Abstract
The increasing scarcity of resources and growing environmental awareness require higher recycling rates for plastic waste. Common techniques to do that are mechanical recycling, thermal recycling and chemical recycling, which is also called feedstock recycling. From all three techniques, chemical recycling is the only one which can produce new materials that correspond to the quality of conventional virgin material. However, the technique is limited to suitable polymers, e.g. polystyrene, which can be depolymerised at elevated temperatures. For an efficient industrial scale-up, a continuous process is desirable. In our work, we present such a continuous process for the recycling of polystyrene from post-industrial waste. A co-rotating, tightly intermeshing twin-screw extruder in high-temperature design is used together with a vacuum separation system with three degassing openings. By determining a stable process point a continuous depolymerisation of polystyrene is technically realised.
The atmospheric oxygen and moisture are removed via the first degassing opening of the extruder. The degradation products of the depolymerisation process are then degassed through the second and third opening. The degradation products are passed through a water-cooled condenser where they are liquefied. The styrene yield is maximised by tuning the process parameters barrel temperature, screw speed and configuration, mass throughput and degassing design. Analysis of the products reveals a considerable influence on increasing recovery rates with increasing barrel temperature, decreasing throughput and longer residence time. A longer residence time is realised by a lower throughput and an optimised screw configuration. We anticipate our process as a very promising technique to efficiently and economically scale-up the chemical recycling of poly-styrene waste.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
PlasticsEurope Homepage: Plastics – the Facts 2018: https://www.plasticseurope.org/download_file/force/2387/319. Accessed 5 May 2019
Menges, G., Michaeli, W., Bittner, M.: Recycling von Kunststoffen. Hanser, München (1992)
Menges, G., Haberstroh, E., Michaeli, W., Schmachtenberg, E.: Werkstoffkunde Kunststoffe. Hanser, München (2014)
Sasse, F., Emig, G., 10: Chemical recycling of polymer materials. Chem. Eng. Technol.: Ind. Chem.‐Plant Equipment‐Bioprocess. Eng.‐Biotechnol. 21, 777–789 (1998)
Elias, H.G.: Makromoleküle: Chemische Struktur und Synthesen. Wiley, Weinheim (1999)
Achilias, S.: Chemical recycling of polymers. The case of poly (methyl methacrylate). In Proceedings of the International Conference on Energy & Environmental Systems, Chalkida, Greece, pp. 8–10 (2006)
Kaminsky, W., Predel, M., Sadiki, A.: Feedstock recycling of polymers by pyrolysis in a fluidised bed. Polym. Degrad. Stab. 85(3), 1045–1050 (2004)
Yang, M., Shibasaki, Y.: Mechanisms of thermal degradation of polystyrene, polymethacrylonitrile, and their copolymers on flash pyrolysis. J. Polym. Sci., Part A: Polym. Chem. 36(13), 2315–2330 (1998)
Audisio, G., Bertini, F., Beltrame, P.L., Carniti, P.: Catalytic degradation of polymers: Part III—Degradation of polystyrene. Polym. Degrad. Stab. 29(2), 191–200 (1990)
Michaeli, W., K. Breyer: Chemisches Recycling von PMMA–Depolymerisation durch Extrusion. Achema Mag. 97(53) (1997)
Hottinger, A.: Konstruktion, Aufbau und Erprobung eines Laborstandes zur Depolymerisation von Polymethylmethacrylat (PMMA). Institut für Kunststoffverarbeitung, RWTH Aachen, Diplomarbeit (1993)
Schwarz, R.: Aufbau und Inbetriebnahme einer Extrusionsanlage zur kontinuierlichen Depolymerisation von PMMA. Studienarbeit am Institut für Kunststoffverarbeitung, RWTH Aachen (1995)
Born, M., Carl, C., Schneider, G.: Fachkunde Gefahrstoffe. Storck Verlag, Hamburg (2017)
N.N.: Entgasen beim Erstellen und Aufbereiten von Kunststoffen. VDI-Verlag, Düsseldorf (1991)
Acknowledgements
The investigations set out in this report received financial support from Germany’s Federal Ministry of Education and Research within the initiative “Plastics in the Envi-ronment – Sources. Sinks. Solutions.” of the BMBF-framework programme “Research for Sustainable Development” (No. 033R194C), to whom we extend our thanks.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2020 Springer-Verlag GmbH Germany, part of Springer Nature
About this paper
Cite this paper
Schäfer, P. et al. (2020). Continuous Chemical Recycling of Polystyrene with a Twin – Screw Extruder. In: Hopmann, C., Dahlmann, R. (eds) Advances in Polymer Processing 2020. Springer Vieweg, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-60809-8_4
Download citation
DOI: https://doi.org/10.1007/978-3-662-60809-8_4
Published:
Publisher Name: Springer Vieweg, Berlin, Heidelberg
Print ISBN: 978-3-662-60808-1
Online ISBN: 978-3-662-60809-8
eBook Packages: EngineeringEngineering (R0)