Abstract
Transient radicals and triplet-state molecules are generated simultaneously in solution by laser irradiation, and chemically induced electron polarization (CIDEP) of the radicals is studied by time-resolved ESR spectroscopy. The triplet-state molecules are found to induce emissive electron spin polarizations due to triplet-state quenching by radicals as well as quartet-doublet mixing and splitting in radical-triplet pairs.
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S.K. Wong, D.A. Hutchinson, J.K.S. Wan, J. Chem. Phys. 58 (1973) 985.
F.J. Adrian, J. Chem. Phys . 54 (1971) 3918 .
U.E. Steiner, T. Ulrich, Chem. Rev. 89 (1989) 51, and references cited therein.
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© 1990 Springer-Verlag Berlin Heidelberg
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Blättler, C., Jent, F., Paul, H. (1990). A Novel Radical-Triplet Pair Mechanism for Cidep of Free Radicals. In: Mehring, M., von Schütz, J.U., Wolf, H.C. (eds) 25th Congress Ampere on Magnetic Resonance and Related Phenomena. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-76072-3_84
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DOI: https://doi.org/10.1007/978-3-642-76072-3_84
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-540-53136-4
Online ISBN: 978-3-642-76072-3
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