Abstract
The use of nanotechnology is of prominent research interest in the construction industry. Introducing nanomaterials into cementitious systems enhances its characteristic material properties. Nano-silica is the most efficient nanomaterial in replacing cement without compromising its strength and durability. Nano-silica also enhances the properties of cement when in conjugation with other supplementary cementitious materials. Nano-silica offers high chemical reactivity and introduces filler effect in the cement matrix, thereby densifying the interfacial transition zone (ITZ) and improving the properties of cement-based materials. However, the addition of nano-silica more than the optimum dosage reduces the strength and durability. Apart from the dosage, many other parameters also influence the properties of nano-slica blended cement composites. This study deals with the changes in characteristic properties of cement and cement-based materials upon incorporation of nano-silica.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Ogbeide, S. O. (2010). Developing an optimization model for CO2 reduction in cement production process. Journal of Engineering Science and Technology Review, 3(3), 85–88.
Flores, I., Sobolev, K., Torres-Martinez, L., Cuellar, E., Valdez, P., & Zarazua, E. (2010). Performance of cement systems with nano-SiO2 particles produced by using the sol-gel method. Transportation Research Record: Journal of the Transportation Research Board, 2141, 10–14. https://doi.org/10.3141/2141-03.
Farshchi, S., Booshehrian, A., & Hosseini, P. (2010). Influence of nano-SiO2 addition on microstructure and mechanical properties of cement mortars for ferrocement. Transportation Research Record: Journal of the Transportation Research Board, 2141, 15–20. https://doi.org/10.3141/2141-04.
Hosseini, P., Afshar, A., Vafaei, B., Booshehrian, A., Molaei Raisi, E., & Esrafili, A. (2017). Effects of nano-clay particles on the short-term properties of self-compacting concrete. European Journal of Environmental and Civil Engineering, 21, 127–147. https://doi.org/10.1080/19648189.2015.1096308.
Supit, S. W. M. (2014). Shaikh FUA (2014) Effect of nano-CaCO3 on compressive strength development of high volume fly ash mortars and concretes. Journal of Advanced Concrete Technology, 12, 178–186. https://doi.org/10.3151/jact.12.178.
Li, H., Xiao, H. G., Yuan, J., & Ou, J. (2004). Microstructure of cement mortar with nano-particles. Composites Part B: Engineering, 35, 185–189. https://doi.org/10.1016/S1359-8368(03)00052-0.
Nazari, A., & Riahi, S. (2011). The role of SiO2 nanoparticles and ground granulated blast furnace slag admixtures on physical, thermal and mechanical properties of self compacting concrete. Materials Science and Engineering A, 528, 2149–2157. https://doi.org/10.1016/j.msea.2010.11.064.
Ma, B., Li, H., Mei, J., Li, X., & Chen, F. (2015). Effects of nano-TiO2 on the toughness and durability of cement-based material. Advances in Materials Science and Engineering. https://doi.org/10.1155/2015/583106.
Aly, M., Hashmi, M. S. J., Olabi, A. G., Messeiry, M., & Hussain, A. I. (2011). Effect of nano clay particles on mechanical, thermal and physical behaviours of waste-glass cement mortars. Materials Science and Engineering A, 528, 7991–7998. https://doi.org/10.1016/j.msea.2011.07.058.
Sanchez, F., & Sobolev, K. (2010). Nanotechnology in concrete—A review. Construction and Building Materials, 24, 2060–2071. https://doi.org/10.1016/j.conbuildmat.2010.03.014.
Aly, M., Hashmi, M. S. J., Olabi, A. G., Messeiry, M., Abadir, E. F., & Hussain, A. I. (2012). Effect of colloidal nano-silica on the mechanical and physical behaviour of waste-glass cement mortar. Materials and Design, 33, 127–135. https://doi.org/10.1016/j.matdes.2011.07.008.
Mohamed, A. M. (2016). Influence of nano materials on flexural behavior and compressive strength of concrete. HBRC J., 12, 212–225. https://doi.org/10.1016/j.hbrcj.2014.11.006.
Givi, A. N., Rashid, S. A., & Aziz, F. N. A. (2010). Salleh MAM (2010) Experimental investigation of the size effects of SiO2 nano-particles on the mechanical properties of binary blended concrete. Composites Part B: Engineering, 41, 673–677. https://doi.org/10.1016/j.compositesb.2010.08.003.
