Abstract
Extensive studies (1–4) of the structure of starch have not been paralleled by studies of the starch-iodine complex beyond the knowledge that the iodine molecule is located within the helix. Rundle et al. (5) proposed that an induced dipole results when iodine molecules are placed inside the helix, where they interact with the field provided by the hydroxyl groups. By contrast, Greenwood et al. (4) proposed a direct oxygen-iodine interaction based on the generation of infrared absorption peaks in the C-O stretching region in the spectra of the solution of iodine in amylose in the dry state. According to a third view (2) the iodine in a complex is simply dissolved in a hydrocarbon solvent.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
Hanes, C. S., New Phytologist 36, 101, 189 (1937).
Freudenberg, K., E. Schaaf, G. Dumpert, and T. Ploetz, Naturwiss. 27, 850 (1939).
Rundle, R. E. and R. R. Baldwin, J. Amer. Chem. Soc. 65, 554 (1943).
Rundle, R. E. and Dexter French, J. Amer. Chem. Soc. 65, 558 (1943).
Rundle, R. E., J. Amer. Chem. Soc. 69, 1769 (1947).
Greenwood C. T. and Hazet Rossetti, J. Polymer Sci. 17, 481 (1958).
Rundle, R. E., J. F. Foster, and R. R. Baldwin, J. Amer. Chem. Soc. 66, 2116 (1944).
Stein, R. S. and R. E. Rundle, J. Chem. Phys. 16, 195 (1948).
Huggins, M. L., J. Amer. Chem. Soc. 64, 2716 (1942).
Frisch, H. L. and Robert Simha, in: F. R. Eirich (Ed.), Rheology, Vol. 1, p. 525 (New York 1956).
Moore, W. R., in: A. D. Jenkins (Ed.), Progress in Polymer Science, Vol. 1, p. 3 (Oxford, New York 1967).
Huggins, M. L., J. Phys. Chem. 42, 911 (1938).
Huggins, M. L., J. Phys. Chem. 43, 439 (1939).
Huggins, M. L., J. Appl. Phys. 10, 700 (1939).
Huggins, M. L., Physical Chemistry of High Polymers (New York, N. Y. 1958).
Manson, J. A. and L. H. Cragg, Canad. J. Chem. 30, 482 (1952).
Doty, P., H. Wagner, and S. Singer, J. Phys. Colloid Chem. 51, 32 (1947).
Schoch, T. J., in: S. P. Colowick and N. O. Kaplan (Eds.), Methods in Enzymology, Vol. III, p. 5 (New York 1957).
Bauer, A. W. and E. Pacsu, Textile Res. J. 13, No. 12, 864 (1953).
Rao, V. S. and Joseph F. Foster, Biopolymer 1, 527 (1963).
Erlander, S. R. and R. Tobin, Makromol. Chem. 111, 212 (1968).
Eirich, E. and J. Risman, J. Polymer Sci. 4, 417 (1949).
Khairy, M., S. Morsi, and C. Sterling, J. Appl. Polymer Sci. 10, 928 (1966).
Burchard, W., Makromol. Chem. 64, 110 (1963).
Cowie, J. M. G., Makromol. Chem. 53, 13 (1962).
Moore, W. R. and A. M. Brown, J. Colloid Sci. 14, 343 (1959).
Moore, W. R. and D. Sanderson, Polymer 9, 153 (1968).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1975 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Liang, JN., Knauss, C.J., Myers, R.R. (1975). Conformational study by intrinsic viscosities of the starch-iodine complex. In: Vallet, G., Meskat, W. (eds) Rheological Theories · Measuring Techniques in Rheology Test Methods in Rheology · Fractures Rheological Properties of Materials · Rheo-Optics · Biorheology. Steinkopff, Heidelberg. https://doi.org/10.1007/978-3-662-41458-3_183
Download citation
DOI: https://doi.org/10.1007/978-3-662-41458-3_183
Publisher Name: Steinkopff, Heidelberg
Print ISBN: 978-3-7985-0424-0
Online ISBN: 978-3-662-41458-3
eBook Packages: Springer Book Archive