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  • Priyabrata GhanaEmail author
Chapter
Part of the Springer Theses book series (Springer Theses)

Abstract

The present work has demonstrated that open-shell tetrylidyne complexes featuring a tetrel-centered unpaired electron can be obtained by one-electron reduction of corresponding closed-shell tetrylidyne complexes. Examples included the first germylidyne radical anion salt K(THF)3[Tp′(CO)2MoGe(C6H3-2,6-Mes2)] (18-Mo) and the neutral stannylidyne radical trans-[H(dmpe)2MnSn(C6H3-2,6-Mes2)] (43).

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© Springer Nature Switzerland AG 2019

Authors and Affiliations

  1. 1.Institute für Anorganische ChemieRheinische Friedrich-Wilhelms-Universität BonnBonnGermany

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