Surface Raman Spectroscopy

  • W. Suëtaka
  • John T. YatesJr.
Part of the Methods of Surface Characterization book series (MOSC, volume 3)

Abstract

Raman scattering, an inelastic scattering of photons by chemical entities, is widely utilized for the investigation of the structure of molecules, crystals, and polymer materials.(1–5) The cross section of normal Raman scattering, however, is low for observing surface species, and most surface Raman experiments were confined to porous or finely divided inorganic materials until recently.(6,7) Before the discovery of surface enhanced Raman scattering (SERS), resonance Raman scattering(8,9) was employed for the most part in the observation of bulk solid surfaces.(10)

Keywords

Raman Spectrum Raman Spectroscopy Surface Enhance Raman Scattering Raman Scattering Raman Band 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    T.R. Gilson and P.J. Hendra, Laser Raman Spectroscopy, Wiley, New York (1970).Google Scholar
  2. 2.
    J.A. Koningstein, Introduction to the Theory of the Raman Effect, Reidel, Dordrecht, Holland (1972).Google Scholar
  3. 3.
    D.A. Long, Raman Spectroscopy, McGraw-Hill, New York (1977).Google Scholar
  4. 4.
    J.G. Grasselli, M.K. Snavely, and B.J. Bulkin, Chemical Applications of Raman Spectroscopy, Wiley, New York (1981).Google Scholar
  5. 5.
    D.P. Strommen and K. Nakamoto, Laboratory Raman Spectroscopy, Wiley, New York (1985).Google Scholar
  6. 6.
    W. Krasser and A.J. Renouprez, J. Raman Spectrosc. 8, 92 (1979).Google Scholar
  7. 7.
    P.P. Yaney and R.J. Becker, Appl. Surf. Sci. 4, 356 (1980).Google Scholar
  8. 8.
    J. Tang and A.C. Albrecht, in: Raman Spectroscopy: Theory and Practice, Vol. 2 (H.A. Szymanski, ed.), Plenum, New York (1970), p. 33.Google Scholar
  9. 9.
    R.J.H. Clark, in: Advances in infrared and Raman Spectroscopy, Vol. 1 (R.J.H. Clark and R.E. Hester, eds.), Heyden, London (1976).Google Scholar
  10. 10.
    H. Yamada, Appl. Spectrosc. Rev. 17, 227 (1981).Google Scholar
  11. 11.
    A. Campion, in: Vibrational Spectroscopy of Molecules on Surfaces (J.T. Yates, Jr. and T.E. Madey, eds.), Plenum, New York (1987), p. 345.Google Scholar
  12. 12.
    A. Campion, J. Electron Spectrosc. Relat. Phenom. 54/55, 877 (1990).Google Scholar
  13. 13.
    J.A. Koningstein and B.F. Gächter, J. Opt. Soc. Am. 63, 892 (1973).Google Scholar
  14. 14.
    H. Yamada and Y. Yamamoto, J. Raman Spectrosc. 9, 401 (1980).Google Scholar
  15. 15.
    P. J. Hendra, ed., Spectrochim. Acta 46A (1990).Google Scholar
  16. 16.
    R.G. Greenler and T.L. Siager, Spectrochim. Acta 29A, 193 (1973).Google Scholar
  17. 17.
    D.R. Mullins and A. Campion, J. Phys. Chem. 88, 8 (1984).Google Scholar
  18. 18.
    M. Ohsawa, W. Kusakari, and W. Suëtaka, Spectrochim. Acta 36A, 389 (1980).Google Scholar
  19. 19.
    Z. Lenac and M.S. Tomaš, J. Raman Spectrosc. 22, 831 (1991).Google Scholar
  20. 20.
    M. Moskovits, J. Chem. Phys. 77, 4408 (1982).Google Scholar
  21. 21.
    V.M. Hallmark and A. Campion, J. Chem. Phys. 84, 2933, 2942 (1986).Google Scholar
  22. 22.
    T. Ikeshoji, Y. Ono, and T. Mizuno, Appl. Opt. 12, 2236 (1973).Google Scholar
  23. 23.
    K.H. Redel, D. Spenkuch, and G.R. Wessler, Opt. Spectrosc. 38, 649 (1975).Google Scholar