Heidari, A., & Tavakoli, D. (2013). A study of the mechanical properties of ground ceramic powder concrete incorporating nano-SiO2 particles. Construction and Building Materials, 38, 255–264. https://doi.org/10.1016/j.conbuildmat.2012.07.110.
Kawashima, S., Hou, P., Corr, D. J., & Shah, S. P. (2013). Modification of cement-based materials with nanoparticles. Cement and Concrete Composites, 36, 8–15. https://doi.org/10.1016/j.cemconcomp.2012.06.012.
Stefanidou, M., & Papayianni, I. (2012). Influence of nano-SiO2 on the Portland cement pastes. Composites Part B: Engineering, 43, 2706–2710. https://doi.org/10.1016/j.compositesb.2011.12.015.
Kong, D., Du, X., Wei, S., Zhang, H., Yang, Y., & Shah, S. P. (2012). Influence of nano-silica agglomeration on microstructure and properties of the hardened cement-based materials. Construction and Building Materials, 37, 707–715. https://doi.org/10.1016/j.conbuildmat.2012.08.006.
Oltulu, M., & Şahin, R. (2013). Effect of nano-SiO2, nano-Al2O3 and nano-Fe2O3 powders on compressive strengths and capillary water absorption of cement mortar containing fly ash: A comparative study. Energy and Buildings, 58, 292–301. https://doi.org/10.1016/j.enbuild.2012.12.014.
Pourjavadi, A., Fakoorpoor, S. M., Khaloo, A., & Hosseini, P. (2012). Improving the performance of cement-based composites containing superabsorbent polymers by utilization of nano-SiO2 particles. Materials and Design, 42, 94–101. https://doi.org/10.1016/j.matdes.2012.05.030.
Zhang, M. H., Islam, J., & Peethamparan, S. (2012). Use of nano-silica to increase early strength and reduce setting time of concretes with high volumes of slag. Cement and Concrete Composites, 34, 650–662. https://doi.org/10.1016/j.cemconcomp.2012.02.005.
Li, H., Zhang, M., & Ou, J. (2006). Abrasion resistance of concrete containing nano-particles for pavement. Wear, 260, 1262–1266.
Ltifi, M., Guefrech, A., Mounanga, P., & Khelidj, A. (2011). Experimental study of the effect of addition of nano-silica on the behaviour of cement mortars. Procedia Engineering, 10, 900–905. https://doi.org/10.1016/j.proeng.2011.04.148.
Gesoglu, M., Güneyisi, E., Asaad, D. S., & Muhyaddin, G. F. (2016). Properties of low binder ultra-high performance cementitious composites: comparison of nanosilica and microsilica. Construction and Building Materials, 102, 706–713. https://doi.org/10.1016/j.conbuildmat.2015.11.020.
Hou, P., Kawashima, S., Kong, D., Corr, D. J., Qian, J., & Shah, S. P. (2013). Modification effects of colloidal nano SiO2 on cement hydration and its gel property. Composites Part B: Engineering, 45, 440–448. https://doi.org/10.1016/j.compositesb.2012.05.056.
Sharkawi, A. M., Abd-Elaty, M. A., & Khalifa, O. H. (2018). Synergistic influence of micro-nano silica mixture on durability performance of cementious materials. Construction and Building Materials, 164, 579–588. https://doi.org/10.1016/j.conbuildmat.2018.01.013.
Flores, Y. C., Cordeiro, G. C., Toledo Filho, R. D., & Tavares, L. M. (2017). Performance of Portland cement pastes containing nano-silica and different types of silica. Construction and Building Materials, 146, 524–530. https://doi.org/10.1016/j.conbuildmat.2017.04.069.
Rupasinghe, M., San Nicolas, R., Mendis, P., Sofi, M., & Ngo, T. (2017). Investigation of strength and hydration characteristics in nano-silica incorporated cement paste. Cement and Concrete Composites, 80, 17–30. https://doi.org/10.1016/j.cemconcomp.2017.02.011.
Barkoula, N. M., Ioannou, C., Aggelis, D. G., & Matikas, T. E. (2016). Optimization of nano-silica’s addition in cement mortars and assessment of the failure process using acoustic emission monitoring. Construction and Building Materials, 125, 546–552. https://doi.org/10.1016/j.conbuildmat.2016.08.055.
