Skip to main content

Theory of Atom Scattering from Surface Phonons: Basic Concepts and Temperature Effects

  • Chapter
  • First Online:
  • 768 Accesses

Part of the book series: Springer Series in Surface Sciences ((SSSUR,volume 63))

Abstract

The reflection coefficient determining the inelastic scattered intensity is defined and analysed theoretically. Various approximations including the Born approximation, the Distorted-Wave Born approximation (DWBA), the GR method and the eikonal approximation are discussed and illustrated with examples. From an expression for the DWBA inelastic reflection coefficient for n-phonon processes, factors determining the relative role of temperature for multiphonon processes and one-phonon scattering are analysed. Several approximate expressions for the Debye-Waller factor are derived and used to define experimental criteria favouring one-phonon scattering. Most of the examples dealt with are for insulator surfaces. Chapter 8 then describes the scattering theory for metal and semiconductor surfaces.

… in the likeness of the waves which in May the course of the wind makes in the cornfields, when one sees the waves running over the fields without the ears of the corn changing their place.

Leonardo da Vinci (1452–1519).

Del moto e misura dell’acqua (Ms F, 87 v).

[cited in Leonardo da Vinci,

by L. H. Heydenreich, Vol 1, p 145 (1954)]

The original version of this chapter was revised: Equations (7.33a) and (7.82) were incorrect, these have been corrected. The correction to this chapter is available at https://doi.org/10.1007/978-3-662-56443-1_15

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   149.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD   199.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Change history

