Abstract
The corrosion and electrochemical behavior of high-strength steel AISI 4340 with or without nitrocarburizing heat-treated conditions was studied using salt spray test under 5% NaCl for 24 hours. Electrochemical experiments were also carried out under corrosive environment of a 1N H2SO4. Without heat-treated results obtained by electrochemical test between potential and log of ampere, it yields the value of corrosion potential to 269.2 mV, and in case of heat-treated sample, value obtained is to be −431.918 mV. For heat-treated samples, the rate of corrosion (Icorr) shows a continuous shifting of graph toward a positive direction, whereas in case of without heat-treated sample, the rate of corrosion (Icorr) for HT sample is higher. In salt spray test, the more corrosion product was found to be deposited on surface of heat-treated specimen. Surface morphology of the salt spray specimen is observed under SEM and optical microscope. It reveals large numbers of corrosion pits, with heavily corroded surface. It was caused due to the decrement of the chromium content in high-strength steel with an increase of nitrocarburizing heat treatment temperature. It was observed that with an increase in heat treatment time, Vickers hardness values of 4340 steel increases from 310.8 to 468.2 HV due to increase of nitrogen (N) content over the compound layer.
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References
Pound, B.G.: Hydrogen trapping in high-strength steels. Acta Mater. 46(16), 5733 (1998)
Bhshan, B., Gupta, B.K.: Handbook of Tribology—Materials, Coatings and Surface Treatments. McGraw-Hill, New York (1991)
Celik, A., Karadeniz, S.: Investigation of compound layer formed during ion nitriding of AISI 4140 steel. Surf. Coat. Technol. 80, 283–286 (1996)
Sun, Y., Bell, T.: Plasma surface engineering of low alloy steel. Mater. Sci. Eng. A 140, 419–434 (1991)
Cho, K.S., Lee, C.O.: The effect of carbon on ion-nitriding. J. Eng. Mater. Technol. 102, 229–233 (1980)
Robino, C.V., İnal, O.T.: Ion nitriding behaviour of several low alloy steels. Mater. Sci. Eng. 59, 79–90 (1983)
Genel, K., Demirkol, M., Çapa, M.: Effect of ion nitriding on fatigue behaviour of AISI 4140 steel. Mater. Sci. Eng. A 279, 207–216 (2000)
Li, C.X., Bell, T.: Corrosion properties of active screen plasma nitrided 316 austenitic stainless steel. Corros. Sci. 46, 1527 (2004)
Xi, Y., et al.: Improvement of corrosion and wear resistances of AISI 420 martensitic stainless steel using plasma nitriding at low temperature. Surf. Coat. Technol. 202, 2577–2583 (2008)
Zhong, J., Sun, M., Liu, D., Li, X., Liu, T.: Effects of chromium on the corrosion and electrochemical behaviors of ultra-high-strength steels. Int. J. Miner. Metall. Mater. 17(3), 282 (2010)
Deng, X., Ju, D.: Prediction of phase composition and nitrogen concentration during the nitriding process in low-alloy steel. Mater. Res. http://doi.org/10.1590/1980-5373-MR-2015-0137
Sabelkin, V., Misak, H., Mall, S.: Fatigue behavior of Zn–Ni and Cd coated AISI 4340 steel with scribed damage in saltwater environment. Int. J. Fatigue 158–165 (2016)
Niazi, N., Nisar, S., Shah, A.: Austempering heat treatment of AISI 4340 steel and comparative analysis of various physical properties at different parameters. Int. J. Multi. Sci. Eng. 5(10) (2014)
Sun, M., Zhong, P.: Stress corrosion cracking of ultra-high-strength martensite steel Cr9Ni5MoCo14 in 3.5% NaCl solution. Aerosp. Sci. Technol. 125–131 (2014)
Nanninga, N., Grochowsi, J., Heldt, L., Rundman, K.: Role of microstructure, composition and hardness in resisting hydrogen embrittlement of fastener grade steels. Corros. Sci. 52, 1237–1246 (2010)
Figueroa, D., Robinson, M.J.: The effects of sacrificial coatings on hydrogen embrittlement and re-embrittlement of ultra-high-strength steels. Corros. Sci. 50, 1066–1079 (2008)
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Bhadauria, S.S., Sharma, V., Gupta, A. (2020). Investigating the Mechanical Properties and Pitting Potential of Heat-Treated AISI 4340 Steel in Various Corrosive Environments. In: Sharma, V., Dixit, U., Sørby, K., Bhardwaj, A., Trehan, R. (eds) Manufacturing Engineering . Lecture Notes on Multidisciplinary Industrial Engineering. Springer, Singapore. https://doi.org/10.1007/978-981-15-4619-8_26
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DOI: https://doi.org/10.1007/978-981-15-4619-8_26
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