Cai, Y., Hou, P., Cheng, X., Du, P., & Ye, Z. (2017). The effects of nano SiO2 on the properties of fresh and hardened cement-based materials through its dispersion with silica fume. Construction and Building Materials, 148, 770–780. https://doi.org/10.1016/j.conbuildmat.2017.05.091.
Mei, J., Ma, B., Tan, H., Li, H., Liu, X., Jiang, W., et al. (2018). Influence of steam curing and nano silica on hydration and microstructure characteristics of high volume fly ash cement system. Construction and Building Materials, 171, 83–95. https://doi.org/10.1016/j.conbuildmat.2018.03.056.
Berra, M., Carassiti, F., Mangialardi, T., Paolini, A. E., & Sebastiani, M. (2012). Effects of nanosilica addition on workability and compressive strength of Portland cement pastes. Construction and Building Materials, 35, 666–675. https://doi.org/10.1016/j.conbuildmat.2012.04.132.
Lin, K. L., Chang, W. C., Lin, D. F., Luo, H. L., & Tsai, M. C. (2008). Effects of nano-SiO2 and different ash particle sizes on sludge ash-cement mortar. Journal of Environmental Management, 88, 708–714. https://doi.org/10.1016/j.jenvman.2007.03.036.
Senff, L., Labrincha, J. A., Ferreira, V. M., Hotza, D., & Repette, W. L. (2009). Effect of nano-silica on rheology and fresh properties of cement pastes and mortars. Construction and Building Materials, 23, 2487–2491. https://doi.org/10.1016/j.conbuildmat.2009.02.005.
Ganesh Rathod, N., Moharana, N. C., & Parashar, S. K. S. (2018). Effect of nano-SiO2 on physical and electrical properties of PPC cement using complex impedance spectroscopy. Materials Today: Proceedings, 5, 193–199. https://doi.org/10.1016/j.matpr.2017.11.071.
Mohammed, B. S., Liew, M. S., Alaloul, W. S., Khed, V. C., Hoong, C. Y., & Adamu, M. (2018). Properties of nano-silica modified pervious concrete. Case studies in construction materials, 8, 409–422. https://doi.org/10.1016/j.cscm.2018.03.009.
Hanif, A., Parthasarathy, P., Ma, H., Fan, T., & Li, Z. (2017). Properties improvement of fly ash cenosphere modified cement pastes using nano silica. Cement and Concrete Composites, 81, 35–48. https://doi.org/10.1016/j.cemconcomp.2017.04.008.
Shaikh, F. U. A., Shafaei, Y., & Sarker, P. K. (2016). Effect of nano and micro-silica on bond behaviour of steel and polypropylene fibres in high volume fly ash mortar. Construction and Building Materials, 115, 690–698. https://doi.org/10.1016/j.conbuildmat.2016.04.090.
Li, L. G., Huang, Z. H., Zhu, J., Kwan, A. K. H., & Chen, H. Y. (2017). Synergistic effects of micro-silica and nano-silica on strength and microstructure of mortar. Construction and Building Materials, 140, 229–238. https://doi.org/10.1016/j.conbuildmat.2017.02.115.
Atahan, H. N., & Arslan, K. M. (2016). Improved durability of cement mortars exposed to external sulfate attack: The role of nano and micro additives. Sustainable Cities and Society, 22, 40–48. https://doi.org/10.1016/j.scs.2016.01.008.
Chithra, S., & Senthil Kumar, S. R. R. (2016). Chinnaraju K (2016) The effect of colloidal nano-silica on workability, mechanical and durability properties of high performance concrete with copper slag as partial fine aggregate. Construction and Building Materials, 113, 794–804. https://doi.org/10.1016/j.conbuildmat.2016.03.119.
Fathi, M., Yousefipour, A., & Hematpoury Farokhy, E. (2017). Mechanical and physical properties of expanded polystyrene structural concretes containing Micro-silica and Nano-silica. Construction and Building Materials, 136, 590–597. https://doi.org/10.1016/j.conbuildmat.2017.01.040.
Isfahani, F. T., Redaelli, E., Lollini, F., Li, W., & Bertolini, L. (2016). Effects of nanosilica on compressive strength and durability properties of concrete with different water to binder ratios. Advances in Materials Science and Engineering. https://doi.org/10.1155/2016/8453567.
