Feasibility Study of the Internal Zr/ZrO2 Reference Electrodes in Supercritical Water Environments

  • Yu-Hsuan Li
  • Yu-Ming Tung
  • Tsung-Kuang Yeh
  • Mei-Ya WangEmail author
Conference paper
Part of the The Minerals, Metals & Materials Series book series (MMMS)


A specifically designed reference electrode was developed for analyzing the electrochemical behaviors of alloy materials in supercritical water (SCW) environments and identifying the associated electrochemical parameters. The internal Zr/ZrO2 reference electrodes constructed for high-temperature conditions were manufactured and adopted to measure the electrochemical corrosion potential (ECP) of the sample in SCW environments. Before the electrochemical analysis, the oxidation behaviour of zirconium would be investigated in SCW environment. The mass gain of zirconium is assumed due to formation of ZrO2 and there was only 78% of the original thickness of zirconium existed after the 1300 h immersion test in SCW environments with 8.3 ppm dissolved oxygen. In deaerated SCW environments, the thickness of zirconium is about 88% of the original one. The outcome indicated that the laboratory-made Zr/ZrO2 reference electrode was able to continuously operate for several months and delivered consistent and steady ECP data of the sample in SCW environments.


Supercritical water Electrochemical corrosion potential Reference electrode 


  1. 1.
    GEN IV International Forum, GIF 2007 Annual Report, pp. 7–11 (2007)Google Scholar
  2. 2.
    A Technology Roadmap for Generation IV Nuclear Energy Systems, Report No. GIF002-00, 1 Dec 2002Google Scholar
  3. 3.
    G.S. Was, S. Teysseyre, Z. Jiao, Corrosion of austenitic alloys in supercritical water. Corrosion 62(11), 989–1005 (2006)CrossRefGoogle Scholar
  4. 4.
    P. Kritzer, Corrosion in High-Temperature and Supercritical Water and Aqueous Solutions: Influence of Solution and Materials Parameters. SCR, Nov 6–8 (Tokyo, Japan, 2000)Google Scholar

Copyright information

© The Minerals, Metals & Materials Society 2019

Authors and Affiliations

  • Yu-Hsuan Li
    • 1
  • Yu-Ming Tung
    • 2
  • Tsung-Kuang Yeh
    • 1
    • 2
  • Mei-Ya Wang
    • 3
    Email author
  1. 1.Institute of Nuclear Engineering and ScienceNational Tsing Hua UniversityHsinchu CityTaiwan
  2. 2.Department of Engineering and System ScienceNational Tsing Hua UniversityHsinchu CityTaiwan
  3. 3.Nuclear Science and Technology Development CenterNational Tsing Hua UniversityHsinchu CityTaiwan

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