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Microwave-Assisted Hydrothermal Synthesis of Agglomerated Spherical Zirconium Phosphate for Removal of Cs+ and Sr2+ Ions from Aqueous System

  • Arshid Bashir
  • Lateef Ahmad Malik
  • G. N. Dar
  • Altaf Hussain PandithEmail author
Chapter

Abstract

Crystalline and agglomerated spherical alpha zirconium phosphate nanoparticles hereafter α-ZrP were synthesized by a facile and rapid microwave-hydrothermal (MW-HT) approach within 30 min at 120 °C in the absence of any complexing or structure directing agent (SDA). The material was characterized by Fourier-transform infrared (FT-IR), powdered X-ray diffraction (PXRD), scanning electron microscopy (SEM), energy dispersive spectroscopic analysis (EDS) and surface area analysis (BET). It crystallizes in the monoclinic P121/n1 space group with the following cell parameters: a = 5.288, b = 9.174, c = 15.384 Å and β = 102.384. Crystallite sizes in the range 3–4 nm evaluated using Scherer equation were obtained for α-ZrP. Ion exchange performance of α-ZrP towards removal of Cs+ and Sr2+ ions was examined under noncompetitive batch conditions. Distribution studies indicate higher selectivity of α-ZrP towards Sr2+ uptake (Kd ca. 4.3 × 104) in comparison with Cs+ (Kd ca. 2.4 × 103). This study suggested to agglomerated α-ZrP as potential adsorbent for the removal of radioactive Sr2+ from acidic wastewater.

List of abbreviations

AAS

Atomic absorption spectroscopy

BET

Surface area analysis

CP

Co-precipitation

DFT

Density functional theory

EDS

Energy dispersive spectroscopic analysis

FT-IR

Fourier transform infrared

IEC

Ion exchange capacity

Kd

Distribution coefficient

MW-HT

Microwave hydrothermal

PXRD

Powdered X-ray diffraction

PZC

Point of zero charge

SDA

Structure directing agents

SEM

Scanning electron microscopy

ZrP

Zirconium Phosphate

Notes

Acknowledgements

We thank the Head Department of Chemistry, the University of Kashmir for providing all the necessary facilities to carry out this work. We would also like to thank Mainak Roy and S. N. Achary, Chemistry Division, BARC, Mumbai for their help with PXRD and FT-IR studies. A. B. would like to thank the Council of Scientific and Industrial Research (CSIR), GOI, for financial assistance in the form of a Junior Research Fellowship (JRF). G. N. thanks the DST, GOI, for a research grant for carrying out this work.

