Retrospective of Mixed-Refrigerant Technology and Modern Status of Cryocoolers Based on One-Stage, Oil-Lubricated Compressors

  • M. J. Boiarski
  • V. M. Brodianski
  • R. C. Longsworth
Part of the Advances in Cryogenic Engineering book series (ACRE, volume 43)

Abstract

Advancement of applied thermodynamics made it possible starting in the late 1960’s to tackle the problem of developing a highly-efficient single circuit throttling refrigeration cycle. It was shown by means of the exergy analysis that the Carnot efficiency of the well-known throttling refrigeration cycle may be essentially improved by using multi-component refrigerants (MR). Further, based on both thermodynamics of multi-component mixtures and experimental data on multi-phase vapor-liquid and solid-liquid equilibrium, highly-efficient MRs were proposed for different applications down to cryogenic temperatures. A combination of thermodynamics and technology allows us to design and build highly-reliable cryocoolers which are now commercially-available, based on one-stage oil-lubricated compressors. These low-cost coolers provide refrigeration in the temperature range from 65 K to more than 130 K depending on the MR composition. The development of this technology along with present applications, are discussed.

Keywords

Heat Exchanger Exergy Analysis Supply Pressure Refrigeration Cycle Carnot Cycle 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    V.M. Brodianski. “Sadi Carnot — Biography,” Nauka, Moscow, Russia [in Russian] (1996).Google Scholar
  2. 2.
    V.M. Brodianski, “From solid water to liquid helium, history of low-temperature engineering,” Energoatomizdat, Moscow, Russia [in Russian] (1995).Google Scholar
  3. 3.
    A. Fuderer. “Compression Process for Refrigeration” U. S. Patent 3,203,194 (August 1965).Google Scholar
  4. 4.
    V.M. Brodianski, et al. “The use of mixtures as working gas in throttle (J-T) cryogenic refrigerators,” Communications of XIII Congress IIR/ Washington (1971).Google Scholar
  5. 5.
    D.J. Missimer, “Refrigerant conversion of auto-refrigerating cascade (ARC) systems,” Polycold Systems Internationall San Rafael, CA (1973).Google Scholar
  6. 6.
    G.K. Lavrenchenko, “Formation of optimal mixed refrigerants for throttle refrigerators,” Choiodilnaia Technika and Technology Vol. 34/Kiev, Ukrain (1982).Google Scholar
  7. 7.
    M.J. Boiarski, et al, “Autonomic cryorefrigerators of small capacity,” Energoatomizdat, Moscow, Russia (1984).Google Scholar
  8. 8.
    N.D. Zakharov, et al. “Investigations of enthalpy of nitrogen-freon mixtures,” Chemichesikoe Neftianoe Mashinosroenie, No. 5 [in Russian] (1984).Google Scholar
  9. 9.
    A.P. Klimenko, “One-flow cascade cycle,” IIR Int’I Congress of Refrig./ Copenhagen, Denmark (1959).Google Scholar
  10. 10.
    W.A. Little, “Recent developments in Joule-Thomson cooling: gases, coolers and compressors,” Proceedings of the International Cryocoolers Conference5 (1988).Google Scholar
  11. 11.
    V.M. Brodianski, A.K. Gresin, “Highly efficient throttle refrigerators on multi-component mixtures,” Chemichesikoe Neftianoe Mashinosroenie, No. 12 [in Russian] (1971).Google Scholar
  12. 12.
    V.M. Brodianski, M.J. Boiarski and A.I. Lunin, “The exergy analysis of the throttle refrigerating systems on pure and mixed refrigerants,” Proceedings of the ESDA, PD-Vol.64–3, Eng. Sys. Des.Anl., V.3, ASME (1994).Google Scholar
  13. 13.
    V.N. Alfeev, et al. Great Britain Patent 1,336,892 (1973).Google Scholar
  14. 14.
    M.J. Boiarski, et al. U.S. Patent 5,441,658 (1995).Google Scholar
  15. 15.
    M.J. Boiarski and O.N. Podcherniaev, “Methods of calculations of phase equilibria and thermodynamic properties of mixed refrigerants for analyzing throttle refrigeration cycles,” Visocotemperaturnaia Sverkhprovodimost, Vol. 3–4/ Moscow, Russia [in Russian] (1990).Google Scholar
  16. 16.
    P. K. Lashmet and J. M. Geist, “A closed cycle cascade helium refrigerator” Adv. In Cryogenic Engr. Vol. 8, Plenum Press, NY 1963.Google Scholar
  17. 17.
    R.C. Longsworth, U.S. Patent No.5,337,572 (1994).Google Scholar
  18. 18.
    Khatri, A. and Boiarski, M.J. (1996) “A throttle cycle cryocooler operating with mixed gas refrigerants in 70 K to 120 K temperature range”, Cryocoolers 9, Plenum Press, NY, (1997).Google Scholar
  19. 19.
    R.C. Longsworth, M. J. Boiarski, and L. A. Klusmier, “80 K closed-cycle throttle refrigerator”, Cryocoolers 8, Plenum Press, NY, (1995), p. 537.Google Scholar
  20. 20.
    M. J. Boiarski et al. U.S. Patent No. 5,595,065 (1997)Google Scholar
  21. 21.
    R.C. Longsworth and D. Hill, “65 K two stage MR/02 throttle cycle refrigerator” Cryocoolers 9, Plenum Press, NY, (1997).Google Scholar
  22. 22.
    R.C. Longsworth, M. J. Boiarski and A. Khatri, U.S. Patent No. 5,579,654 (1996).Google Scholar
  23. 23.
    D. Hill, “Throttle cycle cooler vibration characterization”, Cryocoolers 9, Plenum Press, NY, (1997).Google Scholar
  24. 24.
    M. J. Boiarski and A. Khatri, “Water trap refrigerated by a throttle cycle cryocooler using mixed gas refrigerant”, Presented at 1997 CEC.Google Scholar

Copyright information

© Springer Science+Business Media New York 1998

Authors and Affiliations

  • M. J. Boiarski
    • 1
  • V. M. Brodianski
    • 2
  • R. C. Longsworth
    • 1
  1. 1.APD Cryogenics Inc.AllentownUSA
  2. 2.Moscow Power Engineering InstituteMoscowRussia

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