Synthesis of Poly(2-Methoxy-5-Methyl-1,4-Phenylene Vinylene); Substituent Effects on the Electrical and Nonlinear Optical Properties

  • Jeong-Ik Lee
  • Hong-Ku Shim
  • Geon Joon Lee
  • Dongho Kim

Abstract

Conjugated polymers are currently considerable interest as materials for a wide variety of applications in last afew decades.1,2 Among them, the interest in poly(1,4-phenylenevinylene) (PPV) and its derivatives has been increased because they have high environmental and thermal stability, good processibility and high film quality, etc. They can be readily prepared in high molecular weight through the water-soluble precursor route.3 This route has allowed for preparation of a number of derivatives, including alkoxy, alkyl and halogen substituted derivatives.4–9 The substitution on the phenylene ring of the monomer with different type of substituent shows significant difference in electronic structure of the corresponding polymer,4–14 and thus affects the nonlinear optical and electrical properties of the polymer.

Keywords

Magnesium Sulfate Precursor Polymer Elimination Reaction Anhydrous Magnesium Sulfate High Film Quality 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media New York 1995

Authors and Affiliations

  • Jeong-Ik Lee
    • 1
  • Hong-Ku Shim
    • 1
  • Geon Joon Lee
    • 2
  • Dongho Kim
    • 2
  1. 1.Department of ChemistryKorea Advanced Institute of Science and TechnologyTaejonKorea
  2. 2.Spectroscopy Lab.Korea Research Institute of Standards and ScienceTaejonKorea

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