Abstract
This chapter provides the Coriolis coupling parameters of the (521), (700), (280) and (342) interacting states of 16O3 measured using continuous wave–cavity ring down spectroscopy.
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Natural isotopic abundance: 0.992728.
Reference | [2012DeB] |
Method | Continous wave –cavity ring down spectroscopy. |
Equations | Equations 10 and 23 in chapter “Introduction”. |
Statistical errors | One standard deviation in units of the least significant full size digits. |
Remarks | All values are given in cm−1. Calculated constants are purposely given with a supplementary digit, in index form, in order to reproduce the energy levels to experimental accuracy. A definite choice between the (280) and the (342) dark state assignments, is not possible. As a result their vibrational designation could be interchanged in the designation of the Coriolis coupling parameters; Molecular constants determined in the same fit are given in chapter “16O3 Vibrational Energy and Rotational and Centrifugal Distortion Constants for the (521), State, and for the Vibrational Dark States (700), (280), and (342)” The isotopic composition of the elements used for the calculation of the natural isotopic abundance is taken from [2007Coh]. |
Abbreviation | SE: Statistical error. |
Coriolis type coupling parameters | ||||||
|---|---|---|---|---|---|---|
<521|H|dark 700> | <dark 280|H|521> | <dark 342|H|521> | ||||
Value | SE | Value | SE | Value | SE | |
C 001 | -0.008210 | 33 | ||||
C 011 | -0.003558 | 20 | 0.0224866 | 20 | ||
C 003 | 0.000011324 | 55 | ||||
Symbols and abbreviations
Short form | Full form |
|---|---|
C y , C yz | Coriolis coupling parameter |
SE | Statistical error |
References
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Guelachvili, G., Picqué, N. (2019). 16O3 Coriolis Coupling Parameters of the (521), (700), (280) and (342) Interacting States. In: Guelachvili, G. (eds) Molecular Constants Mostly from Infrared Spectroscopy. Molecules and Radicals, vol 20C2. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-57960-2_88
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DOI: https://doi.org/10.1007/978-3-662-57960-2_88
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