Poly(Phenylmetallosiloxane)S: Synthesis, Structure and Properties

  • Olga I. Shchegolikhina
  • Inessa V. Blagodatskikh
  • Yulia A. Pozdnyakova
  • Alexandre A. Zhdanov


The synthesis and the study of metallosiloxane polymers is of a considerable interest due to their unique properties, which include high thermal stability and electrical conductivity. The chemistry of metallosiloxane polymers has already been studied for 25–30 years. The question about their structure was open until the beginning of 1990 when we have first obtained and structurally characterized poly (phenylmetallosiloxane)s (PPMS), containing bivalent transition metal atoms: nickel, manganese, copper and cobalt1-4, which were named the cage-like poly (phenylmetallosiloxane)s8.


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© Springer Science+Business Media New York 1996

Authors and Affiliations

  • Olga I. Shchegolikhina
    • 1
  • Inessa V. Blagodatskikh
    • 1
  • Yulia A. Pozdnyakova
    • 1
  • Alexandre A. Zhdanov
    • 1
  1. 1.Institute of Organo-Element CompoundsRussian Academy of SciencesMoscowRussia

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