  • 15 November 2019

    ∎∎∎

References

  1. L. Miglio, F. Quasso, G. Benedek, Surf. Sci. 136, L9 (1984)

    Article  ADS  Google Scholar 

  2. L. Miglio, F. Quasso, G. Benedek, J. Chem. Phys. 83, 913 (1985)

    Article  Google Scholar 

  3. V. Bortolani, A. Franchini, F. Nizzoli, G. Santoro, Phys. Rev. Lett. 52, 429 (1984)

    Article  ADS  Google Scholar 

  4. A. Liebsch, J. Harris, B. Salanon, J. Lapujoulade, Surf. Sci. 123, 338 (1982)

    Article  ADS  Google Scholar 

  5. M.S. Daw, M.I. Baskes, Phys. Rev. Lett. 50, 1285 (1983)

    Article  ADS  Google Scholar 

  6. M.S. Daw, M.I. Baskes, Phys. Rev. B 29, 6443 (1984)

    Google Scholar 

  7. J.S. Nelson, E.C. Sowa, M.S. Daw, Phys. Rev. Lett. 61, 1977 (1988)

    Google Scholar 

  8. P.R. Underhill, Surf. Sci. 200, L441 (1988)

    Google Scholar 

  9. W.K. Jacobsen, J.K. Nørskov, M.J. Puska, Phys. Rev. B 35, 7423 (1987)

    Google Scholar 

  10. P.D. Ditlevsen, J.K. Nørskov, J. El. Spectr. Rel. Phenom. 54(55), 237 (1990)

    Article  Google Scholar 

  11. P.D. Ditlevsen, J.K. Nørskov, Surf. Sci. 254, 261 (1991)

    Article  ADS  Google Scholar 

  12. F. Montalenti, M.I. Trioni, G.P. Brivio, S. Crampin, Surf. Sci. Lett. 364, L595 (1996)

    Article  ADS  Google Scholar 

  13. M.I. Trioni, F. Montalenti, G.P. Brivio, Surf. Sci. Lett. 401, L383 (1998)

    Article  ADS  Google Scholar 

  14. M.I. Trioni, S. Marcotulio, G. Santoro, V. Bortolani, G. Palumbo, G.P. Brivio, Phys. Rev. B 58, 11043 (1998)

    Article  ADS  Google Scholar 

  15. G.P. Brivio, M.I. Trioni, Rev. Mod. Phys. 71, 231 (1999)

    Article  ADS  Google Scholar 

  16. N.D. Lang, Phys. Rev. Lett. 46, 842 (1981)

    Article  ADS  Google Scholar 

  17. E. Zaremba, W. Kohn, Phys. Rev. B 13, 2270 (1976)

    Article  ADS  Google Scholar 

  18. E. Zaremba, W. Kohn, Phys. Rev. B 15, 12769 (1977)

    Article  Google Scholar 

  19. N. Esbjerg, J.K. Norskov, Phys. Rev. Lett. 45, 807 (1980)

    Article  ADS  Google Scholar 

  20. J. Harris, A. Liebsch, Phys. Rev. Lett. 49, 341 (1982)

    Article  ADS  Google Scholar 

  21. A. Liebsch, J. Harris, Surface Sci. 111, 2721 (1981)

    Article  Google Scholar 

  22. M.W. Cole, F. Toigo, Phys. Rev. B 31, 727 (1985)

    Article  ADS  Google Scholar 

  23. V. Celli in Helium Atom Scattering from Surfaces, E. Hulpke (Ed.), (Springer, Berlin, 1992), p. 25

    Google Scholar 

  24. P. Nordlander, J. Harris, J. Phys. C 17, 1141 (1984)

    Article  ADS  Google Scholar 

  25. Y. Chen, S.Y. Tong, K.P. Bohnen, T. Rodach, K.M. Ho, Phys. Rev. Lett. 70, 603 (1993)

    Article  ADS  Google Scholar 

  26. S.Y. Tong, Y. Chen, K.P. Bohnen, T. Rodach, K.M. Ho, Surf. Rev. Lett. 1, 97 (1994)

    Article  ADS  Google Scholar 

  27. K.P. Bohnen, K.M. Ho, Surf. Sci. Reports 19, 99 (1993)

    Article  ADS  Google Scholar 

  28. J.P. Senet, G. Benedek, J.P. Toennies, Europhys. Lett. 57, 430 (2002)

    Article  ADS  Google Scholar 

  29. G. Benedek, M. Bernasconi, V. Chis, E. Chulkov, P.M. Echenique, B. Hellsing, J. Peter, Toennies. J. Phys.: Cond. Matter 22, 084020 (2010)

    ADS  Google Scholar 

  30. IYu. Sklyadneva, G. Benedek, E.V. Chulkov, P.M. Echenique, R. Heid, K.-P. Bohnen, J.P. Toennies, Phys. Rev. Lett. 107, 095502 (2011)

    Article  ADS  Google Scholar 

  31. G. Benedek, M. Bernasconi, K.-P. Bohnen, D. Campi, E.V. Chulkov, P.M. Echenique, R. Heid, IYu. Sklyadneva, J.P. Toennies, Phys. Chem. Chem. Phys. 16, 7159 (2014)

    Article  Google Scholar 

  32. L. Schiff, Quantum Mechanics (McGraw-Hill, New York, 1968)

    Google Scholar 

  33. B.H. Brandsen, C.J. Joachain, Introduction to Quantum Mechanics (Longman, New York)

    Google Scholar 

  34. N. Cabrera, V. Celli, J.R. Manson, Phys. Rev. Lett. 22, 346 (1969)

    Article  ADS  Google Scholar 

  35. J.R. Manson, V. Celli, Surf. Sci. 24, 495 (1971)

    Article  ADS  Google Scholar 

  36. V. Bortolani, A.C. Levi, Riv. Nuovo Cim. 9, 1 (1986)

    Article  ADS  Google Scholar 

  37. L. van Hove, Phys. Rev. 95, 249 (1954)

    Article  ADS  MathSciNet  Google Scholar 

  38. V. Celli, N. Garcia, J. Hutchison, Surf. Sci. 87, 112 (1979)

    Article  ADS  Google Scholar 

  39. A.A. Maradudin, E.W. Montroll, G.H. Weiss, I.P. Ipatova, Theory of Lattice Dynamics in the Harmonic Approximation, Solid State Physics, Suppl. 3 (Academic Press, New York, 1971)

