Abstract
Polymer nanocomposites formed by low-energy ion implantation were studied by means of positron annihilation spectroscopy with a variable-energy positron beam or slow positron beam spectroscopy. Silver ion implantation into polymethylmethacrylate (Ag:PMMA) and hybrid organic-inorganic ureasil (Ag:ureasil) was performed at different ion fluences with a constant energy of 30 keV and a current density of 1 μA/cm2 in order to prepare Ag nanoparticles in the near-surface region of polymer matrix. Contribution of Doppler broadening slow positron beam spectroscopy technique for understanding Ag nanoparticles formation in Ag:PMMA and Ag:ureasil nanocomposite films is demonstrated.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsReferences
Stepanov AL (2010) Synthesis of silver nanoparticles in dielectric matrix by ion implantation: a review. Rev Adv Mater Sci 26:1
Wang J et al (2012) Photoluminescence and reflectivity of polymethylmethacrylate implanted by low-energy carbon ions at high fluences. Appl Surf Sci 261:653
Gupta R et al (2012) Optical characterization of poly(methyl methacrylate) implanted with low energy ions. Appl Surf Sci 263:334
Stepanov AL (2004) Optical properties of metal nanoparticles synthesized in a polymer by ion implantation: a review. Tech Phys 49:143
Galyautdinov MF et al (2016) Formation of a periodic diffractive structure based on poly(methyl methacrylate) with ion-implanted silver nanoparticles. Tech Phys Lett 42:182
Lee EH et al (1992) Improved hardness and wear properties of B-ion implanted polycarbonate. J Mater Res 7:1900
Lee EH et al (1993) Ion beam application for improved polymer surface properties. Nucl Instrum Meth Phys Res B 74:326
Klepikov V, Kruchinin S, Novikov V, Sothikov A (2006) Composite materials with radioactive inclusions as artificial radiation covering. Rev Adv Mater Sci 12:127
Kruchinin S, Novikov V, Klepikov V (2008) Nonlinear current oscillations in a Josephson junction with fractal radioisotope composites. Metrol Meas Syst 15:281
Ermakov V, Kruchinin S, Fujiwara A (2008) In: Bonca J, Kruchinin S (eds) Proceeding of NATO ARW “Electron Transport in Nanosystems”. Springer, pp 341–349
Boldyryeva H et al (2004) Surface modification and nanoparticle formation by negative ion implantation of polymers. Nucl Instr Meth Phys Res B 219–220:953
Boldyryeva H et al (2005) High-fluence implantation of negative metal ions into polymers for surface modification and nanoparticle formation. Surf Coat Technol 196:373
Kavetskyy T S et al (2014) Structural defects and positronium formation in 40 keV B+-implanted polymethylmethacrylate. J Phys Chem B 118:4194
Kavetskyy TS, Stepanov AL (2016) Ion-irradiation-induced carbon nanostructures in optoelectronic polymer materials. In: Monteiro WA (ed) Radiation effects in materials. InTech, Rijeka, pp 287–308
Kavetskyy T et al (2017) High-dose boron and silver ion implantation into PMMA probed by slow positrons: effects of carbonization and formation of metal nanoparticles. J Phys Conf Ser 791:012028
Panzarasa G et al (2016) Positron annihilation spectroscopy: a new frontier for understanding nanoparticle-loaded polymer brushes. Nanotechnology 27:02LT03
Panzarasa G et al (2017) Probing the impact of the initiator layer on grafted-from polymer brushes: a positron annihilation spectroscopy study. Macromolecules 50:5574
Stepanov AL et al (2000) Formation of metal-polymer composites by ion implantation. Phil Mag B 80:23
Stepanov AL et al (2015) Synthesis of porous silicon by ion implantation. Rev Adv Mater Sci 40:155
Kavetskyy T et al (2011) Nanovoids in glasses and polymers probed by positron annihilation lifetime spectroscopy. In: Riethmaier JP et al (eds) Nanotechnological basis for advanced sensors. Springer, Berlin, pp 103–110
Kavetskyy T et al (2012) New organic-inorganic hybrid ureasil-based polymer and glass-polymer composites with ion-implanted silver nanoparticles. Phys Status Solidi C 9:2444
Kavetskyy T et al (2013) New organic-inorganic hybrid ureasil-based polymer materials studied by PALS and SEM techniques. Mater Sci Forum 733:171
Anwand W et al (1995) A magnetically guided slow positron beam for defect studies. Acta Phys Pol A 88:7
Anwand W et al (2012) Design and construction of a slow positron beam for solid and surface investigations. Defect Diffus Forum 331:25
Makhov AF (1961) The penetration of electrons into solids. II. The distribution of electrons in depth. Sov Phys Solid State 2:1942
Vehanen A et al (1987) Profiling multilayer structures with monoenergetic positrons. Phys Rev B 35:4606
Kobayashi Y et al (2008) Application of positron beams to the study of positronium-forming solids. Appl Surf Sci 255:174
Kavetskyy T et al (2017) Acta Phys Pol A Network properties of ureasil-based polymer matrixes for construction of amperometric biosensors as probed by PALS and swelling experiments. 132:1515
Saito F et al (2004) Study of ion irradiated poly-lactic acid using slow positron beam. Mater Sci Forum 445–446:340
Saito F et al (2014) Characterization of ion-irradiated poly-L-lactic acid using nano-cutting. Phys Chem Chem Phys 16:26991
Kavetskyy TS et al (2018) Surface plasmon resonance band of ion-synthesized Ag nanoparticles in high dose Ag: PMMA nanocomposite films. In: Petkov P et al (eds) Advanced nanotechnologies for detection and defence against CBRN agents, Springer, Dordrecht. https://doi.org/10.1007/978-94-024-1298-7_5
Hanemann T, Szabo DV (2010) Polymer-nanoparticle composites: from synthesis to modern applications. Materials 3:3468
Wie S et al (2011) Multifunctional composite core-shell nanoparticles. Nanoscale 3:4474
Kumar KS et al (2013) Recent advancement in functional core-shell nanoparticles of polymers: synthesis, physical properties, and applications in medical biotechnology. J Nanoparticles 2013:672059
Gillet JN, Meunier M (2005) General equation for size nanocharacterization of the core-shell nanoparticles by X-ray photoelectron spectroscopy. J Phys Chem B 109:8733
Puska MJ, Lanki P, Nieminen RM (1989) Positron affinities for elemental metals. J Phys Condens Matter 1:6081
Acknowledgements
This work was financially supported in part by the Ministry of Education and Science of Ukraine (projects #0116U004737 and #0117U007143; to TK), by the Slovak Grant Agency VEGA (project #2/0157/17; to OŠ), and Slovak Research and Development Agency (project #APVV-16-0369; to OŠ), by the National Science Fund of the Bulgarian Ministry of Education (project #FNI-DN09/12-2016; to TK, TP and VB) and by the Russian Foundation for Basic Research (project #15-48-02525; to ALS).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2018 Springer Science+Business Media B.V., part of Springer Nature
About this paper
Cite this paper
Kavetskyy, T.S. et al. (2018). Polymer Nanocomposites with Silver Nanoparticles Formed by Low-Energy Ion Implantation: Slow Positron Beam Spectroscopy Studies. In: Bonča, J., Kruchinin, S. (eds) Nanostructured Materials for the Detection of CBRN. NATO Science for Peace and Security Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-94-024-1304-5_21
Download citation
DOI: https://doi.org/10.1007/978-94-024-1304-5_21
Published:
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-024-1303-8
Online ISBN: 978-94-024-1304-5
eBook Packages: Biomedical and Life SciencesBiomedical and Life Sciences (R0)