Abstract
Small Ag n (n ≤ 13) and Cu n (n ≤ 7) clusters, generated by sputtering with a new ultrahigh vacuum (UHV)-compatible Xe-ion gun and size-selected by a quadrupole mass spectrometer, are deposited in situ in submonolayer quantities on a magnesium oxide film supported on a molybdenum single crystal. At low substrate temperature (T = 45 K), the measured electron energy loss spectra display characteristic losses within the MgO band gap. These novel results are discussed in terms of electronic transitions and plasmon excitations within the cluster.
Preview
Unable to display preview. Download preview PDF.
References
V.E. Henrich, P.A. Cox: The surface science of metal oxides 24. ( Cambridge University Press, Cambridge 1994 )
C.T. Campbell: Surf. Scl, Rep. 27, 1 (1997) .
D.A. King, D.P. Woodruff (Eds.): The chemical physics of solid surfaces, Vol. 8, Growth and properties of ultrathin 26. epitaxial layers ( Elsevier, Amsterdam 1997 )
M.G. Gallagher, M.S. Fyfield, J.P. Cowin, S.A. Joyce: Surf. Sci. 339, L909 (1995)
C. Xu, D.W. Goodman: Chem. Phys. Lett. 263, 13 (1996) .
M.-C. Wu, J.S. Corneille, C.A. Estrada, 2.-W. He, D.W. Goodman: Chem. Phys. Lett. 182, 472 (1991) .
M.-C. Wu, J.S. Corneille, J.-W. He, C.A. Estrada, D.W. Goodman: J. Vac. Sci. Technol. A 10, 1467 (1992) .
S.A. Chambers, T.T. Tran, T.A. Hileman, T.A. Jurgens: Surf. Sci. 320, L81 (1994).
W.A. de Heer: Rev. Mod. Phys. 65, 611 (1993)
U. Heiz: Recent Res. Devel. Phys. Chem. 2, 1029 (1998) 32.
M.-H. Schaffner, F. Patthey, U. Heiz, W.-D. Schneider, O. Kuffer, H.-V. Roy, P. Fayet, J.K. Gimzewski, R. Berndt: 33. Eur. Phys. J. D 2, 79 (1998)
P.W. Palrnberg, T.N. Rhodin, C.J. Todd: Appl. Phys. Lett. 34, 33 (1967) .
F. Didier, J. Jupille: Surf. Sci. 307–309, 587 (1994) .
J.-W. He, P.J. Moller: Surf. Sci. 180, 411 (1987) .
M.-C. Wu, W.S. Oh, D.W. Goodman: Surf. Sci. 330, 61 (1995) .
M.-H. Schaffner, F. Patthey, W.-D. Schneider: Surf. Sci. 417, 159 (1998) .
M.-H. Schaffner, F. Patthey, W.-D. Schneider, L.G.M. Pet.tersson: Surf. Sci, 402–404, 450 (1998)
V. Musolino, A. Selioni, R. Car: J. Chem. Phys, 108, 5014 (1998)
M.-H. Schaffner, j.-F. jeanneret, F. Patthey, W.-D. Schneider: J. Phys. D: Appl. Phys. 31, 3177 (1998)
P. Fayet, F. Patthey, H.-V. Roy, Th. Detzel, W.-D. Schneider: Surf. Sci. 269 /270, 1101 (1992)
H.-V. Roy, J. Boschung, F. Patthey, P. Fayet, W.-D. Schneider: Phys. Rev. Lett. 70, 2653 (1993)
R. Keller, F. NOhniayer, P. Spädtke, M.-H. Schönenberg: Vacuum 34, 31 (1984)
M. Liehr, P.A. Thiry, J.J. Pireaux, R. Caudano: Phys. Rev. B 33, 5682 (1986)
L.H. Tieng, AR. Vos, G.A. Sawatzky: Surf. Sci. 235, 269 (1900)
U. Heiz, F. Vanolli, L Trento, W.-D. Schneider: Rev. Sci. Instrum. 68, 1986 (1997)
K. Bromann, C. Félix, Il. Brune, W. Harbich: R. isvionot, J. Buttet, K. Kern: Science 274, 956 (1976)
A.M. Ferrari, G. Pacchioni: J. Phys. Chem. 100. 9032 (1996)
M.J, Stirniman, C. Huang, R. Scott Smith, S.A. Joyce, B.D. Kay: J. Chem. Phys. 105, 1295 (1990)
J.M. Dyke, N.K. Fayad, A. Morris, I.R. Trickle: J. Phys. B: Atom. Molec, Phys. 12, 2985 (1979)
KJ-. Taylor, C.L. Pettiette-Hall, O. Cheslmovsky, R.E. Smalley: J. Chem. Phys. 96, 3319 (1992)
H. Handschuh, C.-Y. Cha, P.S. Bechthold, G. GantefOr, W. Eberhardt: J. Chem. Phys: 102, 6406 (1995)
A.A. Radzig, B.M. Smirnoy: Reference, Data on Atoms, Molecules and ions ( Springer-Vertag. Berlin 1985 )
S. Fedrigo, W. Harbich, J. Buttet: Phys. Rev. B 47, 10 706 (1993)
T.E. Madey: Science 234, 316 (1986)
M.-C. Wu, P.J. Moller: Phys. Rev. B 40, 6063 (1989)
K.A. Gingerich: Farad. Discuss. Chem. Soc. 14, 109 (1980)
D.H.W. Carstens, W. Brashear, D.R. Eslinger, D.M. Gruen: Appl. Spectrosc. 26, 184 (1972)
M. Moskovits, J.E. Hulse: J. Chem. Phys. 67, 1271 (1977)
L. Brewer, G. King: J. Chem. Phys. 53. 3981 (1970)
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1999 Springer-Verlag Italia
About this paper
Cite this paper
Schaffner, MH., Patthey, F., Schneider, WD. (1999). Size-selected Agn and Cun clusters supported on MgO(100) films. In: Châtelain, A., Bonard, JM. (eds) The European Physical Journal D. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-88188-6_123
Download citation
DOI: https://doi.org/10.1007/978-3-642-88188-6_123
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-88190-9
Online ISBN: 978-3-642-88188-6
eBook Packages: Springer Book Archive