Determination of Acidity in the Interior of the Cross-Linked Polyelectrolyte Grain by the Use of pH-Sensitive Probes

  • Leonid S. Molochnikov
  • Elena G. Kovalyova
  • Igor’ A. Grigor’ev
  • Vladimir A. Reznikov


Circumstantial evidence12 suggests that the state of water in ionite micropores and the acidity of the medium significantly differ from the ones in solution contacting the sorbent. Therefore, the conditions existing in the interior of ionite grains may not be approximated by measurements in solutions, which are performed by researchers. However, it is precisely these conditions that determine complexating processes or catalysis using sorbents as catalysts. Recently, the synthesis of stable nitroxyl radicals (NR) which are sensitive to changes of medium acidity in connection with participation in reactions of proton exchange and may be used as pH-probes, has been carried out.3 4 Using the electron spin resonance spectroscopy (ESR) method, the principal possibility to measure pH-value in a solution at the site of radicals location as well as in micropores of ionites appeared.


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  1. 1.
    V.V.Mank, O.D.Kurilenko. “Investigation of Intermolecular Interaction in Ion-exchange Resins by NMRGoogle Scholar
  2. Method,” Naukova Dumka, Kiev (1976).Google Scholar
  3. 2.
    G.Zundel. “Hydration and Intermolecular Interaction,” Academic Press, N.Y (1969).Google Scholar
  4. 3.
    J.F.W.Keana, MJ.Acarregui, S.L.M.Boyle, 2,2-Disubstituted-4,4-dimethylimidazolidinyl-3-oxynitroxides: indicators of aqueous acidity through variation of aN with pH, J.Am.Chem.Soc. 104:827 (1982).CrossRefGoogle Scholar
  5. 4.
    V.V.Khramtsov, L.M.Wainer, I.A.Grigor’ev, L.B. Volodarsky, Proton exchange in stable nitroxyl radicals, Chem. Phys. Lett. 91:69 (1982).CrossRefGoogle Scholar
  6. 5.
    N.J.Poliansky, G.B.Gorbunov, N.L.Polianskaia. “The Method of Investigations of Ion-exchangers,” Chemistry, Moscow (1976).Google Scholar
  7. 6.
    V.V.Khramtsov. “Proton Exchange in Nitroxyl Radicals,” Abstract of candidate thesis. Novosibirsk (1985).Google Scholar
  8. 7.
    H P.Gregor, L.B.Luttinger, E.Loeble, Metal-polyelectrolyte complexes, J. Phys. Chem. 59:34,366 (1955).CrossRefGoogle Scholar
  9. 8.
    G.S.Libinson. “Physico-chemical Properties of Carboxylic Cationites,” Nauka, Moscow (1969).Google Scholar
  10. 9.
    A.Chatteijee, J.A,Marinsky, Dissociation of methacrylic acid resins, J. Phys. Chem 67:41 (1963).CrossRefGoogle Scholar
  11. 10.
    I.Michaeli, A,Katchalsky, Potentiometric titration of polyelectrolyte gels, J. Polymer Sci. 23:683 (1957).CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 1996

Authors and Affiliations

  • Leonid S. Molochnikov
    • 1
  • Elena G. Kovalyova
    • 1
  • Igor’ A. Grigor’ev
    • 2
  • Vladimir A. Reznikov
    • 2
  1. 1.Ural State Wood Technology Academy37 EkaterinburgRussia
  2. 2.Institite of Organic Chemistry Siberian BranchRussian Academy of Scienes9 NovosibirckRussia

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