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Properties of ZnO Micro/Nanostructures on Aluminum Substrates

  • Shadia J. IkhmayiesEmail author
  • Hassan K. Juwhari
  • Bashar Lahlouh
Conference paper
Part of the The Minerals, Metals & Materials Series book series (MMMS)

Abstract

Zinc oxide (ZnO) micro/nanostructures were produced as thin films on aluminum substrates using the spray pyrolysis method at a substrate temperature Ts = 350 ± 5 °C. The films were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM) that is supported by energy dispersive spectroscopy (EDS), and X-ray fluorescence (XRF). The films displayed hexagonal structure as shown in the XRD diffractograms and SEM observations. XRD diffractograms showed that the strongest reflection is that from the (002) plane, which means the preferred direction of crystal growth, is along the c-axis, perpendicular to the substrates. From the SEM images, it is found that the films have hexagonal micro/nanorods structure. EDS and XRF detected the presence of Zn, O, and other impurities in the films. A future study of the optical and electronic properties is necessary to examine the potential of using such films in optoelectronic industry and other technologies.

Keywords

Zinc oxide Micro/nanorods Spray pyrolysis XRD SEM XRF 

References

  1. 1.
    Muchuweni E, Sathiaraj TS, Nyakotyo H (2017) Synthesis and characterization of zinc oxide thin films for optoelectronic applications. Heliyon 3:e00285.  https://doi.org/10.1016/j.heliyon.2017.e00285CrossRefGoogle Scholar
  2. 2.
    Elhamali SO, Cranton WM, Kalfagiannis N, Hou X, Ranson R, Koutsogeorgis DC (2016) Enhanced electrical and optical properties of room temperature deposited aluminium doped zinc oxide (AZO) thin films by excimer laser annealing. Opt Lasers Eng 80:45–51CrossRefGoogle Scholar
  3. 3.
    Huang XH, Wu JB, Lin Y, Guo RQ (2012) ZnO microrod arrays grown on copper substrates as anode materials for lithium ion batteries. Int J Electrochem Sci 7:6611–6621Google Scholar
  4. 4.
    Choi WS, Kim EJ, Seong SG, Kim YS, Park C, Hahn SH (2009) Optical and structural properties of ZnO/TiO2/ZnO multi-layers prepared via electron beam evaporation. Vacuum 83:878–882CrossRefGoogle Scholar
  5. 5.
    Hamada T, Fujii E, Chu D, Kato K, Masuda Y (2011) Aqueous synthesis of single-crystalline ZnO prisms on graphite substrates. J Cryst Growth 314:180–184CrossRefGoogle Scholar
  6. 6.
    Nunes P, Costa D, Fortunato E, Martins R (2002) Performances presented by zinc oxide thin films deposited by r.f. magnetron sputtering. Vacuum 64:293–297CrossRefGoogle Scholar
  7. 7.
    Caglar M, Ilican S, Caglar Y, Yakuphanoglu F (2009) Electrical conductivity and optical properties of ZnO nano structured thin film. Appl Surf Sci 255:4491–4496CrossRefGoogle Scholar
  8. 8.
    Hossain MF, Zhang ZH, Takahashi T (2010) Novel micro-ring structured ZnO photoelectrode for dye-sensitized solar cell. Nano-Micro Lett 2:53–55CrossRefGoogle Scholar
  9. 9.
    Ikhmayies SJ (2016) Synthesis of ZnO microrods by the spray pyrolysis technique. J Electron Mater 45(8):3964–3969CrossRefGoogle Scholar
  10. 10.
    Ikhmayies SJ, Abu El-Haija NM, Ahmad-Bitar RN (2010) Electrical and optical properties of ZnO:Al thin films prepared by the spray pyrolysis technique. Phys Scr 81:015703 (5 pp)CrossRefGoogle Scholar
  11. 11.
    Ikhmayies SJ, Abu El-Haija NM, Ahmad-Bitar RN (2010) Characterization of undoped spray-deposited ZnO thin films of photovoltaic applications. FDMP 6(2):165–177Google Scholar
  12. 12.
    Ikhmayies SJ, Abu El-Haija NM, Ahmad-Bitar RN (2015) A comparison between different ohmic contacts for ZnO thin films. J. Semicond. 36(3):033005 (5 pp)CrossRefGoogle Scholar
  13. 13.
    Ikhmayies SJ, Abu El-Haija NM, Ahmad-Bitar RN (2010) The influence of annealing in nitrogen atmosphere on the electrical, optical and structural properties of spray-deposited ZnO thin films. FDMP 6(2):219–232Google Scholar
