Intercalation in oxides from 2D to 3D intercalation

  • Claude Delmas
Part of the NATO ASI Series book series (NSSB, volume 172)

Abstract

The intercalation properties of graphite, transition metal dichalcogenides (TMDC) and clays have been intensively studied for at least twenty years. Till the eighties, stoichiometric AMO2 (A: alkali ion, M: transition element) sheet oxides have been mainly studied from a crystal chemistry point of view while only few works were devoted to Ax MO2 layer oxides1–6. During the last few years, numerous new results have been reported in this chemical field, stimulated by the potential interest of some of these compounds as positive electrode for high energy density batteries. This lack of interest in oxides as intercalation compounds arises certainly from the non existence of the fully deintercalated form MO2 with sheet structure. As it will be discussed in the following this property comes from the large electronegativity difference between the oxygen and the M element.

Keywords

Solid State Ionic Type Phase Nickel Hydroxide Lithium Oxide Oxygen Packing 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media New York 1987

Authors and Affiliations

  • Claude Delmas
    • 1
  1. 1.Laboratoire de Chimie du Solide du CNRSUniversité de Bordeaux ITalence CEDEXFrance

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