Highly Curved Defects in Lamellar Phases: Non-Ionic Lamellar Phases and Birefringent Microemulsions

  • J. M. di Meglio
  • M. Dvolaitzky
  • R. Ober
  • L. Paz
  • C. Taupin
Chapter
Part of the Ettore Majorana International Science Series book series (EMISS, volume 41)

Abstract

In the past few years, new efforts have been devoted to the study of the interfacial film of amphiphilic molecules because of the increasing interest for new phases: microemulsions[1] and lyotropic nematics[2]. Among the amphiphiles, non-ionic surfactants[3] have been particularly studied because of several special features:
  • they are commercially available in a very pure form

  • their aqueous micellar solutions exhibit a lower consolute point whose nature is not completely understood[4–7].

  • they are able to form microemulsions without cosurfactant[8] in contrast to ionic surfactants. This capability seems to be correlated with the extension of the lamellar phase in the phase composition diagram.

Keywords

Cloud Point Spin Labelling Lamellar Phase Interfacial Film Curve Region 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    L. M. Prince, “Microemulsions Theory and Practice,” Academic Press, New York, (1977).Google Scholar
  2. 2.
    J. Charvolin, A. M. Levelut and E. T. Samulski, J.Phys.Lett., 40:L-587 (1973).CrossRefGoogle Scholar
  3. 3.
    a) M. J. Schick, “Non Ionic Surfactants,” Marcel Dekker, New York (1967). b) Ibid. p. 86.Google Scholar
  4. 4.
    M. Corti, V. Degiorgio and M. Zulauf, Phys.Rev.Lett., 48: 1617 (1982).ADSCrossRefGoogle Scholar
  5. 5.
    M. Zulauf and J. P. Rosenbusch, J.Phys.Chem., 87: 856 (1983).CrossRefGoogle Scholar
  6. 6.
    P. G. Nilsson, H. Wennerstrom and B. Lindman, J.Phys.Chem., 87: 1377 (1983).CrossRefGoogle Scholar
  7. 7.
    J. C. Ravey, J.Coll.Int.Sci., 94: 289 (1983).CrossRefGoogle Scholar
  8. 8.
    K. Shinoda and H. Kunieda, J.Coll.Int.Sci., 42: 381 (1973).CrossRefGoogle Scholar
  9. 9.
    D. J. Mitchell, G. J. T. Tiddy, L. Waring, T. Bostock and M. P. McDonald, J.Chem.Soc., Faraday Trans. 1: 79: 975 (1983).CrossRefGoogle Scholar
  10. 10.
    J. M. Di Meglio, M. Dvolaitzky, R. Ober and C. Taupin, J.Phys.Lett., 44:L-229 (1983).CrossRefGoogle Scholar
  11. 11.
    M. Dvolaitzky and C. Taupin, Nouv.J.Chim., 1: 355 (1977).Google Scholar
  12. 12.
    L. J. Berliner, “Spin Labeling: Theory and Applications,” Academic Press Inc., New York (1976).Google Scholar
  13. 13.
    J. S. Clunie, J. F. Goodman and p. C. Symons, J.Chem.Soc.Trans.Faraday Soc., 65: 287 (1969).CrossRefGoogle Scholar
  14. 14.
    B. Gallot and A. Skoulios, Kolloid Z.U.Z. Polymer, 208:37 (1966).Google Scholar
  15. 15.
    B. Mely, J. Charvolin and P. Keller, Chem. and Phys.Lipids., 15: 161 (1975).CrossRefGoogle Scholar
  16. 16.
    P. Ekwall, in “Advances in Liquid Crystals,” Vol. 1, G. Brown, ed., Academic Press, New York, p. 1 (1971).Google Scholar
  17. 17.
    W. L. Hubbel and A. M. McConnell, J.Amer.Chem.Soc., 93: 314 (1971).CrossRefGoogle Scholar
  18. 18.
    J. Seelig and H. Limacher, Mol.Cryst.Liq.Cryst., 25: 1051 (1974).CrossRefGoogle Scholar
  19. 19.
    J. Seelig, J.Amer.Chem.Soc., 93: 5017 (1971).CrossRefGoogle Scholar
  20. 20.
    H. Trauble and E. Sackman, J.Amer.Chem.Soc., 94: 4482 (1972).CrossRefGoogle Scholar
  21. 21.
    J. Charvolin and A. Tardieu, in: “Liquid Crystals,” Solid State Physics, Sup. 14, L. Liébert ed., Academic Press (1978).Google Scholar
  22. 22.
    R. C. McCalley, E. J. Shimshick and H. M. McConnell, Chem.Phys. Letters, 13: 115 (1972).ADSCrossRefGoogle Scholar
  23. 23.
    M. Dvolaitzky, R. Ober and C. Taupin, C.R. Hebd.Acad.Sci., B 293: 27 (1982).Google Scholar
  24. 24.
    W. Helfrich, in: “Physics of Defects,” R. Balian ed., North Holland, Amsterdam, p. 713 (1981).Google Scholar
  25. 25.
    M. Allain and J. M. Di Meglio, Mol.Cryst.Liq.Cryst., 124: 115 (1985).CrossRefGoogle Scholar
  26. 26.
    M. Kleman, in: “Springer series in Chemical Physics,” Vol. 11, p. 97 (1980).Google Scholar

Copyright information

© Springer Science+Business Media New York 1989

Authors and Affiliations

  • J. M. di Meglio
    • 1
  • M. Dvolaitzky
    • 1
  • R. Ober
    • 1
  • L. Paz
    • 1
  • C. Taupin
    • 1
  1. 1.Laboratorie de Physique de la Matière CondenséeParis Cedex 05France

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