Abstract
This chapter will present a brief overview of the current sensors for VOC detection, in particular formaldehyde which has become one of the most problematic gases in indoor air. Many sensing technologies were exploited for this purpose but, in this chapter, we will focus on the impedimetric sensors. These sensors consist in a sensitive layer deposited on an insulating substrate fitted with a pair of electrodes. The detection is based on the change of conductivity of the sensitive layer due to surface interactions with the target gas provoking an electron transfer. This kind of sensor acts as a simple variable resistance and is often called chemiresistor. By principle, these sensors are simple, easy to integrate in classical electronics and cheap. Considering the nature of the sensitive coating, we can distinguish several families: metal oxide sensors, semiconductor polymer sensors or based on graphene. All 3 types of sensors will be described in this chapter.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsReferences
IARC, [Formaldehyde, 2-Butoxyethanol and 1-tert-Butoxypropan-2-ol. (2006) IARC monographs on the evaluation of carcinogenic risks to humans, vol. 88], World Health Organization, Lyon, 39–325
World Health Organization (2010) Regional Office for Europe, “WHO guidelines for indoor air quality: selected pollutants”, Geneva, ISBN: 9789289002134
Vairavamurthy A, Roberts JM, Newman L (1992) Methods for determination of low molecular weight compounds in the atmosphere: a review. Atmos Environ 26A:1965–1993
Chung PR, Tzeng CT et al (2013) Formaldehyde gas sensors: a review. Sensors 13:4468–4484
Fleet B, Gunasingham H (1992) Electrochemical sensors for monitoring environmental pollutants. Talanta 39:1449–1457
Sato T, Plashnitsa VV, Utiyama M, Miura (2010) N Potentiometric YSZ-based sensor using NiO sensing electrode aiming at detection of volatile organic compounds (VOCs) in air environment. Electrochem Commun 12:524–526
Mead MI, Popoola OAM et al (2013) The use of electrochemical sensors for monitoring urban air quality in low-cost, high-density networks. Atmos Environ 70:186–203
Si P, Mortensen J, Komolov A et al (2007) Polymer coated quartz crystal microbalance sensors for detection of volatile organic compounds in gas mixtures. Anal Chim Acta 597:223–230
Shafiq Islam AKM, Ismail Z et al (2005) Transient parameters of a coated quartz crystal microbalance sensor for the detection of volatile organic compounds (VOCs). Sensors Actuators B109:238–243
Khot LR, Panigrahi S, Lin D (2011) Development and evaluation of piezoelectric-polymer thin film sensors for low concentration detection of volatile organic compounds related to food safety applications. Sensors Actuators B Chem 153:1–10
Fan X, Du B (2012) Selective detection of trace p-xylene by polymer-coated QCM sensors. Sensors Actuators B166–167:753–760
Clifford KH, Lindgren RE et al (2003) Development of a surface acoustic wave sensor for in-situ monitoring of volatile organic compounds. Sensors 3:236–247
Fang M, Vetelino K, Rothery M et al (1999) Detection of organic chemicals by SAW sensor array. Sensors Actuators B56:155–157
Fernández MJ, Fontecha JL, Sayago I et al (2007) Discrimination of volatile compounds through an electronic nose based on ZnO SAW sensors. Sensors Actuators B127:277–283
Wolfbeis OS (2002) Fiber-optic chemical sensors and biosensors. Anal Chem 74:2663–2678
Elosua C, Matias IR, Bariain C et al (2006) Volatile organic compound optical fiber sensors: a review. Sensors 6:1440–1465
