Abstract
From the work of Haubenreißer /1/ and other authors /2/,/3/,/4/ it i s well known, that structural units of different type in solid phosphates, either crystalline or amorphous, give different values of the 31P-NMR chemical shift tensor. By investigations of a large number of crystalline phosphates a correlation was found /l/ between the degree of condensation and the chemical shift tensor parameters δiso, Δδ and η. The Δδ values are very suitable to identify the degree of condensation of the proton-free phosphates /1/,/2/.
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Hartmann, P., Schnabel, B., Vogel, J. (1990). 31P-NMR Investigations of Crystalline Hydrogen Phosphates. In: Mehring, M., von Schütz, J.U., Wolf, H.C. (eds) 25th Congress Ampere on Magnetic Resonance and Related Phenomena. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-76072-3_334
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DOI: https://doi.org/10.1007/978-3-642-76072-3_334
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