beverage and environmental water samples. Anal Bioanal Chem 405:4765–4776CrossRefGoogle Scholar

Copyright information

© Springer Nature Switzerland AG 2019

Authors and Affiliations

  • Kamlesh Shrivas
    • 1
  • Sanyukta Patel
    • 2
  • Pathik Maji
    • 3
  • Deepak Sinha
    • 2
  1. 1.School of Studies in ChemistryPt. Ravishankar Shukla UniversityRaipurIndia
  2. 2.Department of ChemistryGovernment Nagarjuna Post Graduate College of ScienceRaipurIndia
  3. 3.Department of ChemistryGuru Ghasidas VishwavidyalayaBilaspurIndia

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