Yoon J, Chae SK, Kim JM (2007) Colorimetric sensors for volatile organic compounds (VOCs) based on conjugated polymer-embedded electrospun fibers. J Am Chem Soc 129:3038–3039
González-Vila Á, Debliquy M, Lahem D et al (2017) Molecularly imprinted electropolymerization on a metal-coated optical fiber for gas sensing applications. Sensors Actuators B244:1145–1151
Patel SV, Mlsna TE et al (2003) Chemicapacitive microsensors for volatile organic compound detection. Sensors Actuators B96:541–553
Lee DS, Jung JK, Lim J. W et al (2001) Recognition of volatile organic compounds using SnO2 sensor array and pattern recognition analysis. Sensors Actuators B77: 228–236
Zhang WM, Hu JS et al (2007) Detection of VOCs and their concentrations by a single SnO2sensor using kinetic information. Sensors Actuators B123:454–460
Mishra RK, Sahay PP (2012) Synthesis characterization and alcohol sensing property of Zn-doped SnO2 nanoparticles. Ceram Int 38:2295–2304
Zeng W, Tian-Mo L (2010) Gas-sensing properties of SnO2–TiO2-based sensor for volatile organic compound gas and its sensing mechanism. Phys B Condens Matter 405:1345–1348
Lahem D, Lontio FR et al (2016) Formaldehyde gas sensor based on nanostructured nickel oxide and the microstructure effects on its response. In: IC-MAST2015 IOP Conf. Series: materials science and engineering 108
Zhang YM, Lin YT et al (2014) A high sensitivity gas sensor for formaldehyde based on silver doped lanthanum ferrite. Sensors Actuators B190:171–176
Neri G (2015) First fifty years of chemoresistive gas sensors. Chemosensors 3:1–20
Moseley PT, Norris J, Williams DE (1991) Techniques and mechanisms in gas sensing. In: Adam Hilger
Korotcenkov G, Cho BK (2017) Metal oxide composites in conductometric gas sensors: achievements and challenges. Sensors Actuators B 244:182–210
Kanan SM, El-Kadri OM et al (2009) Semiconducting metal oxide based sensors for selective gas pollutant detection. Sensors 9:8158–8196
Decroly A, Krumpmann A, Debliquy M et al (2016) Nanostructured TiO2 Layers for Photovoltaic and Gas Sensing Applications, INTECH Book “Green Nanotechnology”. ISBN 978-953-51-4692-6
Seiyama T, Kato A (1962) A new detector for gaseous components using semiconductor thin film. Anal Chem 34:1502–1503
Seiyama T (1988) Chemical sensors-current status and future outlook. In: Seiyama T (ed) Chemical Sensor Technology, vol 1. Elsevier, Amsterdam
Yamazoe N (1991) New approaches for improving semiconductor gas sensors. Sensors Actuators B Chem 5:7–19
Shimizu Y, Egashira M (1999) Basic aspects and challenges of semiconductor gas sensors. MRS Bull 24:18–24
Yamazoe N (2005) Toward innovations of gas sensor technology. Sensors Actuators B108:2–14
Gurlo A, Bârsan N, Weimar U (2006) In: Fierro JLG (ed) Gas sensors based on semiconductiong metal oxides. In metal oxides: chemistry and applications. CRC Press, Boca Raton, p 683
Aleixandre M, Gerboles M (2012) Review of small commercial sensors for indicative monitoring of ambient gas. Chem Eng Trans 30:169–174
Bârsan N, Hübner M, Weimar U (2011) Conduction mechanisms in SnO2 based polycrystalline thick film gas sensors exposed to CO and H2 in different oxygen backgrounds. Sensors Actuators B 157:510–517
Bârsan N, Tomescu A (1995) Calibration Procedure for SnO2-based Gas Sensors. Thin Solid Films 259:91–95
Niebling G, Schlachter A (1995) Qualitative and quantitative gas analysis with non-linear interdigital sensor arrays and artificial neural networks. Sensors and Actuators B26–27:289