    Google Scholar 

  40. A.A. Maradudin, R.F. Wallis, L. Dobrzynski, Handbook of Surfaces and Interfaces, vol. 3 (Garland, New York, 1980)

    Google Scholar 

  41. D. Eichenauer, J.P. Toennies, J. Chem. Phys. 85, 532 (1986)

    Article  ADS  Google Scholar 

  42. C. Zener, Proc. Roy. Soc. (London) 40 (1932) 178 and 335

    Google Scholar 

  43. J.M. Jackson, N.F. Mott, Proc. Roy. Soc. (London) A 137, 703 (1932)

    Google Scholar 

  44. G. Benedek, G. Seriani, Japan J. Appl. Phys. Suppl 2(Pt. 2), 545 (1974)

    Article  ADS  Google Scholar 

  45. G. Benedek, G. Boato, Europhys. News 8, 5 (1977)

    Article  Google Scholar 

  46. Y. Wang, B.H. Choi, N.L. Liu, Phys. Rev. B 43, 7458 (1991)

    Article  ADS  Google Scholar 

  47. B.H. Choi, R.T. Poe, J. Chem. Phys. 83, 1330 (1985); ibidem 83,1344 (1985)

    Google Scholar 

  48. H.-J. Ernst, E. Hulpke, J.P. Toennies, Phys. Rev. Lett. 58, 1941 (1987)

    Article  ADS  Google Scholar 

  49. N. Garcia, J. Ibanez, J. Solana, N. Cabrera, Surf. Sci. 60, 385 (1976)

    Article  ADS  Google Scholar 

  50. N. Garcia, Phys. Rev. Lett. 37, 912 (1976)

    Article  ADS  Google Scholar 

  51. N. Garcia, J. Chem. Phys. 67, 897 (1977)

    Article  ADS  Google Scholar 

  52. G. Benedek, N. Garcia, Ned. Tijdsch. Vacuumtechniek 16, 344 (1978)

    Google Scholar 

  53. G. Benedek, N. Garcia Surf. Sci. 80, 543 (1979). This work is very similar to that of Armand and Manson (AM), quoted at [53]. Here however the first order correction to the source function (δf) is included while AM produced an argument to disregard it. Indeed δf contributes two additional terms in the one-phonon cross section, the first being an inelastic correction to the diffraction amplitudes (required by unitarity), the second an incoherent contribution to the elastic diffuse scattering due to the thermal motion. Both terms, though physically meaningful, do not affect the shape of the one-phonon HAS spectrum and were therefore disregarded in AM theory as well as in all subsequent calculations based on the GR method

    Google Scholar 

  54. G. Benedek, in Dynamics of Gas-Surface Interaction, ed. by G. Benedek, U. Valbusa (Springer, Berlin, Heidelberg, 1982), p. 227

    Google Scholar 

  55. G. Benedek, N. Garcia, Surf. Sci. 103, L143 (1981)

    Article  ADS  Google Scholar 

  56. G. Armand, J.R. Manson, Surf. Sci. 80, 532 (1979)

    Article  ADS  Google Scholar 

  57. G. Benedek, R.B. Doak, J.P. Toennies, Phys. Rev. B 28, 7277 (1983)

    Article  ADS  Google Scholar 

  58. G. Benedek, N. Garcia, Le Vide Suppl. 201, 818 (1980)

    Google Scholar 

  59. G. Benedek, G. Brusdeylins, R.B. Doak, J.P. Toennies, J. Physique (Paris) 42, C6–793 (1981)

    Google Scholar 

  60. J.H. Weare, J. Chem. Phys. 61, 2900 (1974)

    Article  ADS  Google Scholar 

  61. G. Brusdeylins, R.B. Doak, J.P. Toennies, Phys. Rev. Lett. 44, 1417 (1980)

    Article  ADS  Google Scholar 

  62. A.C. Levi, Nuovo Cim. 54 B, 357 (1979)

    Google Scholar 

  63. A.C. Levi, G. Benedek, L. Miglio, G. Platero, V.R. Velasco, F. Garcia-Moliner, Surf. Sci. 143, 253 (1984)

    Article  ADS  Google Scholar 

  64. G. Platero, V.R. Velasco, F. Garcia-Moliner, G. Benedek, L. Miglio, Surf. Sci. 143, 244 (1984)

    Article  ADS  Google Scholar 

  65. G. Brusdeylins, R. Rechsteiner, J.G. Skofronick, J.P. Toennies, G. Benedek, L. Miglio, Phys. Rev. Lett. 54, 466 (1985)

