The Development and Challenges of Oxidative Abatement for Contaminants of Emerging Concern

Wacławek, Stanisław; Černík, Miroslav; Dionysiou, Dionysios D.

doi:10.1007/978-981-13-9447-8_10

Stanisław Wacławek³,
Miroslav Černík³ &
Dionysios D. Dionysiou⁴

1292 Accesses
4 Citations

Abstract

For several years now, many substances that are known for saving the lives of billions of people, have paradoxically appeared as a new group of very dangerous contaminants. These compounds (for example, pharmaceuticals, pesticides, their metabolites, etc.) often have chronic and acute dangerous effects on humankind and other living beings. The presence of these pollutants is being documented and novel systems are being developed for their treatment every day. In this chapter, we review the literature from approximately the past 10 years, illustrating the decontamination of these chemicals by advanced oxidation processes (AOPs). A range of methods including novel catalytic systems for hydroxyl radical production as well as computation methods for prediction of CEC removal rate constants and their transformations are discussed. Furthermore, many (bio)transformation (by)products possess different (lower/higher) toxicological fingerprints, which can now also be assessed by advanced modelling. Moreover, many of these AOPs are limited commercially by their high capital and operating costs. All of these issues are addressed in this book chapter.

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Abbreviations

2,4-D:: 2,4-dichlorophenoxyacetic acid
ACR:: Acridine
AOPs:: Advanced Oxidation Processes
AST:: Activated Sludge Treatment
ATZ:: Atrazine
BE:: Benzocaine
BHT:: Butylated Hydroxytoluene
BPA:: Bisphenol A
BZ8:: Dioxybenzone
CAF:: Caffeine
CBZ:: Carbamazepine
CD-polymers:: Cyclodextrin polymers
CECs:: Contaminants of Emerging Concern
CFD:: Computational Fluid Dynamics
CIP:: Ciprofloxacin
CPI:: Controlled Periodic Illumination
DCF:: Diclofenac
DO:: Dissolved Oxygen
DOM:: Dissolved Organic Matter
E1:: Estrone
E2:: 17-β-Estradiol
EDCs:: Endocrine disruptors
EE/O:: Electrical energy per order for degradation
EE2:: 17-α-ethinylestradiol
EEME:: Mestranol
EU:: European Union
GBZ:: Gemfibrozil
GCN:: Graphitic Carbon Nitride
HCNNSs:: Hollow Carbon Nitride Nanospheres
HCT:: Hydrochlorothiazide
IBP:: Ibuprofen
ISCO:: In Situ Chemical Oxidation
I-TEF:: International-Toxicity Equivalency Factor
LDH:: Lactate Dehydrogenase
LDPE:: Low-Density Polyethylene
LFER:: Linear Free Energy Relationship
MTT:: Methyl-thiazolyl blue tetrazolium reduction
NP4EO:: Nonylphenol ethoxylate
NPX:: Naproxen
O₃-MB:: Ozonated microbubbles
ODZ:: Oxadiazon
OSTP:: Office of Science and Technology Policy
P4:: Progesterone
PCDD/Fs:: Polychlorinated dibenzo-p-dioxins and dibenzofurans
PDNN:: Prednisolone
PPCPs:: Pharmaceuticals and Personal Care Products
PVA:: Polyvinyl Alcohol
ROS:: Reactive Oxygen Species
TRI:: Triallate
QC:: Quantum Chemical Computations
QSARs/QSPR:: Quantitative Structure–Activity(Property) Relationships
SMX:: Sulfamethoxazole
SQX:: Sulfaquinoxaline
TBA:: Terbuthylazine
TF:: Task Force on emerging contaminants
TMP:: Trimethoprim
TPs:: Transformation Products
TCS:: Triclosan
TST:: Transition State Theory
UV:: Ultraviolet light
W/WWTP:: Water and Wastewater Treatment Plant
YAS:: Yeast Androgen Screen
YES:: Yeast Estrogen Screen

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Acknowledgements

This review was supported by the Ministry of Education, Youth and Sports in the framework of the targeted support of the OPR & DI project ‘Extension of CxI facilities’ (CZ.1.05/2.1.00/19.0386). The authors would also like to acknowledge the assistance provided by the Research Infrastructure NanoEnviCz, supported by the Ministry of Education, Youth and Sports of the Czech Republic under Project No. LM2015073. This work was also supported by the Ministry of Education, Youth and Sports of the Czech Republic and the European Union—European Structural and Investment Funds in the framework of the Operational Programme Research, Development and Education—project ‘Hybrid Materials for Hierarchical Structures’ (HyHi, Reg. No. CZ.02.1.01/0.0/0.0/16_019/0000843). D. D. Dionysiou also acknowledges support from the University of Cincinnati through a UNESCO co-Chair Professor position on ‘Water Access and Sustainability’ and the Herman Schneider Professorship in the College of Engineering and Applied Sciences.

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Centre for Nanomaterials, Advanced Technologies and Innovation, Technical University of Liberec, Studentská 1402/2, 461 17, Liberec 1, Czech Republic
Stanisław Wacławek & Miroslav Černík
Environmental Engineering and Science Program, Department of Chemical and Environmental Engineering, 705 Engineering Research Center, University of Cincinnati, Cincinnati, OH, 45221-0012, USA
Dionysios D. Dionysiou

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State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-environmental Sciences, Chinese Academy of Sciences, Beijing, China
Guibin Jiang
Department of Civil and Environmental Engineering, Faculty of Construction and Environment, The Hong Kong Polytechnic University, Hong Kong, China
Xiangdong Li

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Wacławek, S., Černík, M., Dionysiou, D.D. (2020). The Development and Challenges of Oxidative Abatement for Contaminants of Emerging Concern. In: Jiang, G., Li, X. (eds) A New Paradigm for Environmental Chemistry and Toxicology. Springer, Singapore. https://doi.org/10.1007/978-981-13-9447-8_10

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DOI: https://doi.org/10.1007/978-981-13-9447-8_10
Published: 10 August 2019
Publisher Name: Springer, Singapore
Print ISBN: 978-981-13-9446-1
Online ISBN: 978-981-13-9447-8
eBook Packages: Earth and Environmental ScienceEarth and Environmental Science (R0)

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