Yamaura H, Tamaki J, Moriya K et al (1997) Highly selective CO sensor using indium oxide doubly promoted by cobalt oxide and gold. J Electrochem Soc 144
Mochida T, Kikuchi K, Kondo T, Ueno H, Matsuura Y (1995) Highly sensitive and selective H2S gas sensor from r.f. sputtered SnO2 thin film. Sensors Actuators B 25:433–437
Tricoli A, Righettoni M, Pratsinis SE (2009) Minimal cross-sensitivity to humidity during ethanol detection by SnO2-TiO2 solid solutions. Nanotechnology 20:315502
Cederquist A, Gibbons E, Meitzler A (1976) Characterization of Zirconia and Titania Engine Exhaust Gas Sensors for air/fuel feedback control systems. SAR Tech Pap. https://doi.org/10.4271/7602
Kolmakov A, Moskovits M (2004) Chemical sensing and catalysis by one-dimensional metal-oxide nanostructures. Annu Rev Mater Res 34:151–180
Arafat MM, Dinan B et al (2012) Gas sensors based on one dimensional nanostructured metal-oxides: a review. Sensors 12:7207–7258
Thong LV, Hoa ND et al (2010) On-chip fabrication of SnO2-nanowire gas sensor: the effect of growth time on sensor performance. Sensors Actuators B Chem 146:361–367
Huang MH, Mao S, Feick H et al (2001) Room-temperature ultraviolet nanowire nanolasers. Science 292:1897–1899
Yang Z, Li LM, Wan Q et al (2008) High-performance ethanol sensing based on an aligned assembly of ZnO nanorods. Sensors Actuators B Chem 135:57–60
Wan Q, Li QH, Chen YJ et al (2004) Fabrication and ethanol sensing characteristics of ZnO nanowire gas sensors. Appl Phys Lett 84:3654–3656
Jones T, Bott B, Thorpe S (1989) Fast response metal phthalocyanine-based gas sensors. Sensors Actuators B 17:467–474
Simon J, André JJ (1985) Molecular semiconductors. Springer, Berlin/Heidelberg
Wright JD (1991) Gas adsorption on phthalocyanines and its effects on electrical properties. Prog Surf Sci 31:1–60
Mukhopadhyay S, Hogarth CA (1994) Gas sensing properties of phthalocyanine Langmuir–Blodgett films. Adv Mater 6:162–164
Capone S, Mongelli S et al (1999) Gas sensitivity measurements on NO2 sensors based on Copper(II) tetrakis(n-butylaminocarbonyl) phthalocyanine LB films. Langmuir 15:1748–1753
Simon J, Bouvet M, Bassoul P (1994) The encyclopedia of advanced materials. Pergamon, Oxford, pp 1680–1692
Rodriguez-Mendez ML, Aroca R, Desaja JA (1993) Electrochromic and gas adsorption properties of Langmuir-Blodgett films of lutetium bisphthalocyanine complexes. Chem Mater 5(7):933–937
Weiss R, Fischer J (2006) Lanthanide phthalocyanine complexes. The porphyrin handbook, 1st ed., vol. 16, Kadish K, Smith KM, Guilard R (eds); Academic Press Inc., New York, pp 171–246
Paolo Bondavallia P, Legagneux P, Pribat D (2009) Carbon nanotubes based transistors as gas sensors: state of the art and critical review. Sensors Actuators B 140:304–318
Espinosa EH, Ionescu R, Chambon B et al (2007) Hybrid metal oxide and multiwall carbon nanotube films for low temperature gas sensing. Sensors Actuators B 127:137–142
Helbling T, Pohle R, Durrer L et al (2008) Sensing NO2 with individual suspended single-walled carbon nanotubes. Sensors Actuators B 132:491–497
Bittencourt C, Felten A, Espinosa EH et al (2006) Evaporation of WO3 on carbon nanotube films: a new hybrid film. Smart Mater Struct 15:1555–1560
Ionescu R, Espinosa EH et al (2006) Oxygen functionalisation of MWNT and their use as gas sensitive thick-film layers. Sensors Actuators B 113:36–46
Mu H, Zhang Z et al (2014) High sensitive formaldehyde graphene gas sensor modified by atomic layer deposition zinc oxide films. Appl Phys Lett 105:033107
