Polymers and Organic-Inorganic Hybrids for Second-Order Nonlinear Optics
Chapter
Abstract
Poled nonlinear optical (NLO) polymers have been the great interest for photonics applications.1,2 Using such materials, electro-optic modulators with a 100 GHz bandwidth have already been realized at the laboratory level,3 and a number of passive and active photonic devices also sucessfully fabricated.4–6 From the beginning stage of the NLO polymeric materials research in the middle of 1980’s, thermal relaxation and low values of NLO coefficients of chromophores in these systems were the major obstacles for practical applications. Since then there have been continuous efforts toward reducing thermal relaxation and increasing NLO activity of the materials. In recent years, in addition to improving these two fundamental factors, research was also extended to enhance optical quality, processibility and chemical stability of NLO materials, which are the properties closely related to those of matrix polymers.7,8
Keywords
Composite Film Second Harmonic Generation Second Harmonic Generation Signal Good Optical Quality Mitsunobu Reaction
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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