  14. 14.
    Ikhmayies SJ, Zbib MB (2018) Synthesis of ZnO hexagonal prisms on aluminum substrates by the spray pyrolysis technique. In: Sayigh A (ed) Transition towards 100% renewable energy, innovative renewable energy. Springer, pp 177–186Google Scholar
  15. 15.
    Ikhmayies SJ (2018) ZnO thin films of flowered-fibrous micro/nanowebs on glass substrates using the spray pyrolysis method. In: Li B, Li J, Ikhmayies S, Zhang M, Kalay YE, Carpenter JS, Hwang J-Y, Monteiro SN, Firrao D, Brown A, Bai C, Peng Z, Escobedo-Diaz JP, Goswami R, Kim J (eds) Characterization of minerals, metals, and materials 2018, pp 209–215Google Scholar
  16. 16.
    Lahlouh BI, Ikhmayies SJ, Juwhari KH (2018) Structural, optical, and vibrational properties of ZnO microrods deposited on silicon substrate. J Electron Mater 47(8):4455–4462CrossRefGoogle Scholar
  17. 17.
    Ikhmayies SJ, Zbib MB (2017) Spray pyrolysis synthesis of ZnO micro/nano rods on glass substrates. J Electron Mater 46(10):5629–5634CrossRefGoogle Scholar
  18. 18.
    Ikhmayies SJ (2017) Formation of three dimensional ZnO micro flowers from self assembled ZnO micro discs. Metall Mater Trans A 48(8):3625–3629CrossRefGoogle Scholar
  19. 19.
    Ikhmayies SJ, Zbib MB (2017) Synthesis of ZnO hexagonal micro discs on glass substrates using the spray pyrolysis technique. J Electron Mater 46(7):3982–3986CrossRefGoogle Scholar
  20. 20.
    Juwhari KH, Ikhmayies SJ, Lahlouh BI (2017) Room temperature photoluminescence of spray-deposited ZnO thin films on glass substrates. Int J Hydrog Energ 42(28):17741–17747CrossRefGoogle Scholar
  21. 21.
    Muchuweni E, Sathiaraj TS, Nyakotyo H (2016) Effect of gallium doping on the structural, optical and electrical properties of zinc oxide thin films prepared by spray pyrolysis. Ceram Int 42:10066–10070CrossRefGoogle Scholar
  22. 22.
    Schneider CA, Rasband WS, Eliceiri KW (2012) NIH Image to ImageJ: 25 years of image analysis. Nat Methods 9(7):671–675CrossRefGoogle Scholar
  23. 23.
    Schindelin J, Rueden CT, Hiner MC, Eliceiri KW (2015) The imageJ ecosystem: an open platform for biomedical image analysis. Mol Reprod Dev 82(7–8):518–529CrossRefGoogle Scholar
  24. 24.
    McMurdie HF, Morris M, Evans E, Paretzkin B, Wong-Ng W, Ettlinger L, Hubbard C (1986) Powder Diffr 1:76. (JCPDS file 36-1451)Google Scholar
  25. 25.
    Shannon RD (1976) Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Cryst A 32:751–767CrossRefGoogle Scholar
  26. 26.
    Tüzemen EŞ Kavak H, Esen R (2007) Influence of oxygen pressure of ZnO/glass substrate produced by pulsed filtered cathodic vacuum arc deposition. Phys B Condens Matter 390:366–372Google Scholar
  27. 27.
    Wang YG, Lau SP, Lee HW, Yu SF, Tay BK, Zhang XH, Tse KY, Hng HH (2003) Comprehensive study of ZnO films prepared by filtered cathodic vacuum arc at room temperature. J Appl Phys 94:1597–1604CrossRefGoogle Scholar
  28. 28.
    Aksoy S, Caglar Y, Ilican S, Caglar M (2010) Effect of deposition temperature on the crystalline structure and surface morphology of ZnO films deposited on p–Si. Adv Control Chem Eng Civ Eng Mech Eng:227–231Google Scholar
  29. 29.
    Seetawan U, Jugsujinda S, Seetawan T, Ratchasin A, Euvananont C, Junin C, Thanachayanont C, Chainaronk P (2011) Effect of calcinations temperature on crystallography and nanoparticles in ZnO disk. Mater Sci Appl 2:1302–1306Google Scholar

Copyright information

© The Minerals, Metals & Materials Society 2019

Authors and Affiliations

  • Shadia J. Ikhmayies
    • 1
    Email author
  • Hassan K. Juwhari
    • 2
  • Bashar Lahlouh
    • 2
  1. 1.Faculty of Science, Physics DepartmentIsra UniversityAmmanJordan
  2. 2.Department of Physics, School of ScienceUniversity of JordanAmmanJordan

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