Zhua BL, Xie CS, Wu J et al (2006) Influence of Sb, In and Bi dopants on the response of ZnO thick films to VOC’s. Mater Chem Phys 96:459–465
Elmi I, Zampolli S et al (2008) Development of ultra-low-power consumption MOX sensors with ppb-level VOC detection capabilities for emerging applications. Sensors Actuators B Chem 135:342–351
Daza L, Dassy S, Delmon B (1993) Chemical sensors based on SnO2 and WO3 for the detection of formaldehyde: cooperative effects. Sensors Actuators B Chem 10:99–105
Lee DS, Jung JK et al (2001) Recognition of volatile organic compounds using SnO2 sensor array and pattern recognition analysis. Sensors Actuators B 77:228–236
Zhu BL, Xie CS, Wang WY (2004) Improvement in gas sensitivity of ZnO thick film to volatile organic compounds (VOCs) by adding TiO2. Mater Lett 58:624–629
Srivastava AK (2003) Detection of volatile organic compounds (VOCs) using SnO2 gas-sensor array and artificial neural network. Sensors Actuators B 96:24–37
Lai X, Wang D et al (2010) Ordered arrays of bead-chain-like In2O3 nanorods and their enhanced sensing performance for formaldehyde. Chem Mater 22:3033–3042
Castro-Hurtado I, Herrán J et al (2011) Studies of influence of structural properties and thickness of NiO thin films on formaldehyde detection. Thin Solid Films 520:947–952
Gou X, Wang G et al (2008) Chemical synthesis, characterisation and gas sensing performance of copper oxide nanoribbons. J Mater Chem 18:965–969
Dirksen JA, Duval K, Ring TA (2001) NiO thin film formaldehyde gas sensor. Sensors Actuators B Chem 80:106–115
Lee CY, Chiang CM, Wang YH et al (2007) A self-heating gas sensor with integrated NiO thin film for formaldehyde detection. Sensors Actuators B Chem 122:503–510
Lahem D, Lontio FR et al (2016) Formaldehyde gas sensor based on nanostructured nickel oxide and the microstructure effects on its response. In: Proceedings IC-MAST2015 IOP Conf. Series: materials science and engineering 108
Zhang L, Hu JF et al (2005) Formaldehyde sensing characteristics of perovskite La0.68Pb0.32FeO3 nano-materials. Physica B 370:259–263
Wang J, Liu L, Cong SY et al (2008) An enrichment method to detect low concentration formaldehyde. Sensors Actuators B Chem 134:1010–1015
Wang J, Zhang P et al (2009) Silicon-based micro-gas sensors for detecting formaldehyde. Sensors Actuators B Chem 136:399–404
Lv P, Tang ZA et al (2008) Study on a microgas sensor with SnO2–NiO sensitive film for indoor formaldehyde detection. Sensors Actuators B Chem 132:74–80
Han N, Tian Y, Wu X et al (2009) Improving humidity selectivity in formaldehyde gas sensing by a two-sensor array made of Ga-doped ZnO. Sensors Actuators B Chem 138:228–235
Han N, Chai L, Wang Q et al (2010) Evaluating the doping effect of Fe, Ti and Sn on gas sensing property of ZnO. Sensors Actuators B Chem 147:525–530
Chen T, Zhou Z, Wang Y (2008) Effects of calcining temperature on the phase structure and the formaldehyde gas sensing properties of CdO-mixed In2O3. Sensors Actuators B Chem 135:219–223
Huang S, Qin H, Song P et al (2007) The formaldehyde sensitivity of LaFe1−xZnxO3-based gas sensor. J Mater Sci 42:9973–9977
Zeng W, Tianmo Liu T et al (2009) Selective detection of formaldehyde gas using a Cd-doped TiO2-SnO2 sensor. Sensors 9:9029–9038
Wollenstein J, Plaza JA et al (2003) A novel single chip thin film metal oxide array. Sensors Actuators B Chem 93:350–355
Lee CY, Chiang CM, Chou PC et al (2005) A novel microfabricated formaldehyde gas sensor with NiO thin film, sensors for industry conference p, pp 1–5