  24. 24.
    M. Fujihara and T. Osa, J. Am. Chem. Soc. 98, 7850 (1976).Google Scholar
  25. 25.
    W. Carious and O. Schrötter, Z. Phys. Chem. (Leipzig) 262, 711 (1981).Google Scholar
  26. 26.
    J. Cipriani, S. Racine, R. Dupeyrat, H. Hasmonay, M. Dupeyrat, Y. Levy, and C. Imbert, Opt. Comm 11, 70 (1974).Google Scholar
  27. 27.
    J.F. Rabolt, R. Santo, and J.D. Swalen, Appl. Spectrosc. 33, 549 (1979).Google Scholar
  28. 28.
    R. Iwamoto, M. Miya, K. Ohta, and S. Mima, J. Am. Chem. Soc. 102, 1212 (1980); J. Chem. Phys. 74, 4780 (1981).Google Scholar
  29. 29.
    T. Takenaka and T. Nakanaga, J. Phys. Chem. 80, 475 (1976).Google Scholar
  30. 30.
    G.S. Agarwal, Phys. Rev. A12, 1475 (1975).Google Scholar
  31. 31.
    W. Lukosz and R.E. Kunz, J. Opt. Soc. Am. 67, 1607, 1615 (1977).Google Scholar
  32. 32.
    W. Lukosz, J. Opt. Soc. Am. 69, 1495 (1979); 71, 744 (1981).Google Scholar
  33. 33.
    W. Lukosz and R.E. Kunz, Opt. Commn. 31, 251 (1979).Google Scholar
  34. 34.
    G. Mattei, B. Fornari, and M. Pagannone, Solid State Comm. 36, 309 (1980).Google Scholar
  35. 35.
    M. Ohsawa, K. Hashima, and W. Suëtaka, Appl. Surf. Sci. 20, 109 (1984).Google Scholar
  36. 36.
    J.F. Rabolt and J.D. Swalen, in: Spectroscopy of Surfaces (R.J.H. Clarke and R.E. Hester, eds.), Wiley, New York (1988), p. 1.Google Scholar
  37. 37.
    Y. Levy, C. Imbert, J. Cipriani, S. Racine, and R. Dupeyrat, Opt. Comm. 11, 66 (1974).Google Scholar
  38. 38.
    J.F. Rabolt, R. Santo, and J.D. Swalen, Appl. Spectrosc. 34, 517 (1980).Google Scholar
  39. 39.
    J.F. Rabolt, N.E. Schlotter, and J.D. Swalen, J. Phys. Chem. 85, 4141 (1981).Google Scholar
  40. 40.
    C.G. Zimba, V.M. Hallmark, S. Turrell, J.D. Swalen, and J.F. Rabolt, J. Phys. Chem. 94, 939 (1990).Google Scholar
  41. 41.
    C.G. Zimba and J.F. Rabolt, Thin Solid Films 206, 388 (1991).Google Scholar
  42. 42.
    G.I. Stcgeman, R. Fortenberry, R. Moshrefzadeh, W.H. Hetherington III, N.E. Van Wyck, and J.E. Sipe, Opt. Lett. 8, 295 (1983).Google Scholar
  43. 43.
    W.H. Hetherington III, Z.Z. Ho, E.W. Koenig, G.I. Stegcman, and R. Fortenberry, Chem. Phys. Lett. 128, 150 (1986).Google Scholar
  44. 44.
    G. Karagounis and R. Issa, Z. Elektrochem. 66, 874 (1962).Google Scholar
  45. 45.
    R.O. Kagel, J. Phys. Chem. 74, 4518 (1970).Google Scholar
  46. 46.
    T. A. Egerton, A.H. Hardin, Y. Kozirovsky, and N. Shcppard, J. Catal. 32, 343 (1974).Google Scholar
  47. 47.
    P.J. Hcndra, J.R. Horder, and E. J. Loader, J. Chem. Soc. 1766 (1971); P.J. Hcndra, I.D.M. Turner, E.J. Loader, and M. Stacey, J. Phys. Chem. 78, 300 (1974).Google Scholar
  48. 48.
    M.L. Howe, K.L. Walters, and R.G. Greenler, J. Phys. Chem. 80, 382 (1976).Google Scholar
  49. 49.
    J.M. Stencel and E.B. Bradley, Spectrosc. Lett. 11, 563 (1978).Google Scholar
  50. 50.
    J.M. Stencel, D.M. Noland, E.B. Bradley, and C.A. Frenzel, Rev. Sci. Instrum. 49, 1163 (1978).Google Scholar
  51. 51.
    J.M. Stencel and E.B. Bradley, J. Raman Spectrosc. 8, 203 (1979).Google Scholar
  52. 52.
    H.A. Marzouk, K.A. Arunkumar, and E.B. Bradley, Surf. Sci. 147, 477 (1984).Google Scholar
  53. 53.
    A. Campion, J.K. Brown, and V.M. Grizzle, Surf. Sci. 115, L153 (1982).Google Scholar
  54. 54.