References

  1. 1.
    Rahman ROA, Ibrahium HA, Hung YT (2011) Liquid radioactive wastes treatment: a review. Water 3:551–565CrossRefGoogle Scholar
  2. 2.
    Paulus WJ, Komarneni S, Roy R (1992) Bulk synthesis and selective exchange of strontium ions in Na4Mg6 Al4 Si4O20F4 mica. Nature 357:571–573CrossRefGoogle Scholar
  3. 3.
    Sun JM, Shang C, Huang JC (2003) Co-removal of hexavalent chromium through copper precipitation in synthetic wastewater. Environ Sci Technol 37:4281–4287CrossRefGoogle Scholar
  4. 4.
    Abdelfattah I, Ismail AA, Sayed FA et al (2016) Biosorption of heavy metals ions in real industrial wastewater using peanut husk as efficient and cost effective adsorbent. Environ Nanotech Monit Manag 6:176–183CrossRefGoogle Scholar
  5. 5.
    Boccelli DL, Small MJ, Dzombak D (2005) Enhanced coagulation for satisfying the arsenic maximum contaminant level under variable and uncertain conditions. Environ Sci Technol 39:6501–6507CrossRefGoogle Scholar
  6. 6.
    Vergili I, Kaya Y, Sen U et al (2012) Techno-economic analysis of textile dye bath wastewater treatment by integrated membrane processes under the zero liquid discharge approach. Resour Conserv Recycl 58:25–35CrossRefGoogle Scholar
  7. 7.
    Jawor A, Hoek EMV (2010) Removing cadmium ions from water via nanoparticle-enhanced ultrafiltration. Environ Sci Technol 44:2570–2576CrossRefGoogle Scholar
  8. 8.
    Abdolali A, Ngo HH, Guo W et al (2016) A breakthrough biosorbent in removing heavy metals: equilibrium, kinetic, thermodynamic and mechanism analyses in a lab-scale study. Sci Total Environ 542:603–611CrossRefGoogle Scholar
  9. 9.
    Cheng Y, Wang XD, Jaenicke S et al (2018) Mechanochemistry-based synthesis of highly crystalline γ-zirconium phosphate for selective ion exchange. Inorg Chem 57:4370–4378CrossRefGoogle Scholar
  10. 10.
    Wen T, Zhao Z, Shen C et al (2016) Multifunctional flexible free-standing titanate nanobelt membranes as efficient sorbents for the removal of radioactive 90Sr2+and 137Cs+ions and oils. Sci. Rep. 6, 20920.  https://doi.org/10.1038/srep20920
  11. 11.
    Xiao X, Hayashi F, Shiiba H et al (2016) Platy KTiNbO5 as a selective Sr ion adsorbent: crystal growth, adsorption experiments, and DFT calculations. J Phys Chem C 120:11984–11992CrossRefGoogle Scholar
  12. 12.
    Mertz JL, Fard ZH Kanatzidi MG et al (2013) Selective removal of Cs+,Sr2+ and Ni2+ by K2xMgxSn3−x S6(x = 0.5 − 1) (KMS-2) relevant to nuclear waste remediation. J Chem Mater 25:2116–2127Google Scholar
  13. 13.
    Manos MJ, Kanatzidis MG (2016) Metal sulfide ion exchangers: superior sorbents for the capture of toxic and nuclear waste-related metal ions. Chem Sci 7:4804–4824CrossRefGoogle Scholar
  14. 14.
    Zhu Y, Shimizu T, Kitajima T (2014) Synthesis of robust hierarchically porous zirconium phosphate monolith for efficient ion adsorption. New J Chem.  https://doi.org/10.1039/c4nj01749hCrossRefGoogle Scholar
  15. 15.
    He W, Ai K, Ren X et al (2017) Inorganic layered ion-exchangers for decontamination of toxic metal ions in aquatic systems. J Mater Chem A 5:19593–19606CrossRefGoogle Scholar
  16. 16.
    Mrad O, Abdul-Hadi A, Arsan H (2011) Preparation and characterization of three different phases of zirconium phosphate: study of the sorption of 234Th,238U, and134 Cs. J Radioanal Nucl Chem 287:177–183CrossRefGoogle Scholar
  17. 17.
    Bashir A, Ahad S, Pandith AH (2016) Soft template assisted synthesis of zirconium resorcinol phosphate nanocomposite material for the uptake of heavy-metal ions. Ind Eng Chem Res 55:4820–4848CrossRefGoogle Scholar
  18. 18.
    Varshney KG, Pandith AH, Gupta U (1998) Synthesis and characterization of zirconium alumino phosphate: a new cation exchanger. Langmuir 14:7353–7358CrossRefGoogle Scholar
  19. 19.
    Mu W, Yu Q, Zhang R et al (2017) Controlled fabrication of flower-like α-zirconium phosphate for the efficient removal of radioactive strontium from acidic nuclear wastewater. J Mater Chem A 5:24388–24395CrossRefGoogle Scholar
  20. 20.
    Mosby BM, Goloby Clearfield A et al (2014) Designable architectures on nanoparticle surfaces: zirconium phosphate nanoplatelets as a platform for tetravalent metal and phosphonic acid assemblies. Langmuir 30:2513–2521CrossRefGoogle Scholar
