Off-Resonance Rotating Frame Spin—Lattice Relaxation

Theory, and in Vivo MRS and MRI Applications
  • Thomas Schleich
  • G. Herbert Caines
  • Jan M. Rydzewski
Part of the Biological Magnetic Resonance book series (BIMR, volume 11)

Abstract

The off-resonance rotating frame spin-lattice relaxation experiment represents a class of magnetic resonance techniques in which a low-power, continuous-wave radiofrequency (RF) field is applied off-resonance from a selected resonance. Application of such an irradiation field establishes nuclear spin polarization along an effective field inclined at an angle Θ away from the z axis of the rotating frame. In its original form, this approach was employed for the determination of the rotational correlation time, i.e., the rotational diffusion characteristics of a reorienting macromolecule (James et al., 1978; Schleich et al., 1989). More generally, the off-resonance rotating frame spin-lattice relaxation experiment can be thought of as a form of off-resonance saturation, in which a selected resonance is either completely or partially saturated. Viewed in these terms, the off-resonance rotating frame spin-lattice relaxation formalism, modified to include magnetization transfer phenomena, may be used to obtain chemical exchange kinetic and magnetic cross-relaxation information.

Keywords

Magnetization Transfer Rotational Correlation Time Chemical Shift Anisotropy Spin Bath Aqueous Protein Solution 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media New York 1992

Authors and Affiliations

  • Thomas Schleich
    • 1
    • 2
  • G. Herbert Caines
    • 1
  • Jan M. Rydzewski
    • 1
  1. 1.Department of Chemistry and Biochemistry, Sinsheimer LaboratoriesUniversity of CaliforniaSanta CruzUSA
  2. 2.Department of Pharmaceutical Chemistry, School of PharmacyUniversity of CaliforniaSan FranciscoUSA

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