Wang YH, Lee CY et al (2008) Enhanced sensing characteristics in MEMS-based formaldehyde gas sensors. Microsyst Technol 14:995–1000
Lin S, Li D et al (2011) A selective room temperature formaldehyde gas sensor using TiO2 nanotube arrays. Sensors Actuators B 156:505–509
Peng L, Zhao Q et al (2009) Ultraviolet-assisted gas sensing: a potential formaldehyde detection approach at room temperature based on zinc oxide nanorods. Sensors Actuators B 136:80–85
Mu H, Zhang Z et al (2014) Highly sensitive formaldehyde graphene gas sensor modified by atomic layer deposition zinc oxide films. Appl Phys Lett 105:033107
Adhikari B, Majumdar S (2004) Polymers in sensor applications. Prog Polym Sci 29:699–766
Bartlett PN, Archer PB et al (1989) Conducting polymer gas sensors Part I: fabrication and characterization. Sensors Actuators B Chem 19:125–140
Bartlett PN, Sk L-C (1989) Conducting polymer gas sensors Part II: response of polypyrrole to methanol vapour. Sensors Actuators B Chem 19:141–150
Bartlett PN, Sk L-C (1989) Conducting polymer gas sensors Part III: results for four different polymers and five different vapours. Sensors Actuators B Chem 20:287–292
Agbor NE, Petty MC et al (1995) Polyaniline thin films for gas sensing. Sensors Actuators B Chem 28:173–179
Anitha G, Subramanian E (2005) Recognition and exposition of intermolecular inter-action between CH2Cl2 and CHCl3 by conducting polyaniline materials. Sensors Actuators B Chem 107:605–615
Li ZF, Blum FD, Bertino MF et al (2008) One-step fabrication of a polyaniline nanofiber vapor sensor. Sensors Actuators B Chem 134:31–35
Antwi-Boampong S, Bel Bruno JJ (2013) Detection of formaldehyde vapor using conductive polymer films. Sensors Actuators B Chem 182:300–306
Lange U, Roznyatovskaya NV, Mirsky VM (2008) Conducting polymers in chemical sensors and arrays. Anal Chim Acta 614:1–26
Guadarrama A, Rodrıguez-Méndez ML et al (2001) Electronic nose based on conducting polymers for the quality control of the olive oil aroma: discrimination of quality, variety of olive and geographic origin. Anal Chim Acta 432:283–292
Haupt K, Linares AV et al (2011) In: Haupt K (ed) Molecularly imprinted polymers. Springer, Berlin Heidelberg, pp 1–28
Vasapollo G, Del Sole R et al (2011) Molecularly imprinted polymers: present and future prospective. Int J Mol Sci 12:5908–5945
Kröger S, Tumer APF et al (1999) Imprinted polymerbased sensor system for herbicides using differential-pulse voltammetry on screen-printed electrodes. Anal Chem 71:3698–3702
Luo C, Liu M, Mo Y et al (2001) Thickness-shear mode acoustic sensor for atrazine using molecularly imprinted polymer as recognition element. Anal Chim Acta 428:143–148
Tan Y, Yin J, Liang C et al (2001) A study of a new TSM bio-mimetic sensor using a molecularly imprinted polymer coating and its application for the determination of nicotine in human serum and urine. Bioelectrochemistry 53:141–148
Manbohi A, Shamaeli E, Alizadeh N (2014) Nanostructured conducting molecularly imprinted polypyrrole film as a selective sorbent for benzoate ion and its application in spectrophotometric analysis of beverage samples. Food Chem 155:186–191
Justino CIL, Freitas AC et al (2015) Recent developments in recognition elements for chemical sensors and biosensors. TrAC—Trends Anal Chem 68:2–17
Whitcombe MJ, Kirsch N, Nicholls IA (2014) Molecular imprinting science andtechnology: a survey of the literature for the years 2004–2011. J Mol Recognit 27:297–401
