Abstract
This chapter provides the resonance coupling parameters of the (017) and (045) interacting states of 18O3 measured using continuous wave–cavity ring down spectroscopy.
You have full access to this open access chapter, Download chapter PDF
Similar content being viewed by others
Natural isotopic abundance: 8.62 × 10−9.
Reference | [2012Sta] |
Method | Continous Wave – Cavity Ring Down Spectroscopy. |
Equations | Equation 26 in chapter “Introduction”. |
Statistical errors | One standard deviation in units of the least significant full size digit. |
Remarks | All values are given in cm−1. Statistical errors are given in parentheses. The calculated parameters is purposely given with one supplementary digit, in index form, in order to reproduce the energy levels to experimental accuracy. Molecular constants determined in the same fit are given in chapter “18O3 Vibrational Energy and Rotational and Centrifugal Distortion Constants of the (017) and (045) Interacting States. Band Centers for the ν2 + 7ν3, and 4ν2 + 5ν3 Transitions.” The isotopic composition of the elements used for the calculation of the natural isotopic abundance is taken from [2007Coh]. |
Parameter | <017|H|045> |
|---|---|
A200 × 103 | −0.3546 (55) |
Symbols and abbreviations
Short form | Full form |
|---|---|
A 200 | Resonance coupling parameter |
SE | Statistical error |
References
Cohen, E.R., Cvitaš, T., Frey, J.G., Holmström, B., Kuchitsu, K., Marquardt, R., Mills, I., Pavese, F., Quack, M., Stohner, J., Strauss, H.L., Takami, M., Thor, A.J.: Quantities, Units and Symbols in Physical Chemistry. The IUPAC Green Book, 3rd Ed., Cambridge: RSC Publishing, 2007.
Starikova, E., Barbe, A., De Backer-Barilly, M.R., Tyuterev, V.G., Mondelain, D., Kassi, S., and Campargue, A.: Analysis of the CRDS spectrum of 18O3 between 6950 and 7125 cm−1. J. Quant. Spectrosc. Radiat. Transfer. 113 (2012) 1741–1752.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2019 Springer-Verlag GmbH Germany, part of Springer Nature
About this chapter
Cite this chapter
Guelachvili, G., Picqué, N. (2019). 18O3 Resonance Coupling Parameters of the (017) and (045) Interacting States. In: Guelachvili, G. (eds) Molecular Constants Mostly from Infrared Spectroscopy. Molecules and Radicals, vol 20C2. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-57960-2_364
Download citation
DOI: https://doi.org/10.1007/978-3-662-57960-2_364
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-662-57959-6
Online ISBN: 978-3-662-57960-2