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The Catalytic System Ti-Complex/MgCl2

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Catalytical and Radical Polymerization

Part of the book series: Advances in Polymer Science ((POLYMER,volume 81))

Abstract

MgCl2 supported Ziegler-Natta catalysts for the polymerization of olefins have had recently a spectacular success in simplyfling polymerization processes and improving polymer quality; a rich literature is available reporting various data and interpretations of the mechanisms involved in this type of catalysis.The authors’ aim was to review thoroughly and critically the scientific and patent literature. The characteristics of the components and their interaction are particularly borne in mind in view of the catalysts’ activity and selectivity. Other items concern structure and concentration of the active centers, polymerization kinetics and the role of the catalyst in determining polymer morphology.

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  1. Centro Ricerche Giulio Natta, Himont Italia S.p.A., Piazzale Donegani 12, 44100, Ferrara, Italy

    Pier Camillo Barbé, Giuliano Cecchin & Luciano Noristi

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  1. Pier Camillo Barbé
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  2. Giuliano Cecchin
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  3. Luciano Noristi
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Barbé, P.C., Cecchin, G., Noristi, L. (1986). The Catalytic System Ti-Complex/MgCl2 . In: Catalytical and Radical Polymerization. Advances in Polymer Science, vol 81. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-15187-7_1

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