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Is There an Analogy Between Jahn-Teller Effect and an Instability of Spin Populations in Kramers Clusters with Odd Number of Atoms?

  • Ion I. Geru
Chapter
Part of the Springer Tracts in Modern Physics book series (STMP, volume 281)

Abstract

The molecules and molecular clusters of high symmetry with orbital degeneracy of the ground state are unstable with respect to a weak structural deformation due to Jahn-Teller effect. In the Sect. 7.1 is discussed the possibility for existence of an analogical effect of instability of spin populations of the trihomonuclear magnetic cluster with respect to a weak structural deformation (the Kahn’s instability) in the case when each of three ions of the cluster has the spin \(S=1/2\).

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© Springer Nature Switzerland AG 2018

Authors and Affiliations

  1. 1.Institute of ChemistryAcademy of Sciences of MoldovaChisinauMoldova

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