Ultratrace Speciation and Biogenesis of Methyltin Transport Species in Estuarine Waters

  • F. E. Brinckman
  • J. A. Jackson
  • W. R. Blair
  • G. J. Olson
  • W. P. Iverson
Part of the NATO Conference Series book series (NATOCS, volume 9)

Abstract

Environmental tin, widely dispersed at low concentrations in waters, sediments, and biota, is shown to be a bioactive element susceptible to methylation and even hydridization by marine bacteria. The redox cycle of tin in natural waters is poorly understood and recent advances in tin-specific molecular characterization fail to speciate Sn(II) and Sn(IV) reliably. Nonetheless, such rapid developments in speciation methodology now permit growing numbers of studies of organotin distributions in aquatic systems, raising the question of the “natural” biogeochemical flux of methylstannanes in relation to increased anthropogenic organo-tin influx from industry and shipping. New methods for direct speciation of aquated or involatile organotins by liquid chromatography are compared with advances in purge-and-trap sampling of volatile or hydrophobic organotins speciated by gas chromatography. The work in our laboratory indicates that effective models for estuarine formation and transport may ultimately be developed, but that basic roadblocks to progress stem from inadequate descriptive aqueous organometallic chemistry and knowledge of critical kinetic parameters for the lifetimes of key organotin species in sea water, occurring at sub-nanomolar concentrations.

Keywords

Estuarine Water Antifouling Paint Flame Photometric Detector Calibration Slope Baltimore Harbor 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media New York 1983

Authors and Affiliations

  • F. E. Brinckman
    • 1
  • J. A. Jackson
    • 1
  • W. R. Blair
    • 1
  • G. J. Olson
    • 1
  • W. P. Iverson
    • 1
  1. 1.Chemical and Biodegradation Processes GroupNational Bureau of StandardsUSA

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