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Modeling Analysis for Species, Pressure, and Temperature Regulation in Proton Exchange Membrane Fuel Cells

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Nanostructured Materials for Next-Generation Energy Storage and Conversion

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Abstract

The performance degradation of proton exchange membrane or polymer electrolyte membrane fuel cell (PEMFC) stems from air starvation and water flooding. In the mathematical modeling, the conservation equations were applied for momentum, mass, species, charge, and energy, to investigate the heat transfer and temperature distribution in the cathode along with the multiphase and multi-species transport under the steady-state condition. This model shows the effect of stoichiometry of reactants and relative humidity on the water saturation. The back-diffusion of water from the cathode to the anode is considered to reduce possible flooding. The feedback controls are used to address the transient water, pressure, and temperature management problems of a PEMFC system. An anode recirculation system measures the feedback signals to regulate the anode and cathode humidities and the pressure difference between the anode and cathode compartments. It was found that the robust nonlinear controller is insensitive to parametric uncertainty, maintaining performance around any equilibrium point.

Author Contributions

Zhaohui Wang is solely responsible for this review on the modeling analysis of the PEM fuel cell.

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Acknowledgment

The author thanks Dr. Jingbo Liu and Dr. Bashir for their support and encouragement to finish this review chapter.

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Authors and Affiliations

  1. Department of Electrical Engineering and Computer Science, Texas A&M University-Kingsville, Kingsville, TX, USA

    Zhaohui Wang

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  1. Zhaohui Wang
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Correspondence to Zhaohui Wang .

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Editors and Affiliations

  1. Beijing Key Laboratory for Catalysis and Separation, Department of Chemistry and Chemical Engineering College of Environmental and Energy Engineering, Beijing University of Technology, Beijing, China

    Fan Li

  2. Department of Chemistry, Texas A&M University-Kingsville, Kingsville, TX, USA

    Sajid Bashir

  3. Department of Chemistry, Texas A&M University-Kingsville, Kingsville, TX, USA

    Jingbo Louise Liu

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Wang, Z. (2018). Modeling Analysis for Species, Pressure, and Temperature Regulation in Proton Exchange Membrane Fuel Cells. In: Li, F., Bashir, S., Liu, J. (eds) Nanostructured Materials for Next-Generation Energy Storage and Conversion. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-56364-9_9

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