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Cobalt(II) Complexes as Single-Ion Magnets

  • Shalini Tripathi
  • Atanu Dey
  • Maheswaran ShanmugamEmail author
  • Ramakirushnan Suriya Narayanan
  • Vadapalli Chandrasekhar
Chapter
Part of the Topics in Organometallic Chemistry book series (TOPORGAN, volume 64)

Abstract

This book chapter is mainly devoted to the recent findings about the cobalt(II) single-ion magnets (SIMs). Influence of various coordination numbers (from 2 to 8) around Co(II) in determining the spin Hamiltonian (SH) parameters of the complexes is reviewed. This chapter also discloses the importance of proper ligand design for stabilizing Ising or uniaxial anisotropy in mononuclear Co(II) complexes.

Keywords

Cobalt complexes EPR Magnetism Single-ion magnets X-ray diffraction 

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Copyright information

© Springer International Publishing AG, part of Springer Nature 2018

Authors and Affiliations

  • Shalini Tripathi
    • 1
  • Atanu Dey
    • 2
  • Maheswaran Shanmugam
    • 1
    Email author
  • Ramakirushnan Suriya Narayanan
    • 2
  • Vadapalli Chandrasekhar
    • 2
    • 3
  1. 1.Department of ChemistryIndian Institute of Technology BombayMumbaiIndia
  2. 2.Tata Institute of Fundamental Research HyderabadHyderabadIndia
  3. 3.Department of ChemistryIndian Institute of Technology KanpurKanpurIndia

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