The Effect of Sewage Effluents on the Flocculation of Major and Trace Elements in a Stratified Estuary

  • Richard A. Feely
  • Gary J. Massoth
  • Marilyn F. Lamb
Part of the NATO Conference Series book series (NATOCS, volume 9)

Abstract

In order to study the effects of sewage effluents on the flocculation of trace elements in a stratified estuary, water samples were collected from the Duwamish River Estuary at stations located above and below the Renton Sewage Disposal Site. The water samples were filtered through 0.2-µm pore size Nuclepore filters, the filtrate mixed with various amounts of filtered sea water from Elliott Bay, and the products refiltered onto 0.2-µm filters and analyzed for major and minor elements by x-ray secondary emission spectrometry. The results show that the downstream samples produced two to three times more flocculated material and three to five times more P, Ca, Fe, Ni, Cu and Zn than the upstream samples. In contrast, little differences were found for Al and Ti. Similar experiments utilizing the effluent from the Renton Sewage Treatment Plant also showed the same trends, suggesting that the sewage effluent enhanced the flocculation of these elements in the estuary. Major element analysis of the flocculated material indicates that it is mainly composed of organic material.

Keywords

Trace Metal Particulate Organic Carbon Suspended Matter Total Suspended Matter Sewage Effluent 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    Galloway, J.N., 1972: Man’s alteration of the natural geochemical cycle of selected trace metals, Ph.D. dissertation, University of California, San Diego.Google Scholar
  2. 2.
    Bruland, K.W., K. Bertine, M. Koide and E.D. Goldberg, 1974: History of metal pollution in southern California Coastal zone. Environ. Sci. Tech. 8, 425–432.CrossRefGoogle Scholar
  3. 3.
    Eganhouse, R.P. and D.R. Young, 1976: Mercury in tissues of mussels off southern California. Mar. Pol. Bul. 7(8), 145–147.CrossRefGoogle Scholar
  4. 4.
    Eganhouse, R.P., D.R. Young and J.N. Johnson, 1978: Geochemistry of mercury in Palos Verdes sediments. Environ. Sci. and Tech. 12(10), 1151–1157.CrossRefGoogle Scholar
  5. 5.
    Rohatgi, N. and R.Y. Chen, 1975: Transport of trace metals by suspended particulates on mixing with seawater. Journal of Water Pollution Control Federation 47, 2298–2316.Google Scholar
  6. 6.
    Sholkovitz, E.R., 1978: The flocculation of dissolved Fe, Mn, Al, Cu, Ni, Co and Cd during estuarine mixing. Earth Planet Sci. Lett. 41, 77–86.CrossRefGoogle Scholar
  7. 7.
    Elderfield, H., H. and A. Hepworth, 1975: Diagenesis, metals and pollution in estuaries. Mar. Pollut. Bull. 6, 85–87.CrossRefGoogle Scholar
  8. 8.
    Krauskopf, K.B., 1956: Factors controlling the concentrations of thirteen rare metals in seawater. Geochim. Cosmochim. Acta. 9, 1–32.CrossRefGoogle Scholar
  9. 9.
    Kharkar, D.P., K.K. Turekian and K.K. Bertine, 1968: Stream supply of dissolved silver, molybdenum, antimony, selenium, chromium, cobalt, rabidium and cesium to the oceans. Geochim. Cosmochim. Acta. 32, 285–298.CrossRefGoogle Scholar
  10. 10.
    Murray, C.N. and L. Murray, 1973: Adsorption-desorption equilibria of some radionuclides in sediment-fresh water and sediment-seawater systems. In: “Radioactive Contamination of the Marine Environment”, pp. 105–124, IAEA, Vienna.Google Scholar
  11. 11.
    Dawson, W.A. and L.J. Tilley, 1972: Measurement of salt wedge excursion distance in the Duwamish River Estuary, Seattle, Washington, by means of the dissolved-oxygen gradient. U.S. Geological Survey Water Supply Paper 1873-D, 27 pp.Google Scholar
  12. 12.
    Santos, J.F. and J.D. Stoner, 1972: Physical, chemical and biological aspects of the Duwamish River estuary, King County, Washington, 1963–1967. U.S. Geological Survey Water Supply Paper 1873-C, 74 pp.Google Scholar
  13. 13.
    Gardner, G.B. and J.D. Smith, 1978: Turbulent mixing in a salt wedge estuary. In: “Hydrodynamics of Estuaries and Fjords”, (ed. J.C.J. Nicoul ), pp. 79–106, Elsevier Publishing Co., Amsterdam, Netherlands.CrossRefGoogle Scholar
  14. 14.
    Hamilton, S.E. and J. Cline, 1981: Hydrocarbons associated with suspended matter in the Green River, Washington. NOAA Tech. Mem. ERL PMEL-30, 116 pp.Google Scholar
  15. 15.
    Gardner, W.D., 1977: Incomplete extraction of rapidly settling particles from water samples. Limnol. Oceanogr. 22(4), 764–768.CrossRefGoogle Scholar
  16. 16.