    Article  ADS  Google Scholar 

  66. B. Dorner, Coherent Inelastic Neutron Scattering in Lattice Dynamics (Springer, Berlin, Heidelberg, 1982)

    Book  Google Scholar 

  67. R.S. Leigh, B. Szigeti, V.K. Tewari, Proc. R. Soc. London Ser. A 320, 505 (1971)

    Article  ADS  Google Scholar 

  68. W. Cochran, Acta Crystallogr. Sec. A 27, 556 (1971)

    Article  ADS  Google Scholar 

  69. N.J. Chesser, J.D. Axe, Phys. Rev. B 9, 4060 (1974)

    Article  ADS  Google Scholar 

  70. H. Ibach, D.L. Mills, Electron Energy Loss Spectroscopy and Surface Vibrations (Academic Press, New York, 1982)

    Google Scholar 

  71. J.E. Yater, A.D. Kulkarni, F.W. de Wette, J.L. Erskine, J. Electr. Spectr. Rel. Phenom. 54/55, 395 (1990)

    Google Scholar 

  72. J.L. Erskine, E.-J. Jeong, J. Yater, Y. Chen, S.Y. Tong, J. Vac. Sci. Technol., A 8, 2649 (1990)

    Article  ADS  Google Scholar 

  73. A. Glebov, W. Silvestri, J.P. Toennies, G. Benedek, J.G. Skofronick, Phys. Rev. B 54, 17866 (1996)

    Article  ADS  Google Scholar 

  74. A. Schuller, S. Wethekam, H. Winter, Phys. Rev. Lett. 98, 016103 (2007)

    Article  ADS  Google Scholar 

  75. J.R. Manson, H. Khemliche, P. Roncin, Phys. Rev. B 78, 155408 (2008)

    Article  ADS  Google Scholar 

  76. N. Bundaleski, H. Khemliche, P. Soulisse, P. Roncin, Phys. Rev. Lett. 101, 177601 (2008)

    Article  ADS  Google Scholar 

  77. W. Brenig, Z. Phys. B 36, 81 (1979)

    Google Scholar 

  78. J. Böheim, W. Brenig, Z. Phys. B 41, 243 (1981)

    Google Scholar 

  79. K. Burke, B. Gumhalter, D.C. Langreth, Phys. Rev. B 47, 12852 (1993)

    Article  ADS  Google Scholar 

  80. B. Gumhalter, K. Burke, D.C. Langreth, Surf. Rev. Lett. 1, 133 (1994)

    Article  ADS  Google Scholar 

  81. A. Bilić, B. Gumhalter, Phys. Rev. B 52, 12307 (1995)

    Article  ADS  Google Scholar 

  82. B. Gumhalter, Phys. Rep. 351, 1 (2001)

    Article  ADS  Google Scholar 

  83. W. Brenig, B. Gumhalter, J. Phys. Chem. B 108, 14549 (2004)

    Article  Google Scholar 

  84. J.L. Beeby, J. Phys. C 5, 3438 (1972)

    Article  ADS  Google Scholar 

  85. J.L. Beeby, J. Phys. C 5, 3457 (1972)

    Article  ADS  Google Scholar 

  86. R. Brako, D.M. Newns, Phys. Rev. Lett. 48, 1859 (1982)

    Article  ADS  Google Scholar 

  87. R. Brako, D.M. Newns, Surf. Sci. 117, 42 (1982)

    Article  ADS  Google Scholar 

  88. R. Brako, D.M. Newns, Surf. Sci. 123, 439 (1982)

    Article  ADS  Google Scholar 

  89. V. Celli, D. Himes, P. Tran, J.P. Toennies, Ch. Wöll, G. Zhang, Phys. Rev. Lett. 66, 3160 (1991)

    Article  ADS  Google Scholar 

  90. D. Himes, V. Celli, Surf. Sci. 272, 139 (1992)

    Article  ADS  Google Scholar 

  91. J.R. Manson, Comp. Phys. Comm. 80, 145 (1994)

    Article  ADS  Google Scholar 

  92. R.J. Glauber, Phys. Rev. 98, 1692 (1955); Phys. Rev. 131, 2766 (1963)

    Google Scholar 

  93. N. Terzi, in Collective Excitations in Solids, ed. by. B. Di Bartolo (Plenum, New York, 1983) pp. 149–181; G.M. Mazzucchelli, N. Terzi, Solid State Comm. 48, 679 (1983)