Sharma PS, D’Souza F, Kutner W (2012) Molecular imprinting for selective chemical sensing of hazardous compounds and drugs of abuse. TrAC—TrendsAnal Chem 34:59–76
Hirayama K, Sakai Y, Kameoka K et al (2002) Preparation of a sensor device with specific recognition sites for acetaldehyde by molecular imprinting technique. Sensors Actuators B 86:20–25
Ihdene Z, Mekki A et al (2014) Quartz crystal microbalance VOCs sensor based on dip coated polyaniline emeraldine salt thin films. Sensors Actuators B 203:647–654
Wu N, Feng L et al (2009) An optical reflected device using a molecularly imprinted polymer film sensor. Anal Chim Acta 653:103–108
Lépinay S, Ianoul A, Albert J (2014) Molecular imprinted polymer-coated optical fiber sensor for the identification of low molecular weight molecules. Talanta 128:401–407
Cennamo N, Donà A, Pallavicini P et al (2015) Sensitive detection of 2,4,6-trinitrotoluene by tridimensional monitoring of molecularly imprinted polymer with optical fiber and five-branched gold nanostars. Sens Actuators B 208:291–298
Debliquy M, Dony N et al (2016) Acetaldehyde chemical sensor based on molecularly imprinted polypyrrole. Procedia Eng 168:569–573
Tang X, Raskin JP, Lahem D (2017) A formaldehyde sensor based on molecularly-imprinted polymer on a TiO2, nanotube array. Sensors 17:675
Schedin F, Geim AK et al (2007) Detection of individual gas molecules absorbed on graphene. Nat Mater 6(9):652–655
Chen CW, Hung SC et al (2011) Oxygen sensors made by monolayer graphene under room temperature. Appl Phys Lett 99(24):243502
Fowler JD, Matthew JA, Tung VC et al (2009) Practical chemical sensors from chemically derived graphene. ACS Nano 3(2):301–306
Juree H, Lee S et al (2015) A highly sensitive hydrogen sensor with gas selectivity using a PMMA membrane-coated Pd nanoparticle/single-layer graphene hybrid.” ACS Appl Mater Interfaces, 150209062057005
Pandey PA, Wilson NR, Covington JA (2013) Pd-doped reduced graphene oxide sensing films for H2 detection. Sensors Actuators B Chem 183:478–487
Lu G, Ocola LE, Chen J (2009) Reduced graphene oxide for room temperature gas sensors. Nanotechnology 20:445502
Hu N, Yang Z. Wang Y et al (2014) Ultrafast and sensitive room temperature NH3 gas sensors based on chemically reduced graphene oxide. Nanotechnology 25, no. 2:025502
Le H, Zhang Z et al (2015) Multifunctional graphene sensors for magnetic and hydrogen detection. ACS Appl Mater Interfaces 7(18):9581–9588
Wang T, Da H, Zhi Y et al (2016) A review on graphene-based gas/vapor sensors with unique properties and potential applications. Nano-Micro Lett 8(2):95–119
Tahe A, Soltani LH (2013) Graphene/poly(methylMethacrylate) chemiresistor sensor for formaldehyde odor sensing. J Hazard Mater 248–249:401–406
Schedin F, Geim AK, Morozov SV et al (2007) Detection of individual gas molecules absorbed on graphene. Nat Mater 6(9):652–655
Wangyang F, Jiang L, van Geest EP et al (2017) Sensing at the surface of graphene field-effect transistors. Adv Mater 29(6):1603610
Sergey R, Liu G, Shur MS, Potyrailo RA, Balandin AA (2012) Selective gas sensing with a single pristine graphene transistor. Nano Lett 12(5):2294–2298
Elias DC,. Nair RR, Mohiuddin TMG et al (2009) Control of graphene’s properties by reversible hydrogenation: evidence for graphane. Science 323(5914):610–613
Bo L, Zhou L et al (2011) Photochemical chlorination of graphene. ACS Nano 5:5957–5961
Dimiev AM, Tour JM (2014) Mechanism of graphene oxide formation. ACS Nano 8(3):3060–3068
Wei F, Long P et al (2016) Two-dimensional fluorinated graphene: synthesis, structures, properties and applications. Adv Sci 3:1500413
