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pp 1-36 | Cite as

Synthesis and Properties of Zeolite Materials Guided by Periodic Considerations

  • Luis Gómez-Hortigüela
  • Joaquín Pérez-ParienteEmail author
Chapter
Part of the Structure and Bonding book series

Abstract

Since their discovery, zeolite materials were destined to become a relevant topic of fundamental research as well as to have a great impact on the chemical industry because of their specific properties, combining (1) their characteristic shape selectivity imposed by their microporous long-range ordered structures and (2) the availability of a wide number of active sites for multitude of important catalytic reactions, making them excellent heterogeneous catalysts. Both chemical properties are to some extent controlled by the isomorphous substitution of the Si, Al, and P atoms in the basic tetrahedral framework by other elements from different parts of the periodic table. On the one hand, incorporation of certain elements such as Al, Ga, or B generates Brønsted acid sites with varying strengths, while incorporation of tetravalent elements such as Ti or Sn produces interesting Lewis acid sites. On the other hand, introduction of some elements can exert specific structure-directing roles leading to exotic framework microporous structures that could not be produced otherwise. We analyze and rationalize the chemical and structural changes resulting from the incorporation of elements into the zeolitic materials using principles based on the periodic table.

Keywords

Aluminophosphates Brønsted acidity Isomorphous substitution Lewis acidity Zeolites 

Notes

Acknowledgments

The authors acknowledge funding from the Spanish State Research Agency (Agencia Española de Investigación, AEI) and the European Regional Development Fund (Fondo Europeo de Desarrollo Regional, FEDER) through the Project MAT2016-77496-R (AEI/FEDER, UE).

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Copyright information

© Springer Nature Switzerland AG 2019

Authors and Affiliations

  • Luis Gómez-Hortigüela
    • 1
  • Joaquín Pérez-Pariente
    • 1
    Email author
  1. 1.Instituto de Catálisis y Petroleoquímica (ICP-CSIC)MadridSpain

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