Skip to main content

Abstract

The properties of silicon nitride based ceramics, particularly at high temperatures, are controlled by secondary intergranular phases, normally glassy, which are present as a result of sintering additives. Properties of the sintered product can be improved by post-sintering heat treatments to crystallise the grain boundary glass. Second-phase reinforcements, such as SiC platelets or whiskers, offer further possibilities for improvements in properties and this paper describes sintering studies of silicon nitride with SiC inclusions, densified with mixed oxide additives such as Y2O3 + Al2O3. Densities as high as the matrix can be achieved by pressureless sintering with 10% platelets. SiC platelets allow increases in toughness not shown by whisker reinforcements. Toughening mechanisms involve crack deflection around the platelets.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Somiya, S., Kanai, E. and Ando, K. (eds) Proc. 1st Int. Symp. Ceramic components for Engineers, KTK Scientific Publisher, Tokyo, 1984.

    Google Scholar 

  2. Bunk, W. and Hausner, H. (eds) Proc. 2nd Int. Symp. Ceramic Materials and Components for Engines, DKG, Bad Honnef, 1986.

    Google Scholar 

  3. Tennery, V.J. (ed) Proc 3rd Int. Symp. Ceramic Materials and Components for Engines, Am. Ceram. Soc. Inc., 1989.

    Google Scholar 

  4. Hampshire, S. (ed) Non-oxide Technical and Engineering Ceramics, Elsevier-Applied Science Publishers, London, 1986s.

    Google Scholar 

  5. Hampshire, S. and Jack, K.H. The Kinetics of Densification and Transformation of Nitrogen Ceramics. In Special Ceramics 7, ed. P. Popper, Brit. Ceram. Proc., 1981, 31, 37–50.

    Google Scholar 

  6. Wotting, G., Kanka, B. and Ziegler, G. Microstructural Development, Microstructural Characterisation and Relation to Mechanical Properties of Dense Silicon Nitride. In Non-oxide Technical and Engineering Ceramics, ed. S. Hampshire, Elsevier-Applied Science Publishers, 1986, pp.83–96.

    Google Scholar 

  7. Hampshire, S., The Role of Additives in the Pressureless Sintering of Nitrogen Ceramics for Engine Applications. Metals Forum, 1984, 7, 162–170.

    Google Scholar 

  8. Wotting, G. and Ziegler, G., Powder Characteristics and Sintering Behaviour of Si3N4 Powders. Interceram, 1986, 35, 32–35.

    Google Scholar 

  9. Hampshire, S., Pomeroy, M.J. and Saruhan, B. Kinetics of Sintering ofSilicon Nitride with Mixed Oxide Additives. In Hi-tech Ceramics, ed. P. Vincenzini, Elsevier, Mat. Sci. Monogr., 1987, 38A, pp 941–951.

    Google Scholar 

  10. Hampshire, S., Leigh, M., Morrissey, V.J., Pomeroy, M.J. and Saruhan, B., Crystallisation Heat-Treatments of Silicon Nitride Ceramics and Glass-Ceramics Containing Neodymia. In Proc. 3rd Int. Symp. Ceramic Materials and Components for Engines., ed. V. J. Tennery, Am. Ceram. Soc. Inc., 1989, pp.434–442.

    Google Scholar 

  11. Raj. R. and Bordia, R.K., Sintering Behaviour of Bi-Model Powder Compacts. Acta Metal., 1984, 32, 1003–1019.

    Article  Google Scholar 

  12. Hsueh, C.H., Evans, A.G., Cannon, R.M. and Brook, R.J., Acta. Met., 1986, 34, 927.

    Article  Google Scholar 

  13. Buljan, S.T. and Sarin, V.K., Composites, 1987, 18, 99.

    Article  Google Scholar 

  14. Shalek, P.D., Petrovic, J.J., Hurley, G.F. and Gac, F.D., SiC Whisker-Hot Pressed Si3N4 Matrix Composites. Am. Ceram. Soc. Bull., 1986, 65, 351–356.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1992 Elsevier Science Publishers Ltd and MPA Stuttgart

About this chapter

Cite this chapter

Hampshire, S., Song, YJ., O’Sullivan, D., Gunay, V. (1992). Sintering and Toughening of Silicon Nitride-Based Composites. In: Carlsson, R., Johansson, T., Kahlman, L. (eds) 4th International Symposium on Ceramic Materials and Components for Engines. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-2882-7_78

Download citation

  • DOI: https://doi.org/10.1007/978-94-011-2882-7_78

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-85166-776-5

  • Online ISBN: 978-94-011-2882-7

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics