Prospects for Chiral Discrimination in Reversed Micelles

  • L. J. Magid
Part of the Forschung Soziologie book series


Chiral discrimination in the aggregation properties of optically active surfactants and their use in reaction catalysis are briefly reviewed. Suggestions for enhancing the observed stereoselectivities 1n reversed micellar systems are presented.


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  1. 1.
    S. Miyagishi and M. Nishida, J.Colloid Interface Sci., 65: 380 (1978).CrossRefGoogle Scholar
  2. 2.
    E.M. Arnett, B.J. Kinzig, M.V. Stewart, O. Thompson, J. Chao and R.J. Verbiar, J. Am. Chem. Soc., 104: 389 (1982).CrossRefGoogle Scholar
  3. 3.a.
    M.V. Stewart and E.M. Arnett, Top. Stereochem., 13: 195 (1982)Google Scholar
  4. b.
    E.M. Arnett and J.M. Gold, J. Am. Chem. Soc., 104: 636 (1982).CrossRefGoogle Scholar
  5. 4.
    See S.-T. Chen and C.S. Springer, Chem. Phys. Lipids, 23: 23 and references therein (1979).CrossRefGoogle Scholar
  6. 5.
    K. Kon-no, M. Tosaka and A. Kitahara, J. Colloid Interface Sci., 86: 288 (1982).CrossRefGoogle Scholar
  7. 6.
    A.H. Beckett, G. Kirk and A.S. Virji, J. Pharm. Pharmac. 19: 827 (1967).CrossRefGoogle Scholar
  8. 7.a.
    J.M. Brown and C.A. Bunton, J. Chern. Soc., Chem. Commun. 969 (1974).Google Scholar
  9. b.
    Y. Ihara, J. Chem. Soc., Perkin Trans, 2: 1483 (1980).CrossRefGoogle Scholar
  10. 7.c.
    K. Ohkubo, K. Sugahara, K. Yoshinaga and R. Ueoka, J. Chem. Soc., Chem. Commun., 637 (1980).Google Scholar
  11. d.
    R.A. Moss, Y.-S. Lee and K.W. Alwis, J. Am. Chem. Soc., 102: 6646; Tetrahedron Lett., 22: 283 (1981).CrossRefGoogle Scholar
  12. e.
    R.A. Moss, T. Taguchi and G.O. Bizzigotti, ibid. 23: 1985 (1982).Google Scholar
  13. 8.
    Y. Ihara, N. Kunikiyo, T. Kunimasa, M. Nango and N. Kuroki, Chem. Lett., 667 (1981).Google Scholar
  14. 9.
    Y. Ihara, Y. Kimura, M. Nango and N. Kuroki,, Makromol. Chem., Rapid Commun., 3: 521 (1982).CrossRefGoogle Scholar
  15. 10.
    D.W. Ingles, J.R. Knowles and J.A. Tomlinson, Biochem. Biophys. Res. Commun., 23: 619 (1966).CrossRefGoogle Scholar
  16. 11.
    J.H. Fendler in “Membrane Mimetic Chemistry”, John Wiley & Sons New York, p. 322 (1982).Google Scholar
  17. 12.
    J.-M. Lehn and C. Sirlin, J. Chem. Soc. Chem. Commun., 949 (1978).Google Scholar
  18. 13.
    T. Kunitake, N. Nakashima, S. Hayashida and K. Yonemori, Chem. Lett., 1413 (1979).Google Scholar
  19. 14.
    Y. Murakami, A. Nakano, A. Yoshimatsu and K. Fukuya, J. Am. Chem. Soc., 103: 728 (1981).CrossRefGoogle Scholar
  20. 15.
    J.H. Fendler and E.J. Fendler, “Catalysis in Micellar and Macromolecular Systems”, Academic Press, New York (1975).Google Scholar
  21. 16.
    J. Sunamoto, K. Iwamoto, M. Akutagawa, M. Nagase and H. Kondo, J. Am. Chem. Soc., 104: 4904 (1982).CrossRefGoogle Scholar
  22. 17.
    R.A. Moss and W.L. Sunshine, J. Org. Chem., 39: 1083 (1974).CrossRefGoogle Scholar
  23. 18.
    K. Kon-no, M. Tosaka and A. Kitahara, J. Colloid Interface Sci., 79: 581 (1981).CrossRefGoogle Scholar
  24. 19.
    See for example the references in L.J. Magid and C.A. Martin, this volume.Google Scholar
  25. 20.
    H. Brockerhoff, “Bioorganic Chemistry”, van Tamlen E.E., Ed. Academic Press, New York, Vol. 3, Chapter 1 (1977).Google Scholar

Copyright information

© Springer Science+Business Media New York 1984

Authors and Affiliations

  • L. J. Magid
    • 1
  1. 1.Department of ChemistryUniversity of TennesseeKnoxvilleUSA

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