    A. Campion, and D.R. Mullins, Surf. Sci. 158, 263 (1985).Google Scholar
  55. 55.
    D. Harradine and A. Campion, Chem. Phys. Lett. 135, 501 (1987).Google Scholar
  56. 56.
    C. Shannon and A. Campion, Surf. Sci. 227, 219 (1990).Google Scholar
  57. 57.
    R.N. Zitter, Surf. Sci. 28, 335 (1971).Google Scholar
  58. 58.
    J.A. Cape, L.G. Hale, and W.E. Tennant, Surf. Sci. 62, 639 (1977).Google Scholar
  59. 59.
    R. Tsu and S.S. Jha, J. Phys. (Paris) 41, C4–25 (1980).Google Scholar
  60. 60.
    H.J. Stolz and A. Abstreiter, Solid State Comm. 36, 857 (1980).Google Scholar
  61. 61.
    G.P. Schwartz, B. Schwartz, D. DiStefano, G.J. Gualtieri, and J.E. Griffiths, Appl. Phys. Lett. 34, 205 (1979).Google Scholar
  62. 62.
    Y. Dai, J.S. Swinnea, H. Steinfink, J.B. Goodenough, and A. Campion, J. Am. Chem. Soc. 109, 5291 (1987).Google Scholar
  63. 63.
    G. Mattei, B. Fornari, M. Pagannone, and L. Mattioli, J. Phys. (Paris) 45, C5–249 (1984); Solid State Comm. 44, 1495 (1982).Google Scholar
  64. 64.
    Y. Tian, J. Umemura, T. Takenaka, and T. Kunitake, Langmuir 4, 1064 (1988).Google Scholar
  65. 65.
    D.R. Miller, O.H. Hahn, and P.W. Bonn, Appl. Spectrosc. 41, 245 (1987).Google Scholar
  66. 66.
    J.P. Rabe, J.D. Swalen, and J.F. Rabolt, J. Chem. Phys. 86, 1601 (1987).Google Scholar
  67. 67.
    S.S. Perry and A. Campion, Surf. Sci. 234, L275 (1990).Google Scholar
  68. 68.
    S.S. Perry and A. Campion, J. Electron Spectrosc. Relat. Phenom. 54/55, 933 (1990).Google Scholar
  69. 69.
    S.S. Perry and A. Campion, Surf. Sci. 259, 207 (1991).Google Scholar
  70. 70.
    M. Fleischmann, P.J. Hendra, and A. J. McQuillan, J. Chem. Soc. Chem. Comm. 80 (1973).Google Scholar
  71. 71.
    M. Fleischmann, P.J. Hendra, and A.J. McQuillan, Chem. Phys. Lett. 26, 163 (1974).Google Scholar
  72. 72.
    E.S. Reid, R.P. Cooney, P.J. Hendra, and M. Fleischmann, J. Electroanal. Chem. 80, 405 (1977).Google Scholar
  73. 73.
    M. Pourbaix, Atlas of Electrochemical Equilibria in Aqueous Solutions, Pergamon, Oxford (1966).Google Scholar
  74. 74.
    B.H. Loo, J. Phys. Chem. 86, 433 (1982).Google Scholar
  75. 75.
    B.H. Loo and Y.G. Lee, Appl. Surf. Sci. 18, 345 (1984).Google Scholar
  76. 76.
    C. Shannon and A. Campion, J. Phys. Chem. 92, 1385 (1988).Google Scholar
  77. 77.
    C.A. Melendres, J.J. McMahon, and W. Ruther, J. Electroanal. Chem. 208, 175 (1986); Proceedings of the Tenth International Congress on Metallic Corrosion 4, 3481 (1987).Google Scholar
  78. 78.
    C.A. Melendres, J. Electroanal. Chem. 286, 273 (1990).Google Scholar
  79. 79.
    W.P. Acker, B. Tip, D.H. Leach, and R.K. Chang, J. Appl. Phys. 64, 2263 (1988).Google Scholar
  80. 80.
    D.K. Veirs, V.K.F. Chia, and G.M. Rosenblatt, Appl. Opt. 26, 3530 (1987).Google Scholar
  81. 81.
    D.L. Jeanmaire, M.R. Suchanski, and R.P. Van Duyne, J. Am. Chem. Soc. 97, 1699 (1975).Google Scholar
  82. 82.
    M.R. Suchanski and R.P. Van Duyne, J. Am. Chem. Soc. 98, 250 (1976).Google Scholar
  83. 83.
    W.L. Wallace, C.D. Jaeger, and A.J. Bard, J. Am. Chem. Soc. 101, 4840 (1979).Google Scholar
  84. 84.
    I. Blatter-Mörke, H. von Känel, and P. Wächter, J. Phys. Chem. 91, 663 (1987).Google Scholar
  85. 85.
