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NLO Properties of Metal Alkynyl and Related Complexes

  • Joseph P.L. Morrall
  • Mark G. Humphrey
  • Gulliver T. Dalton
  • Marie P. Cifuentes
  • Marek Samoc
Part of the Challenges and Advances in Computational Chemistry and Physics book series (COCH, volume 1)

Abstract

The NLO properties of iron, ruthenium, osmium, nickel, and gold alkynyl complexes and some related compounds prepared in the authors’ laboratories are reviewed. Structure-property relationships for both quadratic and cubic NLO merit for these complexes have been developed from hyper-Rayleigh scattering studies at 1.064μm and Z-scan studies at 0.800μ m, respectively

Keywords

Organometallics Alkynyl Vinylidene Quadratic Hyperpolarizability Cubic Hyper-polarizability 

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Copyright information

© Springer 2006

Authors and Affiliations

  • Joseph P.L. Morrall
    • 1
    • 2
  • Mark G. Humphrey
    • 1
  • Gulliver T. Dalton
    • 1
    • 2
  • Marie P. Cifuentes
    • 1
  • Marek Samoc
    • 2
  1. 1.Department of ChemistryAustralian National UniversityAustralia
  2. 2.Laser Physics CentreResearch School of Physical Sciences and Engineering, Australian National UniversityAustralia

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