Mukharjee, B. B., & Barai, S. V. (2015). Development of construction materials using nano-silica and aggregates recycled from construction and demolition waste. Waste Management and Research, 33, 515–523. https://doi.org/10.1177/0734242X15584840.
Durgun, M. Y., & Atahan, H. N. (2018). Strength, elastic and microstructural properties of SCCs’ with colloidal nano silica addition. Construction and Building Materials, 158, 295–307. https://doi.org/10.1016/j.conbuildmat.2017.10.041.
Li, L. G., Zheng, J. Y., Zhu, J., & Kwan, A. K. H. (2018). Combined usage of micro-silica and nano-silica in concrete: SP demand, cementing efficiencies and synergistic effect. Construction and Building Materials, 168, 622–632. https://doi.org/10.1016/j.conbuildmat.2018.02.181.
Son, H. M., Park, S. M., Jang, J. G., & Lee, H. K. (2018). Effect of nano-silica on hydration and conversion of calcium aluminate cement. Construction and Building Materials, 169, 819–825. https://doi.org/10.1016/j.conbuildmat.2018.03.011.
Adamu, M., Mohammed, B. S., & Shahir Liew, M. (2018). Mechanical properties and performance of high volume fly ash roller compacted concrete containing crumb rubber and nano silica. Construction and Building Materials, 171, 521–538. https://doi.org/10.1016/j.conbuildmat.2018.03.138.
Erdem, S., Hanbay, S., & Güler, Z. (2018). Micromechanical damage analysis and engineering performance of concrete with colloidal nano-silica and demolished concrete aggregates. Construction and Building Materials, 171, 634–642. https://doi.org/10.1016/j.conbuildmat.2018.03.197.
Atmaca, N., Abbas, M. L., & Atmaca, A. (2017). Effects of nano-silica on the gas permeability, durability and mechanical properties of high-strength lightweight concrete. Construction and Building Materials, 147, 17–26. https://doi.org/10.1016/j.conbuildmat.2017.04.156.
Güneyisi, E., Gesoglu, M., Azez, O. A., & Öz, H. Ö. (2016). Effect of nano silica on the workability of self-compacting concretes having untreated and surface treated lightweight aggregates. Construction and Building Materials, 115, 371–380. https://doi.org/10.1016/j.conbuildmat.2016.04.055.
El, S. A., Kishar, E. A., & Zedan, S. R. (2016). Mohamed RA Effect of nano-SiO2 (NS) on dolomite concrete towards alkali silica reaction. HBRC J, 2, 2–7. https://doi.org/10.1016/j.hbrcj.2016.08.004.
Zabihi, N., & Hulusi Ozkul, M. (2018). The fresh properties of nano silica incorporating polymer-modified cement pastes. Construction and Building Materials, 168, 570–579. https://doi.org/10.1016/j.conbuildmat.2018.02.084.
Massana, J., Reyes, E., Bernal, J., León, N., & Sánchez-Espinosa, E. (2018). Influence of nano- and micro-silica additions on the durability of a high-performance self-compacting concrete. Construction and Building Materials, 165, 93–103. https://doi.org/10.1016/j.conbuildmat.2017.12.100.
Liu, M., Zhou, Z., Zhang, X., Yang, X., & Cheng, X. (2016). The synergistic effect of nano-silica with blast furnace slag in cement based materials. Construction and Building Materials, 126, 624–631. https://doi.org/10.1016/j.conbuildmat.2016.09.078.
Muthu, M., & Santhanam, M. (2018). Effect of reduced graphene oxide, alumina and silica nanoparticles on the deterioration characteristics of Portland cement paste exposed to acidic environment. Cement and Concrete Composites, 91, 118–137. https://doi.org/10.1016/j.cemconcomp.2018.05.005.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2019 Springer Nature Singapore Pte Ltd.
About this paper
Cite this paper
Varghese, J., Gopinath, A., Bahurudeen, A., Senthilkumar, R. (2019). Influence of Nano-Silica on Characteristics of Cement Mortar and Concrete. In: Das, B., Neithalath, N. (eds) Sustainable Construction and Building Materials. Lecture Notes in Civil Engineering , vol 25. Springer, Singapore. https://doi.org/10.1007/978-981-13-3317-0_75
Download citation
DOI: https://doi.org/10.1007/978-981-13-3317-0_75
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-13-3316-3
Online ISBN: 978-981-13-3317-0
eBook Packages: EngineeringEngineering (R0)