    Google Scholar 

  94. L. van Hove, Phys. Rev. 95, 249 (1954)

    Article  ADS  MathSciNet  Google Scholar 

  95. M.H.L. Pryce, in Phonons in Perfect Lattices and in Lattices with Point Imperfections, ed. by R.W.H. Stevenson (Oliver and Boyd, Edimburgh, 1966), p. 403

    Google Scholar 

  96. A. Giorgetti, N. Terzi, Solid State Comm. 39, 635 (1981)

    Article  ADS  Google Scholar 

  97. A. Šiber, B. Gumhalter, A.P. Graham, J.P. Toennies, Phys. Rev. B 63, 115411 (2001)

    Article  ADS  Google Scholar 

  98. K. Kern, Dissertation (University of Bonn, 1986)

    Google Scholar 

  99. A.C. Levi, H.G. Suhl, Surf. Sci. 88, 221 (1979)

    Article  ADS  Google Scholar 

  100. H.-D. Meyer, Surf. Sci. 104, 117 (1981)

    Article  ADS  Google Scholar 

  101. T. Rahman, private communication

    Google Scholar 

  102. S.K.S. Ma, F.W. de Wette, G.P. Alldredge, Surf. Sci. 78, 598 (1978)

    Article  ADS  Google Scholar 

  103. L. Yang, T.S. Raman, Phys. Rev. Lett. 67, 2327 (1991)

    Article  ADS  Google Scholar 

  104. L. Yang, T.S. Rahman, M.S. Daw, Phys. Rev. B 44, 13725 (1991-II)

    Google Scholar 

  105. Y.W. Lin, S.A. Adelman, G. Wolken, Surf. Sci. 66, 376 (1977)

    Article  ADS  Google Scholar 

  106. B. Baule, Ann. der Physik 44, 145 (1914)

    Article  ADS  Google Scholar 

  107. For a derivation of the Baule formula see R.E. Stickney, Adv. Atomic and Mol. Physics 3 (1967) 143 Appendix

    Google Scholar 

  108. J.W.M. Frenken, P.M.J. Maree, J.F. van der Veen, Phys. Rev. B. 34, 7506 (1986)

    Article  ADS  Google Scholar 

  109. F. Lindemann, Phys. Z. 11, 609 (1910)

    Google Scholar 

  110. H. Lowey, Phys. Rep. 237, 249 (1994)

    Article  ADS  Google Scholar 

  111. T.S. Rahman, J.D. Spangler, A. Al-Rawi, J. Phys. Cond. Matt. 14, 4903 (2002)

    Article  Google Scholar 

  112. G. Brusdeylins, R.B. Doak, J.P. Toennies, Phys. Rev. B 27, 3662 (1983)

    Article  ADS  Google Scholar 

  113. D. Eichenauer, U. Harten, J.P. Toennies, V. Celli, J. Chem. Phys. 86, 3693 (1987)

    Article  ADS  Google Scholar 

  114. J.R. Manson, G. Benedek, S. Miret-Artès, Chem. Phys. Lett. 7, 1016–1021 (2016)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Giorgio Benedek .

Rights and permissions

Reprints and permissions

Copyright information

© 2018 Springer-Verlag GmbH Germany, part of Springer Nature

About this chapter

Check for updates. Verify currency and authenticity via CrossMark

Cite this chapter

Benedek, G., Toennies, J.P. (2018). Theory of Atom Scattering from Surface Phonons: Basic Concepts and Temperature Effects. In: Atomic Scale Dynamics at Surfaces. Springer Series in Surface Sciences, vol 63. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-56443-1_7

Download citation

  • DOI: https://doi.org/10.1007/978-3-662-56443-1_7

  • Published:

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-662-56441-7

  • Online ISBN: 978-3-662-56443-1

  • eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)

Publish with us

Policies and ethics