Infrared Studies of Hydrogen Bonding in Pure Liquids and Solutions
While many properties of nonpolar or weakly polar substances can be arranged according to the critical temperature T c or the molecular weight M,(896) the properties of a series of strongly polar substances cannot be derived from the molecular weight or from the dipole moment µ (serving as a measure of polarity). A comparison of H2S with H2O illustrates this situation. The special interaction that comes into play in these substances is referred to as “hydrogen bonding” because it is found only in proton-containing substances.
KeywordsHydrogen Bond Frequency Shift Intramolecular Hydrogen Bond Pure Liquid Side Band
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