Hang Z, Bekyarova E et al (2011) Aryl functionalization as a route to band gap engineering in single layer graphene devices. Nano Lett 11:4047–4051
Milowska KZ, Majewski JA (2013) Stability and electronic structure of covalently functionalized graphene layers: covalently functionalized graphene layers. Phys Status Solidi B 250:1474–1477
Lin C-T, Loan PTK et al (2013) Label-free electrical detection of DNA hybridization on graphene using hall effect measurements: revisiting the sensing mechanism. Adv Funct Mater 23:2301–2307
Ye L, Goldsmith BR, Kybert NJ et al (2010) DNA-decorated graphene chemical sensors. Appl Phys Lett 97:083107
Lerner MB, Matsunaga F et al (2014) Scalable production of highly sensitive nanosensors based on graphene functionalized with a designed G protein-coupled receptor. Nano Lett 14:2709–2714
Lingyan F, Wu L et al (2012) Detection of a prognostic indicator in early-stage cancer using functionalized graphene-based peptide sensors. Adv Mater 24:125–131
Bochen Z, Uddin MA et al (2016) Temperature dependent carrier mobility in graphene: effect of Pd nanoparticle functionalization and hydrogenation. Appl Phys Lett 108:093102
Xiaochen D, Fu D et al (2009) Doping single-layer graphene with aromatic molecules. Small 5:1422–1426
Zhu Y, Yufeng H et al (2016) A graphene-based affinity nanosensor for detection of low-charge and low-molecular-weight molecules. Nanoscale 8:5815–5819
Liu J, Liu Z, Barrow CJ et al (2015) Molecularly engineered graphene surfaces for sensing applications: a review. Anal Chim Acta 859:1–19
Tang X, Mager N et al (2017) Defect-free functionalized graphene sensor for formaldehyde detection. Nanotechnology 28:055501
Milowska KZ, Majewski JA (2014) Graphene-based sensors: theoretical study. J Phys Chem C 118:17395–17401
Ferrari AC (2007) Raman spectroscopy of graphene and graphite: disorder, electron–phonon coupling, doping and nonadiabatic effects. Solid State Commun 143:47–57
Yaping D, Lu Y, Kybert NJ et al (2009) Intrinsic response of graphene vapor sensors. Nano Lett 9:1472–1475
Ruoxi W, Zhang D et al (2006) Boron-doped carbon nanotubes serving as a novel chemical sensor for formaldehyde. J Phys Chem B 110:18267–18271
Reckinger N, Tang X et al (2016) Oxidation-assisted graphene heteroepitaxy on copper foil. Nanoscale 8:18751–18759
Mei C, Zhao YP (2009) Adsorption of formaldehyde molecule on the intrinsic and Al-doped graphene: a first principle study. Comput Mater Sci 46:1085–1090
Rumyantsev S, Liu G, Shur MS et al (2012) Selective gas sensing with a single pristine graphene transistor. Nano Lett 12:2294–2298
Vineet D, Surwade SP et al (2010) All-organic vapor sensor using inkjet-printed reduced graphene oxide. Angew Chem Int Ed 49:2154–2157
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2019 Springer Nature B.V.
About this paper
Cite this paper
Debliquy, M., Krumpmann, A., Lahem, D., Tang, X., Raskin, JP. (2019). Chemical Sensors for VOC Detection in Indoor Air: Focus on Formaldehyde. In: Bittencourt, C., Ewels, C., Llobet, E. (eds) Nanoscale Materials for Warfare Agent Detection: Nanoscience for Security. NMWAD 2017. NATO Science for Peace and Security Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-94-024-1620-6_4
Download citation
DOI: https://doi.org/10.1007/978-94-024-1620-6_4
Published:
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-024-1619-0
Online ISBN: 978-94-024-1620-6
eBook Packages: Biomedical and Life SciencesBiomedical and Life Sciences (R0)