    Calvert, S.E. and M.J. McCartney, 1979: The effect of incomplete recovery of large particles from water samples on the chemical composition of oceanic particulate matter. Limnol. Oceanogr. 24(3), 532–636.CrossRefGoogle Scholar
  17. 17.
    Feely, R.A., E.T. Baker, J.D. Schumacher, G.J. Massoth and W.D. Landing, 1979: Processes affecting the distribution and transport of suspended matter in the northeast Gulf of Alaska. Deep-Sea Res. 26 (4A), 445–464.Google Scholar
  18. 18.
    Baker, E.T. and D.Z. Piper, 1976: Suspended particulate matter: Collection by pressure filtration and elemental analysis by thin-film x-ray fluorescence. Deep-Sea Res. 23, 1181–1186.Google Scholar
  19. 19.
    Feely, R.A., G.J. Massoth and A.J. Paulson, 1981: Distribution and elemental composition of suspended matter in Norton Sound and the northeastern Bering Sea Shelf: Implication for Mn and Zn cycling in coastal waters. In: “The Eastern Bering Sea Shelf: Oceanography and Resources”, (eds. D.W. Hood and J.A. Calder ), pp 321–338. U.S. Department of Commerce, Office of Marine Pollution Assessment. Washington, D. C.Google Scholar
  20. 20.
    Sharp, J.H., 1974: Improved analysis for particulate organic carbon and nitrogen from seawater. Limnol. Oceanogr., 6 (19), 984–989.Google Scholar
  21. 21.
    Paulson, A.J., (n.d.). Unpublished data.Google Scholar
  22. 22.
    Appriou, P.Y., 1980: Analyse des technologies de dosage des métaux lourds en trace. Final Scientific Report 78/1886, Université de Bretagne Occidentale, Brest, France, 56 pp.Google Scholar
  23. 23.
    Sholkovitz, E.R., 1976: Flocculation of dissolved organic and inorganic matter during the mixing of river water and seawater. Geochim. Cosmochim. Acta. 40, 831–845.CrossRefGoogle Scholar
  24. 24.
    Murray, J.W. and G. Gill, 1978: The geochemistry of iron in Puget Sound. Geochim. Cosmochim. Acta. 43, 9–19.Google Scholar
  25. 25.
    Aston, S.R. and R. Chester, 1973: The influence of suspended particles on the precipiatation of iron in natural waters. Est. Coast. Mar. Sci. 1, 225–231.CrossRefGoogle Scholar
  26. 26.
    Holliday, L.M. and P.S. Liss, 1976: The behavior of dissolved iron, manganese and zinc in the Beaulieu estuary, S. England. Est. Coast. Mar. Sci. 4, 349–353.CrossRefGoogle Scholar
  27. 27.
    Eaton, A., 1979: Observations on the geochemistry of soluble copper, iron, nickel and zinc in the San Francisco Bay estuary. Environ. Sci. Technol. 13, 425–432.CrossRefGoogle Scholar
  28. 28.
    Sholkovitz, E.R. and N.B. Price, 1980: The major-element chemistry of suspended matter in the Amazon estuary. Geochim. Cosmochim. Acta. 44, 163–171.CrossRefGoogle Scholar
  29. 29.
    Malins, D.C., B.B. McCain, D.W. Brown, A.K. Sparks and H.O. Hodgins, 1980: Chemical contaminants and biological abnormalities in central and southern Puget Sound. NORA Tech. Memo., OMPA-2, Boulder, CO.Google Scholar
  30. 30.
    Riley, R.G., E.A. Crecelius, D.C. Mann, K.G. Abel, B.L. Thomas and R.M. Bean, 1980: Quantitation of pollutants in suspended matter and water from Puget Sound. NORA Tech. Memo., ERL MESA-49, 99 pp.Google Scholar
  31. 31.
    Schell, W.R., A. Nevissi, D. Piper, G. Christian, J.W. Murray, D.S. Spyradukis, S. Olsen, D. Hantaner, E. Knudson and D. Zafiropoulos, 1977: Heavy metals near the West Point outfall and in the central basin of Puget Sound. Report to the Municipality of Metropolitan Seattle, 174 pp.Google Scholar
  32. 32.
    Louma, S.N. and E.A. Jenne, 1977: The availability of sediment-bound cobalt, silver and zinc to a deposit-feeding clam. In: “Biological Implications of Metals in the Environment”, (eds. H. Drucker and R.E. Wildung), pp. 213–231, U.S. NTIS Conf. 750729, Springfield, VA.Google Scholar
  33. 33.
    Louma, S.N. and G.W. Bryan, 1978: Factors controlling the availability of sediment-bound lead to the estuarine bivalve Scorbicalaria plana. J. Mar. Biol. Ass. U.K., 58, 793–802.Google Scholar
  34. 34.
    Furr, A.K., T.F. Parkinson, J. Ryther, C.A. Bache, W.H. Butenmann, I.S. Pakrala and D.J. Lisk, 1981: Concentrations of elements in a marine food chain cultured in sewage wastewater. Bull. Environ. Contam. Toxicol. 26, 54–59.CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 1983

Authors and Affiliations

  • Richard A. Feely
    • 1
  • Gary J. Massoth
    • 1
  • Marilyn F. Lamb
    • 1
  1. 1.Pacific Marine Environmental LaboratoryEnvironmental Research Laboratories, NOAASeattleUSA

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