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Subpicosecond Time Resolved Multiphoton Ionization: Excited State Dynamics of CIS-Stilbene under Collision Free Conditions

  • B. I. Greene
  • R. C. Farrow
Conference paper

Abstract

We report the results of a novel subpicosecond measurement performed on a cis-stilbene in the vapor phase. As will be described below, we have extended a well-known pulsed laser technique1,2 into the 10−13 sec time regime, and choose to focus renewed scientific attention on the dynamics of stilbene photoisomerization. We believe this measurement will establish the technique of gas phase multiphoton ionization as a viable and potentially powerful subpicosecond probe of intramolecular dynamics.

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Copyright information

© Springer Science+Business Media New York 1984

Authors and Affiliations

  • B. I. Greene
    • 1
  • R. C. Farrow
    • 1
  1. 1.Bell LaboratoriesMurray HillUSA

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