  21. 21.
    Hajipour AR, Karimi H (2014) Synthesis and characterization of hexagonal zirconium phosphate nanoparticles. Mater Lett 116:356–358CrossRefGoogle Scholar
  22. 22.
    Bellezza F, Cipiciani A, Costantino U et al (2006) Zirconium phosphate nanoparticles from water-in-oil microemulsion. Colloid Polym Sci 285:19–25CrossRefGoogle Scholar
  23. 23.
    Shuai M, Mejia AF, Chang YW et al (2013) Hydrothermal synthesis of layered α-zirconium phosphate disks: control of aspect ratio and polydispersity for nano-architecture. Cryst Eng Comm 15:1970–1977CrossRefGoogle Scholar
  24. 24.
    Smeets S, Liu L, Dong (2015) Ionothermal synthesis and structure of a new layered zirconium phosphate. J Inorg Chem 54:7953–7958CrossRefGoogle Scholar
  25. 25.
    Cheng Y, Wang X, Jaenicke S et al (2017) Minimalistic liquid-assisted route to highly crystalline α-zirconium phosphate. Chem Sus Chem.  https://doi.org/10.1002/cssc.201700885CrossRefGoogle Scholar
  26. 26.
    Muraliganth T, Murugan A V and Manthiram A (2009) Facile synthesis of carbon-decorated single-crystalline Fe3O4 nanowires and their application as high performance anode in lithium ion batteries. Chem Commun:7360–7362Google Scholar
  27. 27.
    Pica M, Nocchetti M, Ridolfi B et al (2010) Nanosized zirconium phosphate/AgCl composite materials: a new synergy for efficient photocatalytic degradation of organic dye pollutants. J Mater Chem A 3:5525–5534CrossRefGoogle Scholar
  28. 28.
    Culity BD (1976) Elements of X-ray diffraction. Addison-Wesly Publishing Co. Inc. (Chapter 14)Google Scholar
  29. 29.
    Zhang Q, Du Q, Jiao T et al (2013) Selective removal of phosphate in waters using a novel cation adsorbent: zirconium phosphate(ZrP) behavior and mechanism. J Chem Eng 221:315–321CrossRefGoogle Scholar
  30. 30.
    Horsley SE, Nowell DV, Stewart DT (1974) The infrared and raman spectra of α -zirconium phosphate. Spectrochim Acta Part A Mol Spectrosc 30:535–541CrossRefGoogle Scholar
  31. 31.
    Troup JM, Clearfield A (1977) On the mechanism of ion exchange in zirconium phosphates. 20. Refinement of the crystal structure of a-zirconium phosphate. Inorg Chem 16:12, 197Google Scholar
  32. 32.
    Kalita H, Rajput S, Kumar BNP et al (2016) Fe3O4@zirconium phosphate core–shell nanoparticles for pH-sensitive and magnetically guided drug delivery applications. RSC Adv 6:21285–21292CrossRefGoogle Scholar
  33. 33.
    Gatabia MP, Moghaddam HM, Ghorbani M (2016) Point of zero charge of maghemite decorated multiwalled carbon nanotubes fabricated by chemical precipitation method. J Mol Liq 216:117–125CrossRefGoogle Scholar
  34. 34.
    Ahad S, Islam N Pandith AH et al (2015) Adsorption studies of Malachite green on 5-sulphosalicylic acid doped tetraethoxysilane (SATEOS) composite material. RSC Adv 5:92788–92798CrossRefGoogle Scholar
  35. 35.
    Inamuddin, Khan SA, Siddiqui WA et al (2007) Synthesis, characterization and ion-exchange properties of a new and novel ‘organic–inorganic’ hybrid cation exchanger: Nylon-6,6, Zr(IV) phosphate. Talanta 71:841–847CrossRefGoogle Scholar
  36. 36.
    Ahad S, Bashir A, Pandith AH et al (2016) Exploring the ion exchange and separation capabilities of thermally stable acrylamide zirconium(IV) sulphosalicylate (AaZrSs) composite material. RSC Adv 6:35914–35927CrossRefGoogle Scholar
  37. 37.
    Zhao J, Islam SM, Kanatzidis MG et al (2017) Homologous series of 2D chalcogenides Cs − Ag − Bi − Q (Q = S, Se) with ion-exchange properties. J Am Chem Soc 139:12601–12609CrossRefGoogle Scholar
  38. 38.
    Wang L, Xu WH, Yang R et al (2013) Electrochemical and density functional theory investigation on high selectivity and sensitivity of exfoliated nano-zirconium phosphate toward lead(II). J Anal Chem 85:3984–3990CrossRefGoogle Scholar

Copyright information

© Springer Nature Switzerland AG 2019

Authors and Affiliations

  • Arshid Bashir
    • 1
  • Lateef Ahmad Malik
    • 1
  • G. N. Dar
    • 2
  • Altaf Hussain Pandith
    • 1
    Email author
  1. 1.Department of ChemistryUniversity of KashmirHazratbal, SrinagarIndia
  2. 2.Department of PhysicsUniversity of KashmirHazratbal, SrinagarIndia

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