Subpicosecond Time Resolved Multiphoton Ionization: Excited State Dynamics of CIS-Stilbene under Collision Free Conditions

  • B. I. Greene
  • R. C. Farrow
Conference paper


We report the results of a novel subpicosecond measurement performed on a cis-stilbene in the vapor phase. As will be described below, we have extended a well-known pulsed laser technique1,2 into the 10−13 sec time regime, and choose to focus renewed scientific attention on the dynamics of stilbene photoisomerization. We believe this measurement will establish the technique of gas phase multiphoton ionization as a viable and potentially powerful subpicosecond probe of intramolecular dynamics.


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  1. 1.
    T. G. Dietz, M. A. Duncan, M. G. Liverman, and R. C. Smalley,J. Chem. Phys. 73, 4816 (1980).ADSCrossRefGoogle Scholar
  2. 2.
    V. S. Antonov, I. N. Knyazev, V. S. Letokhov, V. M. Matiuk, V. G. Morshev, and V. K. Potapov, Optics Letters 3I 37 (1978)ADSCrossRefGoogle Scholar
  3. 3.
    R. L. Fork, B. I. Greene, and C. V. Shank, Appl. Phys. Lett., 38, 671 (1981).ADSCrossRefGoogle Scholar
  4. 4.
    R. L. Fork, C. V. Shank, and R. T. Yen, Appl. Phys. Lett. 41, 223 (1982).ADSCrossRefGoogle Scholar
  5. 5.
    R. M. Hochstrasser, Pure Appl. Chem. 52, 2683 (1980).Google Scholar
  6. 6.
    J. A. Syage, Wm. R. Lambert, P. M. Felker, A. H. Zewail, and R. M. Hochstrasser, Chem. Phys. Lett. 83, 266 (1982).ADSCrossRefGoogle Scholar
  7. 7.
    K. Yoshihara, A. Namiki, M. Sumitani, and N. Nakashima, J. Chem. Phys. 71, 2892 (1979).ADSCrossRefGoogle Scholar
  8. 8.
    J. P. Maier and D. W. Turner, J. Chem. Soc. Faraday Trans II 69, 196 (1973).CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 1984

Authors and Affiliations

  • B. I. Greene
    • 1
  • R. C. Farrow
    • 1
  1. 1.Bell LaboratoriesMurray HillUSA

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