Abstract
This chapter provides the diffusion coefficient of 1-undecanesulfonic acid sodium salt in dideuterium oxide at different concentrations measured using NMR spin echo pulse gradient.
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3 Diffusion in Liquid Mixtures
3.1. Data
3.1.1. Diffusion in Binary Mixtures
C11 H24 O3 S Na | (1) | 1-undecanesulfonic acid sodium salt | 5838-34-6 |
---|---|---|---|
D2 O | (2) | dideuterium oxide | 7789-20-0 |
Intradiffusion Coefficient: D1T (mi); T = 298.15 ± 0.1 K; Method: NMR PG | Ref.: [1999A11] | ||
m1 [mol/kg] | p [kPa] | D ⋅ 109 [m2/s] | |
0.0752 | 101.32 | 0.157 | |
0.0922 | 101.32 | 0.143 | |
0.1060 | 101.32 | 0.126 | |
0.1388 | 101.32 | 0.102 | |
0.1795 | 101.32 | 0.0797 | |
0.2250 | 101.32 | 0.0651 |
Intradiffusion Coefficient: D1T (mi); T = 298.15 ± 0.1 K; Method: NMR PG | Ref.: [2001R10] | ||
---|---|---|---|
m1 [mol/kg] | p [kPa] | D ⋅ 109 [m2/s] | |
0.0000 | 101.32 | 0.600 ± 3% | |
0.0127 | 101.32 | 0.512 ± 3% | |
0.0159 | 101.32 | 0.454 ± 3% | |
0.0173 | 101.32 | 0.439 ± 3% | |
0.0186 | 101.32 | 0.314 ± 3% | |
0.0246 | 101.32 | 0.287 ± 3% | |
0.0357 | 101.32 | 0.241 ± 3% | |
0.0468 | 101.32 | 0.178 ± 3% | |
0.0638 | 101.32 | 0.134 ± 3% | |
0.0829 | 101.32 | 0.107 ± 3% | |
0.1021 | 101.32 | 0.103 ± 3% | |
0.1205 | 101.32 | 0.083 ± 3% |
Symbols and Abbreviations
Short Form | Full Form |
---|---|
D | diffusion coefficient |
p | pressure |
T | temperature |
NMR PG | NMR spin echo pulse gradient |
m i | molality |
References
Annunziata O., Costantino, L., D’Errico, G., Paduano, L., Vitagliano, V.: J. Colloid Interface Sci. 216 (1999) 16–24.
Roscigno P., Paduano, L., D’Errico, G., Vitagliano, V.: Langmuir 17 (2001) 4510–4518.
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Winkelmann, J. (2018). Diffusion coefficient of 1-undecanesulfonic acid sodium salt in dideuterium oxide. In: Lechner, M.D. (eds) Diffusion in Gases, Liquids and Electrolytes. Physical Chemistry, vol 15B2. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-54089-3_957
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DOI: https://doi.org/10.1007/978-3-662-54089-3_957
Publisher Name: Springer, Berlin, Heidelberg
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