Concerted Reactions

  • Francis A. Carey
  • Richard J. Sundberg

Abstract

There are many reactions in organic chemistry that give no evidence of involving intermediates when they are subjected to the usual probes employed for studying reaction mechanisms. Highly polar transition states do not seem to be involved either, since the rates of such reactions are insensitive to solvent polarity. Efforts to detect free-radical intermediates by physical or chemical means have not been successful, and the reaction rates are neither increased by initiators nor decreased by free-radical inhibitors. This lack of evidence of intermediates leads to the conclusion that the reactions are concerted processes in which bond making and bond breaking both contribute to the structure at the transition state, although not necessarily to the same degree. There are numerous examples of both unimolecular and bimolecular concerted processes.

Keywords

High Occupied Molecular Orbital Lower Unoccupied Molecular Orbital Cycloaddition Reaction Orbital Symmetry Claisen Rearrangement 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer Science+Business Media New York 1984

Authors and Affiliations

  • Francis A. Carey
    • 1
  • Richard J. Sundberg
    • 1
  1. 1.University of VirginiaCharlottesvilleUSA

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