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Organic Molecules: Dipolar Solutes

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Solvation Dynamics

Part of the book series: Springer Series in Chemical Physics ((CHEMICAL,volume 121))

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Abstract

The excessive number of H+ or “:” and their asymmetrical distribution determines the performance of their surrounding water molecules in a way different from that of ordinary water. The naked lone pairs and protons are equally capable of interacting with the solvent H2O molecules to form O:H vdW bond, O:⇔:O super–HB or H↔H anti-HB without charge sharing or new bond forming. Solvation examination of alcohols, aldehydes, formic acids, and sugars reveals that O:H–O formation enables the solubility and hydrophilicity of alcohol; the H↔H anti-HB formation and interface structure distortion disrupt the hydration network and surface stress. The O:H phonon redshift depresses the freezing point of sugar solution of anti-icing.

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  1. School of Electrical and Electronic Engineering, Nanyang Technological University, Singapore, Singapore

    Prof. Dr. Chang Q Sun

  2. Yangtze Normal University, 408100, Chongqing, China

    Prof. Dr. Chang Q Sun

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Sun, C.Q. (2019). Organic Molecules: Dipolar Solutes. In: Solvation Dynamics. Springer Series in Chemical Physics, vol 121. Springer, Singapore. https://doi.org/10.1007/978-981-13-8441-7_7

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