    D.L. Akins, J.W. Macklin, and H-R. Zhu, J. Phys. Chem. 96 4515 (1992).Google Scholar
  86. 86.
    D.L. Akins, J.W. Macklin, and H-R. Zhu, J. Phys. Chem. 95, 793 (1991).Google Scholar
  87. 87.
    M. Ohsawa and W. Suëtaka, Ext. Abst. 26th Intern. Cong. Pure Appl. Chem. 1, 152 (1977).Google Scholar
  88. 88.
    N. Winograd and T. Kuwana, J. Am. Chem. Soc. 93, 4343 (1971).Google Scholar
  89. 89.
    W. Suëtaka and M. Ohsawa, Appl. Surf. Sci. 3, 118 (1979).Google Scholar
  90. 90.
    R.P. Van Duyne, in: Chemical and Biochemical Applications of Lasers, Vol. 4 (C.B. Moore, ed.), Academic, New York (1979), p. 101.Google Scholar
  91. 91.
    F.T. Arecchi, E. Gatti, and A. Sona, Rev. Sci. Instrum. 37, 942 (1966).Google Scholar
  92. 92.
    M. Ohsawa, K. Nishijima, and W. Suëtaka, Surf. Sci. 104, 270 (1980).Google Scholar
  93. 93.
    N. Yagi and W. Suëtaka, unpublished data.Google Scholar
  94. 94.
    M. Ohsawa, D.E. Thesis, Tohoku University (Sendai) 1984.Google Scholar
  95. 95.
    M. Fleischmann, P.J. Hendra, I.R. Hill, and M.E. Pemble, J. Electroanal. Chem. 117, 243 (1981).Google Scholar
  96. 96.
    J.S. Clarke, A.T. Kuhn, and W.J. Orville-Thomas, Electroanal. Chem. Interfacial Electro-chem. 54, 253 (1974).Google Scholar
  97. 97.
    D.L. Jeanmaire and R.P. Van Duyne, J. Electroanal. Chem. 60, 235 (1974).Google Scholar
  98. 98.
    M. Osawa and W. Suëtaka, J. Electroanal. Chem. 270, 261 (1989).Google Scholar
  99. 99.
    R. Rosetti, S.M. Beck, and L.E. Brus, J. Am. Chem. Soc. 104, 7322 (1982); J. Am. Chem. Soc. 106, 980 (1984).Google Scholar
  100. 100.
    M. Froelicher, A. Hugot-Le Goff, C. Pallotta, R. Dupeyrat, and M. Masson, in: Passivity of Metals and Semiconductors (M. Froment, ed.), Elsevier, Amsterdam (1983), p. 101.Google Scholar
  101. 101.
    R.J. Thibeau, C.W. Brown, A.Z. Goldfarb, and R.H. Heidensbach, J. Electrochem. Soc. 127, 37 (1980).Google Scholar
  102. 102.
    R. Kötz and E. Yeager, J. Electroanal. Chem. 111, 105 (1980).Google Scholar
  103. 103.
    C.A. Melendres and S. Xu, J. Electroanal. Chem. 162, 343 (1984);J. Electrochem. Soc. 131, 2239 (1984).Google Scholar
  104. 104.
    C.A. Melendres, N. Camillone, and T. Tipton, Electrochim. Acta 34, 281 (1989).Google Scholar
  105. 105.
    K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th Ed., Wiley-Interscience, New York (1986).Google Scholar
  106. 106.
    C. A. Melendres, T.J. O’Leary and J. Solis, Electrochim. Acta 36, 505 (1991).Google Scholar
  107. 107.
    J.J. McMahon, W. Rüther, and C.A. Melendres, J. Electrochem. Soc. 135, 557 (1988).Google Scholar
  108. 108.
    D. Cubicciotti, J. Nucl. Mater. 167, 241 (1989).Google Scholar
  109. 109.
    V.A. Maroni, C.A. Melendres, T.F. Kassner, and S. Siegel, J. Nucl. Mater. 172, 13 (1990).Google Scholar
  110. 110.
    G.J. Hansen and W.N. Hansen, J. Electroanal. Chem. 150, 193 (1983).Google Scholar
  111. 111.
    J.E. Pemberton and R.L. Sobocinski, J. Electroanal. Chem. 318, 157 (1991).Google Scholar

Copyright information

© Springer Science+Business Media New York 1995

Authors and Affiliations

  • W. Suëtaka
    • 1
  • John T. YatesJr.
    • 2
  1. 1.Tohoku UniversityTsuchiuraJapan
  2. 2.Surface Science CenterUniversity of PittsburghPittsburghUSA

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