State of Water in Certain Perchlorate Crystal Hydrates Formed by Elements of Periodic Group II

  • T. G. Balicheva
  • T. I. Grishaeva

Abstract

The structure and many properties of electrolyte solutions depend on the interaction between the ions and the solvent molecules. The strongest influence for typical complex-forming ions is exerted by the nearest solvent molecules, which form the solvate shell of the ions. However, the state of such molecules and the directly related problem of the composition and structure of their solvate shells in solution are still among the least studied and most difficult problems of solution chemistry. It is difficult to solve them merely by study of the properties of solutions, since such chemical processes as complexing, polymerization, hydrolysis, etc. are superimposed on the phenomenon in question. The lack of reliable data on the short-range environment of ions in solutions of moderate and high concentration is therefore one of the main obstacles to research on the state of coordinated particles.

Keywords

Hydrate Shell Solvate Shell Coordinate Water Molecule Outer Sphere Infrared Absorption Spectrum 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature Cited

  1. 1.
    S. N. Andreev, S. A. Shchukarev, and T. G. Balicheva, Zh. Strukt. Khim., 1: 183 (1960).Google Scholar
  2. 2.
    S. N. Andreev and T. G. Balicheva, in: The Hydrogen Bond [in Russian], Nauka (1964), p. 144.Google Scholar
  3. 3.
    T. G. Balicheva and S. N. Andreev, Zh. Strukt, Khim., 5: 29 (1964).Google Scholar
  4. 4.
    N. D. Sokolov, Doctoral Dissertation, Leningrad University (1952).Google Scholar
  5. 5.
    A. F. West, Z. Krist., 88: 98 (1934).Google Scholar
  6. 6.
    A. F. West, Z. Krist., 91: 480 (1935).Google Scholar
  7. 7.
    A. F. Wells, Structural Inorganic Chemistry [Russian translation], Izd. Inostr. Lit., Moscow (1948), p. 428.Google Scholar
  8. 8.
    I. B. Bersuker and A. V. Ablov, Chemical Bonding in Complex Compounds [in Russian], Izd. Shtinitsa, Akad. Nauk Molday. SSR, 25: 88 (1962).Google Scholar
  9. 9.
    E. V. Biron, Zh. Russk. Fiz.-Khim. Obshch., 47: 964 (1915).Google Scholar
  10. 10.
    S. A. Shchukarev, Zh. Obshch. Khim., 24: 584 (1954).Google Scholar
  11. 11.
    L. S. Lilich and M. E. Mogilev, Zh. Obshch. Khim., 26: 312 (1956).Google Scholar
  12. 12.
    L. S. Lilich and Yu. S. Varshayskii, Zh. Obshch. Khim., 26: 317 (1956).Google Scholar
  13. 13.
    A. B. Lamb and A. J. Jacques, J. Amer. Chem. Soc., 60: 967, 1215 (1938).CrossRefGoogle Scholar
  14. 14.
    R. Olson and Simonson, J. Chem. Phys., 17: 348 (1949).Google Scholar
  15. 15.
    S.. A. Shchukarev, S. N. Andreev, T. G. Balicheva, and L. N. Nechaeva, Vestn. Leningr. Gos. Univ., 16: 120 (1961).Google Scholar
  16. 16.
    G. Bedtker and O. Hassel, Zbl. Chem., 1: 3404 (1933).Google Scholar
  17. 17.
    E. L. Wagner, J. Chem. Phys., 37: 751 (1962).CrossRefGoogle Scholar
  18. 18.
    T. Dreisch and W. Trommer, Z. Phys. Chem., 37: 37 (1937).Google Scholar
  19. 19.
    T. Dreisch and O. Kollschauer, Z. Phys. Chem., 45: 19 (1939).Google Scholar
  20. 20.
    A. M. Buswell, R. Gore, and W. Rodebush, J. Phys. Chem., 45: 543 (1941).CrossRefGoogle Scholar
  21. 21.
    D. Williams and W. Millet, Phys. Rev., 66: 6 (1944).CrossRefGoogle Scholar
  22. 22.
    R. D. Waldron, J. Chem. Phys., 26: 809 (1957).CrossRefGoogle Scholar
  23. 23.
    G. E. Walrafen, J. Chem. Phys., 36: 1035 (1962).CrossRefGoogle Scholar
  24. 24.
    J. W. Schultz and D. F. Hornig, J. Phys. Chem., 65: 2131 (1961).CrossRefGoogle Scholar
  25. 25.
    O. M. Ansheles, V. B. Tatarskii, and A. A. Shternberg, High-Speed Growth of Homogeneous Single Crystals from Solution [in Russian], Lenizdat (1945).Google Scholar
  26. 26.
    T. G. Petrov and E. B. Treivus, Kristallografiya, 5: 425 (1960).Google Scholar
  27. 27.
    K. W. F. Kohlrausch, Raman Spectra [Russian translation], Izd. Inostr. Lit., Moscow (1952), p. 81.Google Scholar
  28. 28.
    R. Chidambaram, J. Chem. Phys., 36: 2361 (1962).CrossRefGoogle Scholar
  29. 29.
    W. C. Hamilton, Ann. Rev. Phys. Chem., 13: 19 (1962).CrossRefGoogle Scholar
  30. 30.
    G. C. Pimentel and A. L. McClellan, The Hydrogen Bond [Russian translation], Mir, Moscow (1964), p. 226.Google Scholar
  31. 31.
    N. D. Sokolov, Usp. Fiz. Nauk, 57: 247 (1955).CrossRefGoogle Scholar
  32. 32.
    J. Nakagawa and T. Schimanouchi, Spectrochim. Acta, 20: 429 (1964).CrossRefGoogle Scholar
  33. 33.
    R. S. Nyukhol’m, Usp. Khim., 32: 354 (1963).Google Scholar
  34. 34.
    L. Orgel, Introduction to Transition-Metal Chemistry [Russian translation], Mir (1964), p. 145. [English edition: J. Wiley & Son, New York (1966), second edition.]Google Scholar
  35. 35.
    O. Theimer, Monatsh. Chem., 61 (3): 301 (1950).CrossRefGoogle Scholar
  36. 36.
    J. P. Mathews, Compt. Rend., 238: 2510 (1954).Google Scholar
  37. 37.
    R. Teylor and G. Vidale, J. Amer. Chem. Soc., 78: 5999 (1956).CrossRefGoogle Scholar
  38. 38.
    S. A. Shchukarev, S. N. Andreev, and T. G. Balicheva, Dokl. Akad. Nauk SSSR, 144: 606 (1962).Google Scholar
  39. 39.
    I. Newbery, Trans. Electrochem. Soc., 69: 17 (1936).CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 1971

Authors and Affiliations

  • T. G. Balicheva
  • T. I. Grishaeva

There are no affiliations available

Personalised recommendations