Polyoxometalate-Based Photo-Sensitive Functional Hybrid Materials

Chapter
Part of the Structure and Bonding book series (STRUCTURE, volume 176)

Abstract

The photochemical behaviors of polyoxometalates (POMs) have been extensively studied and widely used in various photo-redox reactions. Incorporating photo-sensitive organic molecules onto the POM platform not only allows the rational design and fine-controlled synthesis of novel organic–inorganic hybrids but also gives the possibility to explore their potential applications in diverse areas such as photochromics, optical switching, and smart self-assemblies. Herein, we summarize the latest progress of photo-sensitive POM hybrids with a particular focus on the photo-induced reversible coloration, polymerization, and supramolecular self-assembly. The mechanisms and the crucial roles of POM clusters in such reversible processes are also considered.

Keywords

Azobenzene Coumarin Photo-sensitive Polyoxometalate Spiropyran 

Notes

Acknowledgements

This research was supported by the National Basic Research Program of China (973 program, 2014CB932104), the National Nature Science Foundation of China (U1407127, U1507102, 21521005, 21625101), and Fundamental Research Funds for the Central Universities. C.-G.L. appreciates financial support from the China Postdoctoral Science Foundation (2016M591048).

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Copyright information

© Springer International Publishing AG 2017

Authors and Affiliations

  1. 1.State Key Laboratory of Chemical Resource EngineeringBeijing University of Chemical TechnologyBeijingP. R. China
  2. 2.Beijing Advanced Innovation Center for Soft Matter Science and EngineeringBeijing University of Chemical TechnologyBeijingP. R. China

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