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Chemical Modifications of Halomethylated Poly(Methylphenylsilane): A New and Facile Route to Functionalized Polysilanes

  • A. C. Swain
  • S. J. Holder
  • R. G. Jones
  • A. J. Wiseman
  • M. J. Went
  • R. E. Benfield
Chapter

Abstract

Soluble polysilanes are most commonly prepared using the Wurtz type reaction between dichloroorganosilanes and molten sodium metal in refluxing toluene1 or by the action of sodium dispersions in refluxing diethylether.2

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References

  1. 1.
    R.D.Miller and J.Michl, Chem.Rev., (1989), 89, 1361 and references therein.Google Scholar
  2. 2.
    R.H.Cragg, R.G.Jones, A.C.Swain and S.J.Webb, J.Chem.Soc.,Chem.Commun., (1990), 1147.Google Scholar
  3. 3.
    P.Trefonas, R.West, R.D.Miller and D.Hofer, J.Polym.Sci., Polym.Lett.Ed., (1983), 21, 823.CrossRefGoogle Scholar
  4. 4.
    P.Trefonas, R.West and R.D.Miller, J.Am.Chem.Soc., (1985), 107, 2737.CrossRefGoogle Scholar
  5. 5.
    R.West, L.D.David, P.L.Djurovich, K.L.Stearly, K.S.V.Srinivasan and H.Yu, J.Am.Chem.Soc., (1981), 103, 7352.CrossRefGoogle Scholar
  6. 6.
    R.West, L.D.David, P.I.Djurovich, H.Yu and R.Sinclair, Ceram.Bull., (1983), 62, 899.Google Scholar
  7. 7.
    S.Gauthier and D.Worsfold, Macromolecules, (1989), 22, 2213.CrossRefGoogle Scholar
  8. 8.
    R.D.Miller, J.Rabolt, R.Sooriyakumaran, W.Fleming, G.N.Fickes, B.L.Farmer and H.Kuzmany, Inorganic and Organometallic Polymers; M.Zeldin, K.H.Wynne, H.R. Allcock, Eds, ACS Symposium Series; Am.Chem.Soc.:Washington, DC, (1988); Vol. 360, pp 43–60.CrossRefGoogle Scholar
  9. 9.
    R.West, A.R. Wolff and D.J.Peterson, J.Radiat. Curing, (1986), 13, 35.Google Scholar
  10. 10.
    A.R. Wolff and R. West, Applied Organomet. Chem., (1987), 1, 7.CrossRefGoogle Scholar
  11. 11.
    S.Yajima, Y.Hasegawa, J.Hayashi and M.Iiomora, J.Mater.Sci., (1980), 15, 720.CrossRefGoogle Scholar
  12. 12.
    S.Yajima, J.Hayashi and M.Omori, Chem.Lett, (1975), 931.Google Scholar
  13. 13.
    J.P. Wesson and T.C.Williams, J.Polym.Sci.,Polym.Chem.Ed., (1980), 15, 720.Google Scholar
  14. 14.
    J.P.Wesson and T.C.Williams, ibid., (1981), 19, 65.Google Scholar
  15. 15.
    T.Uhsirogauchi, T.Tada and H.Watanabe, Proceedings of Conference on RadiationCuring Ashia, (1986), 101.Google Scholar
  16. 16.
    P.Trefonas, P.I.Djurovich, X.-H.Zhang, R.West, R.D.Miller and D.Hofer, J.Polym.Sci., Polym.Lett.Ed., (1983), 21, 819.CrossRefGoogle Scholar
  17. 17.
    X.-H.Zhang and R.West, J.Polym.Sci.,Polym.Chem.Ed., (1984), 22, 159.CrossRefGoogle Scholar
  18. 18.
    X.-H.Zhang and R.West, ibid., (1984), 22, 225.Google Scholar
  19. 19.
    H.Stuger and R.West, Macromolecules, (1985), 18, 2349.CrossRefGoogle Scholar
  20. 20.
    S.Ho.Yi, N.Maeda, T.Suzuki and H.Sato, Polymer J, (1992), 24, 865.CrossRefGoogle Scholar
  21. 21.
    R.D.Miller, D.Thompson, R.Sooriyakumaran and G.N.Fickes, J.Polym.Sci.,Polym.Chem.Ed., (1991), 29, 813.Google Scholar
  22. 22.
    L.A.Harrah and J.M.Zeigler, Macromolecules, (1987), 20, 2037.CrossRefGoogle Scholar
  23. 23.
    R.Horiguchi, Y.Onishi and S.Hayase, ibid, (1988), 21, 304.Google Scholar
  24. 24.
    H.Ban, K.Sukegawa and S.Tagawa, ibid, (1987), 21, 304.Google Scholar
  25. 25.
    R.E.Benfield, RH.Cragg, R.G.Jones, A.C.Swain, S.J.Webb and M.J.Went, Polymer, in press.Google Scholar
  26. 26.
    T.Seki, T.Tamaki and K.Ueno, Macromolecules, (1992), 25, 3825.CrossRefGoogle Scholar
  27. 27.
    B.L.Van Duisen, A.Sivak, B.M.Goldschmidt, C.Katz and S.Melchionne, J.Natl.Cancer Inst. (1969), 43, 481.Google Scholar
  28. 28.
    M.E.Wright, E.G.Toplikar and S.A.Svejda, Macromolecules, (1991), 24, 5879.CrossRefGoogle Scholar
  29. 29.
    H.Sakurai and F.Kondo, J.Organomet.Chem., (1975), 92, C46.CrossRefGoogle Scholar
  30. 30.
    C.U.Pittman and R F.Felis, J.Organometallic.Chem., (1974), 72, 389.CrossRefGoogle Scholar
  31. 31.
    H.Sakurai, persional communication.Google Scholar
  32. 32.
    H.K.Kim and K.Matyjaszewski, J.Polym.Sci., Part A: Polym.Chem, (1993), 31, 299.CrossRefGoogle Scholar
  33. 33.
    Ch.Elschenbroich and A.Salzer, Organometallics,VCH Verlagsgesellschaft/VCH Publishers, Weinheim/New York (1989)Google Scholar
  34. 34.
    S.Bhaduri, H.Khwaja and V.Khanwalkar, J.Chem.Soc., Dalton Trans., (1981), 445 Google Scholar

Copyright information

© Springer Science+Business Media New York 1996

Authors and Affiliations

  • A. C. Swain
    • 1
  • S. J. Holder
    • 1
  • R. G. Jones
    • 1
  • A. J. Wiseman
    • 1
  • M. J. Went
    • 1
  • R. E. Benfield
    • 1
  1. 1.Centre for Materials Research, Chemical LaboratoryUniversity of KentCanterburyGreat Britain

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